(2,2 (4),4)-trimethylhexamethylene bis(acrylamide)

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: (2,2 (4),4)-trimethylhexamethylene bis(acrylamide)
• 英文别名: N-[3,5,5-trimethyl-6-(prop-2-enoylamino)hexyl]prop-2-enamide
• 化学式: C₁₅H₂₆N₂O₂
• 分子量: 266.384
• InChiKey: QWXHRLYDUAOAPR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  19
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,2,4-三甲基己烷-1,6-二胺 、 丙烯酰氯 在 sodium hydroxide 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 2.0h， 以86%的产率得到(2,2 (4),4)-trimethylhexamethylene bis(acrylamide)
  参考文献：
  名称：

  A polymerizable phosphoric acid ester derivative and a dental composition employing it

  摘要：

  本发明提供了具有以下结构式（A）的可聚合磷酸酯衍生物：其中Z为COOR1、COSR1、CON(R1)2、CONR1R2、CONHR1或CN；R1和R2独立地为氢原子、经过取代或未经取代的C1至C18烷基，可选地经过C3至C8环烷基取代，经过取代或未经取代的C3至C8环烷基，经过取代或未经取代的C4至C18芳基或杂环芳基，经过取代或未经取代的C5至C18烷基芳基或烷基杂环芳基，或经过取代或未经取代的C7至C30芳基烷基，其中两个R1残基可以与它们结合的N原子一起形成一个5-至7-成员杂环，该杂环除了含有所述的N原子外，还可以含有另一个氮原子或一个氧原子，取代基可以经过1到5个C1至C5烷基的取代；a为1至10的整数，优选为1至5；b为1至10的整数，优选为1至5；R代表一个含有a + b个碳原子的有机残基，选择自主要和次要脂肪碳原子、次要脂环碳原子和芳香碳原子，其中每个碳原子连接一个磷酸酯或2-(氧乙基)丙烯酰衍生物基团。

  公开号：

  EP1454911A1

文献信息

• Hydrolysis stable self-etching, self-priming adhesive
  申请人：Klee Joachim

  公开号：US20080194730A1

  公开（公告）日：2008-08-14

  An aqueous one-pack self-etching and self-priming dental adhesive composition having a pH of at most 2, which comprises: (i) a polymerizable N-substituted alkylacrylic or acrylic acid amide monomer which optionally contains an inorganic acidic moiety selected from a phosphonic acid moiety or a sulfonic acid moiety, and (ii) a curing system.

  一种水性单包自酸化和自引发牙科粘接剂组合物，其pH值最大为2，包括：（i）一种可聚合的N-取代烷基丙烯酸或丙烯酸酰胺单体，可选地包含从磷酸基团或磺酸基团中选择的无机酸性基团，以及（ii）一种固化系统。
• Curable composition
  申请人：FUJIFILM Corporation

  公开号：US10005856B2

  公开（公告）日：2018-06-26

  Provided are a curable composition including an amide compound that is represented by Formula (1) below and of which a density of sulfonic acid is 3.9 milliequivalent/g or greater. m represents an integer of 1 or greater, n represents an integer of 2 or greater, L1 represents a m+1-valent linking group, and L2 represents an n-valent linking group. R1 represents a hydrogen atom or an alkyl group, and R2 represents —SO3−M+ or —SO3R3 (R3 represents an alkyl group or an aryl group). Here, in a case where there are plural R2's, not all of the R2's are —SO3R3. M+ represents a hydrogen ion, an inorganic ion, or an organic ion.

