2,5-bis(hydroxymethyl)furan diacrylate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 2,5-bis(hydroxymethyl)furan diacrylate
• 英文别名: 2,5-furandimethanol diacrylate；[5-(Prop-2-enoyloxymethyl)furan-2-yl]methyl prop-2-enoate
• 化学式: C₁₂H₁₂O₅
• 分子量: 236.224
• InChiKey: SFJYFKRLYRWHDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  17
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  65.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2,5-bis(hydroxymethyl)furan diacrylate 、 9,10-二氢-9-氧杂-10-磷杂菲-10-氧化物 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 氯仿 为溶剂， 反应 4.0h， 以92.1%的产率得到2,5‐di[(3‐dopylpropanoyl)methyl]furan
  参考文献：
  名称：

  来自淀粉衍生的双 2,5-（羟甲基）呋喃的有效生物基磷阻燃剂

  摘要：

  通过将淀粉衍生的双-2,5-（羟甲基）呋喃转化为相应的二丙烯酸酯，然后通过迈克尔加成亚磷酸酯生成磷部分通过 P-C 键连接的衍生物，制备了一系列生物基磷阻燃剂。所有化合物在 DGEBA 环氧树脂中都起到有效的阻燃剂的作用。最有效的是 DOPO 衍生物，2,5-二[(3-dopyl-propanoyl)methyl]呋喃。当以提供 2% 磷的水平掺入 DGEBA 共混物中时，与不含添加剂的树脂相比，材料的 LOI 为 30，UL 94 等级为 V0，燃烧峰值放热率降低 40% . 由双酚 A 和四溴双酚 A 生成的类似化合物表现出类似的阻燃性能。

  DOI：

  10.3390/molecules25030592
• 作为产物：
  描述：

  2,5-呋喃二甲醇 、 丙烯酰氯 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 8.0h， 以72.4%的产率得到2,5-bis(hydroxymethyl)furan diacrylate
  参考文献：
  名称：

  来自淀粉衍生的双 2,5-（羟甲基）呋喃的有效生物基磷阻燃剂

  摘要：

  通过将淀粉衍生的双-2,5-（羟甲基）呋喃转化为相应的二丙烯酸酯，然后通过迈克尔加成亚磷酸酯生成磷部分通过 P-C 键连接的衍生物，制备了一系列生物基磷阻燃剂。所有化合物在 DGEBA 环氧树脂中都起到有效的阻燃剂的作用。最有效的是 DOPO 衍生物，2,5-二[(3-dopyl-propanoyl)methyl]呋喃。当以提供 2% 磷的水平掺入 DGEBA 共混物中时，与不含添加剂的树脂相比，材料的 LOI 为 30，UL 94 等级为 V0，燃烧峰值放热率降低 40% . 由双酚 A 和四溴双酚 A 生成的类似化合物表现出类似的阻燃性能。

  DOI：

  10.3390/molecules25030592

文献信息

• MONOMERS AND POLYMERS FROM BIODERIVED CARBON
  申请人：Bloom Paul D.

  公开号：US20090018300A1

  公开（公告）日：2009-01-15

  The present disclosure provides compositions including biobased monomers derived from biological sources for the synthesis of polymers from bioderived carbon. The monomers and resulting polymers are comparable to petroleum derived monomers and polymers, but have a carbon isotope ratio characteristic of bioderived materials. Methods for synthesizing polymers having 100% biobased materials are also disclosed.

  本公开提供了包括从生物源获得的生物基单体的组合物，用于从生物衍生碳合成聚合物。这些单体和聚合物与石油衍生的单体和聚合物相似，但具有生物衍生材料的碳同位素比率特征。本公开还揭示了合成100％生物基材料的聚合物的方法。
• Chemically Recyclable Polyethylene‐like Sulfur‐Containing Plastics from Sustainable Feedstocks
  作者：Yanni Xia、Xinchen Yue、Yue Sun、Chengjian Zhang、Xinghong Zhang

  DOI：10.1002/anie.202219251

  日期：2023.3.20

  We synthesized a new family of chemically recyclable polymers in a large scale from the sustainable monomers H2O, COS, and diacrylates. Such resultant polymers manifest impressive toughness and ductility comparable to commodity polyethylene. The chemical recycling of these polymers can be readily achieved through two closed loops.

  我们从可持续单体 H 2 O、COS 和二丙烯酸酯中大规模合成了一系列新的化学可回收聚合物。此类所得聚合物表现出与商品聚乙烯相当的令人印象深刻的韧性和延展性。这些聚合物的化学回收可以很容易地通过两个闭环实现。
• CURABLE COMPOSITION FOR IMPRINTING, CURED PRODUCT, PATTERN FORMING METHOD, LITHOGRAPHY METHOD, PATTERN, MASK FOR LITHOGRAPHY, AND POLYMERIZABLE COMPOSITION FOR IMPRINTING
  申请人：FUJIFILM Corporation

  公开号：US20200157267A1

  公开（公告）日：2020-05-21

  The curable composition for imprinting includes: a compound represented by the following Formula (1); a radically polymerizable compound other than the compound represented by Formula (1); and a photoradical polymerization initiator, in Formula (1), R 1 and R 2 each independently represent a hydrogen atom or an organic group having 1 to 8 carbon atoms and may be bonded to each other to form a ring, R 3 represents a monovalent organic group, and R 4 and R 5 each independently represent a hydrogen atom or a monovalent organic group.
• KIT, COMPOSITION FOR FORMING UNDERLAYER FILM FOR IMPRINTING, LAMINATE, AND PRODUCTION METHOD USING THE SAME
  申请人：FUJIFILM Corporation

  公开号：US20200363718A1

  公开（公告）日：2020-11-19

  Provided is a kit including a curable composition for imprinting which contains a polymerizable compound having an aromatic ring and a composition for forming an underlayer film for imprinting which contains a polymer and a solvent, in which the polymer contains at least one kind of specific constitutional unit and has a polymerizable group, a film formed of the composition for forming an underlayer film for imprinting is a solid film at 23° C., and a portion that has a continuous partial structure containing an aromatic ring which is included in the polymerizable compound and accounts for 60% by mass or more of the polymerizable compound is common to a continuous partial structure containing an aromatic ring which is included in a substituent R in a side chain in the polymer. Furthermore, the present invention relates to a composition for forming an underlayer film for imprinting which is used in combination with a curable composition for imprinting; a laminate; a method for producing a laminate; a method for producing a cured product pattern; and a method for manufacturing a circuit board.
• COMPOSITION FOR FORMING PATTERN, KIT, CURED FILM, LAMINATE, PATTERN PRODUCING METHOD, AND METHOD FOR MANUFACTURING SEMICONDUCTOR ELEMENT
  申请人：FUJIFILM Corporation

  公开号：US20220009153A1

  公开（公告）日：2022-01-13

  Provided are: a composition for forming a pattern, which contains a polymerizable compound, a photopolymerization initiator, and a sensitizer containing two or more of at least one kind of atom selected from the group consisting of a nitrogen atom and a sulfur atom, in which a length of a specific atom chain from one atom to another atom among the two or more atoms is 2 or 3 in terms of the number of atoms; a kit to which the composition for forming a pattern is applied; a cured film; a laminate; a pattern producing method; and a method for manufacturing a semiconductor element.