2,2',6,6'-tetrachlorobisphenol A

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,2',6,6'-tetrachlorobisphenol A
• 英文别名: 4,4'-Propane-2,2-diylbis(3,5-dichlorophenol)；3,5-dichloro-4-[2-(2,6-dichloro-4-hydroxyphenyl)propan-2-yl]phenol
• 化学式: C₁₅H₁₂Cl₄O₂
• 分子量: 366.071
• InChiKey: PPRWTMVSNOOMDW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  双酚A 在 sodium hypochlorite 作用下， 以 水 为溶剂， 生成 2,2',6,6'-tetrachlorobisphenol A 、 2,4,6-三氯苯酚 、 2-chlorobisphenol A 、 2,6-dichlorobisphenol A
  参考文献：
  名称：

  Chlorination of bisphenol A in aqueous media: formation of chlorinated bisphenol A congeners and degradation to chlorinated phenolic compounds

  摘要：

  The chlorination of bisphenol A (BPA) in aqueous media was investigated in order to describe the degradation profile of this compound and the formation of chlorinated products. Aqueous solutions of BPA (approx. 1 mg/l) were chlorinated by sodium hypochlorite solution at room temperature and under weakly alkaline conditions. Chlorinated compounds were extracted with dichloromethane and determined by gas chromatography/mass spectrometry (GC/ MS). BPA was consumed completely within 5 min of chlorination, when the initial chlorine concentration was 10.24 mg/l (molar ratio to BPA, 58.7). On the other hand, when the initial chlorine concentration was 1.03 mg/l (molar ratio, 6.56), 9.3% of BPA still remained after 60 min chlorination. Five chlorinated BPA congeners, 2-chlorobisphenol A (MCBPA), 2,6-dichlorobisphenol A (2,6-D(2)CBPA), 2,2'-dichlorobisphenol A (2,2'-D(2)CBPA), 2,2',6-trichlorobisphenol A (T(3)CBPA) and 2,2', 6,6'-tetrachlorobisphenol A (T(4)CBPA) were formed in the earlier stages of chlorination. Several chlorinated phenolic compounds, 2,4,6-trichlorophenol (T3CP), 2,6-dichloro-1,4-benzoquinone (D(2)CBQ), 2,6-dichloro-1,4-hydroquinone (D(2)CHQ), C9H10Cl2O2, C9H8Cl2O and C10H12Cl2O2, were also formed by further chlorination. (C) 2002 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0045-6535(01)00198-9

文献信息

• Process for preparing polyarylates in the presence of a diphenyl ether compound and a magnesium catalyst
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0026121A1

  公开（公告）日：1981-04-01

  The present invention deals with a process for preparing polyarylates in the presence of a diphenyl ether compound and a magnesium catalyst. According to the invention, polyarylates are prepared by the reaction of a diester derivative of a dihydric phenol with an aromatic dicarboxylic acid in the presence of from about 10 to about 60 weight percent of a diphenyl ether compound at a temperature of from about 260 to 350°C and in the presence of a magnesium catalyst. This process provides a polyarylate of acceptable molecular weight with a better removal of the acid by-product in a reactant system having a reduced viscosity.

  本发明涉及一种在二苯醚化合物和镁催化剂存在下制备聚芳酸酯的工艺。 根据本发明，聚芳酸酯的制备是通过二元苯酚的二酯衍生物与芳香族二羧酸在约 10 至约 60 重量百分比的二苯醚化合物存在下，在约 260 至 350°C 的温度和镁催化剂存在下进行反应。 该工艺可提供分子量可接受的聚芳酸酯，在粘度降低的反应物体系中可更好地去除酸副产物。
• Mixture of yellow and cyan dyes to form a green hue for color filter array element
  申请人：EASTMAN KODAK COMPANY

  公开号：EP0399473A1

  公开（公告）日：1990-11-28

  A thermally-transferred color filter array element comprising a transparent support having thereon a thermally-transferred image comprising a repeating mosaic pattern of colorants in a receiving layer, one of the colorants being a mixture of a yellow dye and a cyan dye to form a green hue, characterized in that said yellow dye has the formula: wherein: R¹ and R² each independently represents hydrogen; a substituted or unsubstituted alkyl group of from 1 to 6 carbon atoms; a cycloalkyl group of from 5 to 7 carbon atoms; a substituted or unsubstituted aryl or hetaryl group of 6 to 10 carbon atoms; or can be taken together to form, along with the nitrogen to which they are attached, a 5- or 6-membered ring; or either or both of R¹ and R² can be joined to a carbon atom of the aromatic ring at a position ortho to the position of attachment of the anilino nitrogen to form a 5- or 6-membered ring; R³ represents hydrogen or halogen; Y represents hydrogen; halogen; cyano; a substituted or unsubstituted alkyl or alkoxy group of from 1 to 6 carbon atoms; a substituted or unsubstituted aryl or hetaryl group of from 6 to 10 carbon atoms; aryloxy; acylamido, alkylsulfonamido; or arylsulfonamido; and n is a positive integer from 1 to 5; and said cyan dye has the formula: wherein R⁴ and R⁵ each independently represents hydrogen; a substituted or unsubstituted alkyl group of from 1 to 6 carbon atoms; a cycloalkyl group of from 5 to 7 carbon atoms; or a substituted or unsubstituted aryl or hetaryl group of from 6 to 10 carbon atoms; R⁶ represents hydrogen or a substituted or unsubstituted alkyl or alkoxy group of from 1 to 10 carbon atoms; R⁵ may be taken together with R⁴ to form a 5- or 6-membered ring; R⁴ or R⁵ may be combined with R⁶ or may be joined to the carbon atom of the benzene ring at a position ortho to the position of attachment of the anilino nitrogen to form a 5- or 6-membered ring; R⁷ represents hydrogen, a substituted or unsubstituted alkyl or alkoxy group of from 1 to 10 carbon atoms, halogen, sulfonamido or acylamido; R⁸ represents nitro, cyano, fluorosulfonyl, alkylsulfonyl, arylsulfonyl, acyl, alkoxycarbonyl, carbamoyl, sulfamoyl, trifluoromethyl or halogen; R⁹ represents nitro, cyano, acyl, trifluoroacetyl, dicyanovinyl or tricyanovinyl; and J represents -S- or -CH=CR⁸-.

