二茚并[4,3,2,1-cdef:1',2',3'-hi]屈 | 169331-76-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 二茚并[4,3,2,1-cdef:1',2',3'-hi]屈
• 英文名称: diindeno<4,3,2,1-cdef;1',2',3'-hi>chrysene
• 英文别名: Diindeno[4,3,2,1-cdef:1',2',3'-HI]chrysene；octacyclo[15.10.1.02,6.03,16.04,13.05,10.021,28.022,27]octacosa-1,3(16),4(13),5(10),6,8,11,14,17,19,21(28),22,24,26-tetradecaene
• CAS: 169331-76-4
• 化学式: C₂₈H₁₄
• 分子量: 350.419
• InChiKey: YHYWVAPNQFPKSC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  28
• 可旋转键数：
  0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  二茚并[4,3,2,1-cdef:1',2',3'-hi]屈 以 solid 为溶剂， 以0.6%的产率得到fluoreno<1,9,8-abcd>corannulene
  参考文献：
  名称：

  High temperature synthesis to bowl-shaped subunits of fullerenes - IV. From 4-[9H-fluorenylidene-(9)]-4H-cyclopenta[def]phenanthrene to fluoreno[1,9,8-abcd]corannulene and difluoreno[1,9,8,7-cdefg;2′,1′,9′,8′-klmno]anthracene

  摘要：

  Fluoreno[1,9,8-abcd]corannulene (4) and difluoreno[1,9,8,7-cdefg;2',1',9',8'-klmno]-anthracene (8) have been synthesized by multistage thermal and catalytic dehydrocyclization reactions starting from 4-[9H-fluorenylidene-(9)]-4H-cyclopenta[def]phenanthrene and benzo[p]naphtho-[1,8,7-ghi]chrysene, respectively.

  DOI：

  10.1016/0040-4020(95)00330-b
• 作为产物：
  描述：

  4-<9H-fluorenylidene-(9)>-4H-cyclopentaphenanthrene 以 solid 为溶剂， 以22%的产率得到苯并[p]萘并[1,8,7-ghi]屈
  参考文献：
  名称：

  High temperature synthesis to bowl-shaped subunits of fullerenes - IV. From 4-[9H-fluorenylidene-(9)]-4H-cyclopenta[def]phenanthrene to fluoreno[1,9,8-abcd]corannulene and difluoreno[1,9,8,7-cdefg;2′,1′,9′,8′-klmno]anthracene

  摘要：

  Fluoreno[1,9,8-abcd]corannulene (4) and difluoreno[1,9,8,7-cdefg;2',1',9',8'-klmno]-anthracene (8) have been synthesized by multistage thermal and catalytic dehydrocyclization reactions starting from 4-[9H-fluorenylidene-(9)]-4H-cyclopenta[def]phenanthrene and benzo[p]naphtho-[1,8,7-ghi]chrysene, respectively.

  DOI：

  10.1016/0040-4020(95)00330-b

文献信息

• High temperature synthesis to bowl-shaped subunits of fullerenes - IV. From 4-[9H-fluorenylidene-(9)]-4H-cyclopenta[def]phenanthrene to fluoreno[1,9,8-abcd]corannulene and difluoreno[1,9,8,7-cdefg;2′,1′,9′,8′-klmno]anthracene
  作者：Stefan Hagen、Hilmar Christoph、Gerhard Zimmermann

  DOI：10.1016/0040-4020(95)00330-b

  日期：1995.6

  Fluoreno[1,9,8-abcd]corannulene (4) and difluoreno[1,9,8,7-cdefg;2',1',9',8'-klmno]-anthracene (8) have been synthesized by multistage thermal and catalytic dehydrocyclization reactions starting from 4-[9H-fluorenylidene-(9)]-4H-cyclopenta[def]phenanthrene and benzo[p]naphtho-[1,8,7-ghi]chrysene, respectively.