O,O-diethyl (N-phenyl-2,4,5-imidazolidinetrionyl)methyldithiophosphate

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 英文名称: O,O-diethyl (N-phenyl-2,4,5-imidazolidinetrionyl)methyldithiophosphate
• 化学式: C₁₄H₁₇N₂O₅PS₂
• 分子量: 388.405
• InChiKey: ONQYWDNHEAHOBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.97
• 重原子数：
  24.0
• 可旋转键数：
  8.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  76.15
• 氢给体数：
  0.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  二硫代磷酸二乙酯 、 N-chloromethyl-N'-phenyl-2,4,5-imidazolidinetrione 在 sodium carbonate 作用下， 以 丙酮 为溶剂， 反应 4.0h， 以66%的产率得到O,O-diethyl (N-phenyl-2,4,5-imidazolidinetrionyl)methyldithiophosphate
  参考文献：
  名称：

  Synthesis of new phosphorus 2,4,5-imidazolidinetriones

  摘要：

  Phosphorus 2,4,5-imidazolidinetriones are obtained in two different ways : the synthesis of dithiophosphate and phosphonium salt derivatives involves the reaction between a common N-chloromethyl heterocycle and corresponding phosphorus partners, while the preparation of phosphonate and phosphine oxide imidazolidinetriones is done by two multi-step synthesis starting from different phosphorus phthalimides.

  DOI：

  10.1016/0040-4020(95)00595-y

文献信息

• Synthesis of new phosphorus 2,4,5-imidazolidinetriones
  作者：Françoise Plenat、Murielle Cassagne、Henri Jean Cristau

  DOI：10.1016/0040-4020(95)00595-y

  日期：1995.8

  Phosphorus 2,4,5-imidazolidinetriones are obtained in two different ways : the synthesis of dithiophosphate and phosphonium salt derivatives involves the reaction between a common N-chloromethyl heterocycle and corresponding phosphorus partners, while the preparation of phosphonate and phosphine oxide imidazolidinetriones is done by two multi-step synthesis starting from different phosphorus phthalimides.