isovaleric acid diglycol ester

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: isovaleric acid diglycol ester
• 英文别名: 1,2-bis-isovaleryloxy-ethane；1,2-Bis-isovaleryloxy-aethan；Ethane-1,2-diyl bis(3-methylbutanoate)；2-(3-methylbutanoyloxy)ethyl 3-methylbutanoate
• 化学式: C₁₂H₂₂O₄
• 分子量: 230.304
• InChiKey: GCTDXSKNEMXXHP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  异戊酸 、 乙二醇 在 硫酸 、 甲苯 作用下， 生成 isovaleric acid diglycol ester
  参考文献：
  名称：

  Iwakura, Kobunshi Kagaku, 1945, vol. 2, p. 287,296

  摘要：

  DOI：

文献信息

• COLORING COMPOSITION, CURED FILM, COLOR FILTER, METHOD FOR PRODUCING COLOR FILTER, SOLID-STATE IMAGING ELEMENT, IMAGE DISPLAY DEVICE, ORGANIC ELECTROLUMINESCENT ELEMENT, DYE AND METHOD FOR PRODUCING DYE
  申请人：Fujifilm Corporation

  公开号：EP3133126A1

  公开（公告）日：2017-02-22

  A coloring composition having excellent light fastness, color migration properties, and flatness, a colorant, and a method for producing a colorant are provided. Further, a cured film, a color filter, a method for manufacturing a color filter, a solid-state imaging device, an image display device, and an organic electroluminescent element, each using such the coloring composition, are also provided. The coloring composition contains a colorant represented by General Formula (1) and a curable compound, and has a specific absorbance of 5 or more at a maximum absorption wavelength of 400 nm to 800 nm. R1 represents an (m + n)-valent linking group, P represents a monovalent substituent having a repeating units derived from a vinyl compound, D represents a colorant structure, and R2 and L1 each independently represent a single bond or a divalent linking group.         (D-R2)nR1-(L1-P)m     (1)

  本发明提供了一种具有优异耐光性、色彩迁移特性和平整度的着色组合物、着色剂以及生产着色剂的方法。此外，还提供了一种固化薄膜、一种彩色滤光片、一种制造彩色滤光片的方法、一种固态成像装置、一种图像显示装置和一种有机电致发光元件，它们都使用了这种着色组合物。着色组合物含有通式（1）表示的着色剂和可固化化合物，在最大吸收波长 400 纳米至 800 纳米处的比吸收率为 5 或更高。R1 代表(m+n)价连接基团，P 代表具有来自乙烯基化合物的重复单元的单价取代基，D 代表着色剂结构，R2 和 L1 各自独立地代表单键或二价连接基团。 (D-R2)nR1-(L1-P)m (1)
• Catalytic hydroxycarbonylation of isobutylene with carbon monoxide and polyhydric alcohols in the presence of the Pd(acac)2-PPh3-TsOH system
  作者：H. A. Suerbaev、E. G. Chepajkin、B. Zh. Dzhiembaev、I. O. Appazov、G. M. Abyzbekova

  DOI：10.1134/s0965544107050064

  日期：2007.9

  The reaction of isobutylene hydroalcoxycarbonylation with CO and polyhydric alcohols (ethylene glycol, glycerol) in the presence of the catalytic system Pd(aacac)(2)-PPh3-TsOH has been investigated. It was found that carbonylation of isobutylene with CO in the presence of ethylene glycol yields a mixture of mono-and diglycol esters of isovaleric acid, irrespective of the initial reactant ratio. During the hydroalcoxycarbonylation of isobutylene with glycerol, either mono- and di- or mono-, di-, and triglycerides of isovaleric acid are formed depending on the reactant ratio.
• Hydroalkoxycarbonylation of isobutylene with polyhydric alcohols in the presence of catalytic systems based on palladium compounds and tertiary phosphines
  作者：Kh. A. Suerbaev、E. G. Chepaikin、N. O. Appazov、B. Zh. Dzhiembaev

  DOI：10.1134/s0965544112030127

  日期：2012.5

  The reaction of isobutylene hydroalkoxycarbonylation at low carbon monoxide pressures (a parts per thousand currency sign2.0 MPa) with ethylene glycol and glycerol in the presence of catalytic systems based on Pd and mono- and bidentate organic phosphines has been studied. The effect of different conditions of the reaction in the presence of the Pd(Acac)(2)-PPh3-TsOH catalyst system on the ratio of the products, mono- and diglycolides (mono-, di-and triglycerides) of isovaleric acid has been investigated. The relative catalytic activity of a number of binary and ternary systems based on synthesized Pd(Acac)(2), Pd(PPh3)(4), and PdCl2(PPH3)(2) complexes has been determined.
• COLORING COMPOSITION, CURED FILM, COLOR FILTER, METHOD FOR MANUFACTURING COLOR FILTER, SOLID-STATE IMAGING DEVICE, IMAGE DISPLAY DEVICE, ORGANIC ELECTROLUMINESCENT ELEMENT, COLORANT, AND METHOD FOR PRODUCING COLORANT
  申请人：FUJIFILM Corporation

  公开号：US20170010530A1

  公开（公告）日：2017-01-12

  A coloring composition having excellent light fastness, color migration properties, and flatness, a colorant, and a method for producing a colorant are provided. Further, a cured film, a color filter, a method for manufacturing a color filter, a solid-state imaging device, an image display device, and an organic electroluminescent element, each using such the coloring composition, are also provided. The coloring composition contains a colorant represented by General Formula (1) and a curable compound, and has a specific absorbance of 5 or more at a maximum absorption wavelength of 400 nm to 800 nm. R 1 represents an (m+n)-valent linking group, P represents a monovalent substituent having a repeating units derived from a vinyl compound, D represents a colorant structure, and R 2 and L 1 each independently represent a single bond or a divalent linking group. (D-R 2 ) n —R 1 -(L 1 -P) m (1)
• Iwakura, Kobunshi Kagaku, 1945, vol. 2, p. 287,296
  作者：Iwakura

  DOI：——

  日期：——