  一种热转印滤色片阵列元件，包括一个透明支架，在其上有一个热转印图像，该图像包括接收层中着色剂的重复马赛克图案，其中一种着色剂是黄色染料和青色染料的混合物，以形成绿色色调，其特征在于所述黄色染料具有以下式子： 其中R¹和R²各自独立地代表氢；1至6个碳原子的取代或未取代的烷基；5至7个碳原子的环烷基；6至10个碳原子的取代或未取代的芳基或庚基；R¹和R²中的一个或两个可在苯胺基氮连接位置的正交位置与芳香环的碳原子连接，形成 5 或 6 元环； R³ 代表氢或卤素； Y 代表氢；卤素；氰基；1 至 6 个碳原子的取代或未取代的烷基或烷氧基；6 至 10 个碳原子的取代或未取代的芳基或正芳基；芳氧基；酰氨基，烷基磺酰胺基；或芳基磺酰胺基；以及 n 是 1 至 5 的正整数；所述青色染料的化学式为 其中 R⁴ 和 R⁵ 各自独立地代表氢；1 至 6 个碳原子的取代或未取代的烷基；5 至 7 个碳原子的环烷基；或 6 至 10 个碳原子的取代或未取代的芳基或正芳基； R⁶ 代表氢或 1 至 10 个碳原子的取代或未取代的烷基或烷氧基； R⁵ 可与 R⁴ 共同形成 5 或 6 元环； R⁴ 或 R⁵ 可与 R⁶ 结合，或在苯胺基氮连接位置的正交位置与苯环的碳原子连接，形成 5 或 6 元环； R⁷ 代表氢、1 至 10 个碳原子的取代或未取代的烷基或烷氧基、卤素、磺酰氨基或酰氨基； R⁸ 代表硝基、氰基、氟磺酰基、烷基磺酰基、芳基磺酰基、酰基、烷氧基羰基、氨基甲酰基、氨基磺酰基、三氟甲基或卤素； R⁹ 代表硝基、氰基、酰基、三氟乙酰基、二氰基乙烯基或三氰基乙烯基；以及 J 代表-S-或-CH=CR⁸-。
• Hydroxyaliphatic functional epoxy resins
  申请人：——

  公开号：US20020091223A1

  公开（公告）日：2002-07-11

  The present invention concerns hydroxyaliphatic functional diglycidyl ethers of bisphenols (epoxy resins); curable (thermosettable) mixtures of at least one hydroxyaliphatic functional epoxy resin and at least one curing agent and/or catalyst therefor, as well as cured (thermoset) compositions prepared therefrom; and derivatives prepared therefrom. The bisphenol precursor to the diglycidyl ether contains a hydroxyaliphatic group linkage between the two aromatic rings of the bisphenol.

  本发明涉及双酚的羟基脂肪族官能二缩水甘油醚（环氧树脂）；至少一种羟基脂肪族官能环氧树脂和至少一种固化剂和/或催化剂的可固化（热固性）混合物，以及由此制备的固化（热固性）组合物；以及由此制备的衍生物。二缩水甘油醚的双酚前体在双酚的两个芳香环之间含有羟基脂肪基连接。
• Non-polyvinyl chloride, interpenetrating network epoxy/urethane acrylates
  申请人：Diversified Chemical Technologies, Inc.

  公开号：US20030119987A1

  公开（公告）日：2003-06-26

  The present invention provides a polymeric material and a process for making the polymeric material. The polymeric material has adhesive and noise abatement properties over a broad temperature range. Further, the material is chip and corrosion resistant and provides metal panel reinforcement.

  本发明提供了一种聚合材料和制造这种聚合材料的工艺。这种聚合材料在较宽的温度范围内具有粘合和降噪性能。此外，该材料还具有抗切屑和抗腐蚀性能，并可提供金属面板加固。
• HYDROXYALIPHATIC FUNCTIONAL EPOXY RESINS
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP1216265A1

  公开（公告）日：2002-06-26