  本发明提供了一种可固化组合物，其中包括由下式（1）表示的酰胺化合物，其磺酸密度为 3.9 毫当量/克或更高。 m 代表 1 或更大的整数，n 代表 2 或更大的整数，L1 代表 m+1 价连接基团，L2 代表 n 价连接基团。R1 代表氢原子或烷基，R2 代表-SO3-M+ 或-SO3R3（R3 代表烷基或芳基）。这里，在有多个 R2 的情况下，并非所有的 R2 都是-SO3R3。M+ 代表氢离子、无机离子或有机离子。
• CURABLE COMPOSITION, FUNCTIONAL POLYMER HARDENED PRODUCT, STACK OR DEVICE COMPRISING FUNCTIONAL POLYMER MEMBRANE, AMIDE COMPOUND, AND MANUFACTURING METHOD THEREOF
  申请人：FUJIFILM Corporation

  公开号：US20170152331A1

  公开（公告）日：2017-06-01

  Provided are a curable composition including an amide compound that is represented by Formula (1) below and of which a density of sulfonic acid is 3.9 milliequivalent/g or greater, a functional polymer hardened product, a stack or a device including a functional polymer membrane, an amide compound, and a manufacturing method thereof. m represents an integer of 1 or greater, n represents an integer of 2 or greater, L 1 represents a m+1-valent linking group, and L 2 represents an n-valent linking group. R 1 represents a hydrogen atom or an alkyl group, and R 2 represents —SO 3 − M + or —SO 3 R 3 (R 3 represents an alkyl group or an aryl group). Here, in a case where there are plural R 2 's, not all of the R 2 's are —SO 3 R 3 . M + represents a hydrogen ion, an inorganic ion, or an organic ion.
• A polymerizable phosphoric acid ester derivative and a dental composition employing it
  申请人：DENTSPLY DETREY GmbH

  公开号：EP1454911A1

  公开（公告）日：2004-09-08

  The present invention provides a polymerizable phosphoric acid ester derivative having the following formula (A):    wherein       Z is COOR1, COSR1, CON(R1)2, CONR1R2, CONHR1, or CN,       R1 and R2 independently are a hydrogen atom, a substituted or unsubstituted C1 to C18 alkyl group optionally substituted by a C3 to C8 cycloalkyl group, a substituted or unsubstituted C3 to C8 cycloalkyl group, a substituted or unsubstituted C4 to C18 aryl or heteroaryl group, a substituted or unsubstituted C5 to C18 alkylaryl or alkylheteroaryl group, or a substituted or unsubstituted C7 to C30 aralkyl group, whereby two R1 residues may form together with the N-atom to which they are bonded a 5- to 7-membered heterocyclic ring which may contain beside said N-atom a further nitrogen atom or an oxygen atom, and whereby the substituted groups may be substituted by 1 to 5 C1 to C5 alkyl group(s);       a is an integer of from 1 to 10, preferably 1 to 5;       b is an integer of from 1 to 10, preferably 1 to 5; and       R represents an organic residue containing a + b carbon atoms selected from primary and secondary aliphatic carbon atoms, secondary alicyclic carbon atoms, and aromatic carbon atoms, each of said carbon atoms linking a phosphate or 2-(oxa-ethyl)acryl derivative group.

  本发明提供了具有以下结构式（A）的可聚合磷酸酯衍生物：其中Z为COOR1、COSR1、CON(R1)2、CONR1R2、CONHR1或CN；R1和R2独立地为氢原子、经过取代或未经取代的C1至C18烷基，可选地经过C3至C8环烷基取代，经过取代或未经取代的C3至C8环烷基，经过取代或未经取代的C4至C18芳基或杂环芳基，经过取代或未经取代的C5至C18烷基芳基或烷基杂环芳基，或经过取代或未经取代的C7至C30芳基烷基，其中两个R1残基可以与它们结合的N原子一起形成一个5-至7-成员杂环，该杂环除了含有所述的N原子外，还可以含有另一个氮原子或一个氧原子，取代基可以经过1到5个C1至C5烷基的取代；a为1至10的整数，优选为1至5；b为1至10的整数，优选为1至5；R代表一个含有a + b个碳原子的有机残基，选择自主要和次要脂肪碳原子、次要脂环碳原子和芳香碳原子，其中每个碳原子连接一个磷酸酯或2-(氧乙基)丙烯酰衍生物基团。