1-methylcyclododecyl methacrylate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 1-methylcyclododecyl methacrylate
• 英文别名: (1-Methylcyclododecyl) 2-methylprop-2-enoate
• 化学式: C₁₇H₃₀O₂
• 分子量: 266.424
• InChiKey: JCAUKHSUQBYBBD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-methylcyclododecyl methacrylate 、 环戊二烯 以 四氢呋喃 为溶剂， 反应 24.0h， 以70%的产率得到1-methylcyclododecyl 5-norbornene-2-carboxylate
  参考文献：
  名称：

  [EN] CHEMICALLY AMPLIFIED POLYMER HAVING PENDANT GROUP WITH CYCLODODECYL AND RESIST COMPOSITION COMPRISING THE SAME
  [FR] POLYMERE A AMPLIFICATION CHIMIQUE COMPRENANT UN GROUPE PENDANT AVEC CYCLODODECYLE ET COMPOSITION DE RESINE LE RENFERMANT

  摘要：

  本发明涉及一种具有与环十二烷键合的侧链基团的化学增感聚合物，其制备方法，以及包括它的抗蚀剂组合物，更具体地说，涉及一种新型的（甲基）丙烯酸或诺博烯羧酸酯化合物，其与环十二烷键合，其制备方法，用其合成的化学增感聚合物，以及包括该聚合物的用于ArF的正向光刻胶组合物，具有高分辨率和优异的蚀刻抗性。

  公开号：

  WO2004041770A1

文献信息

• Acrylic Acid-Based Polymer and Method of Producing the Same
  申请人：Kubo Hideo

  公开号：US20090111961A1

  公开（公告）日：2009-04-30

  Disclosed are an acrylic acid-based polymer which is a star polymer containing a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I): (wherein R 1 represents a hydrogen atom or a lower alkyl group, and R 2 represents an organic group having a polar group) in an arm portion; an acrylic acid-based polymer containing a repeating unit derived from an poly(α-lower alkyl)acrylic ester and a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I), and a method for producing a polymer through living polymerization, comprising forming an oligomer having a polymerization active end, which is an oligomer higher than an average 1.0-mer and lower than an average 4.0-mer or an average 4.0-mer, and polymerizing using the oligomer having a polymerization active end as an initiating species.

  本发明涉及一种基于丙烯酸的星型聚合物，其包含来自式（I）所表示的（α-较低烷基）丙烯酸酯的重复单元的臂部分；以及一种基于丙烯酸的聚合物，其包含来自聚（α-较低烷基）丙烯酸酯和式（I）所表示的（α-较低烷基）丙烯酸酯的重复单元，并且本发明还提供了通过活性聚合制备聚合物的方法，包括形成具有聚合活性端的寡聚体，该寡聚体高于平均1.0-聚体但低于平均4.0-聚体或平均4.0-聚体，并以具有聚合活性端的寡聚体作为引发物种进行聚合。
• ACRYLIC ACID-BASED POLYMER AND METHOD OF PRODUCING THE SAME
  申请人：Kubo Hideo

  公开号：US20110046333A1

  公开（公告）日：2011-02-24

  Disclosed are an acrylic acid-based polymer which is a star polymer containing a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I): (wherein R 1 represents a hydrogen atom or a lower alkyl group, and R 2 represents an organic group having a polar group) in an arm portion; an acrylic acid-based polymer containing a repeating unit derived from an poly(α-lower alkyl)acrylic ester and a repeating unit derived from an (α-lower alkyl)acrylic ester represented by formula (I), and a method for producing a polymer through living polymerization, comprising forming an oligomer having a polymerization active end, which is an oligomer higher than an average 1.0-mer and lower than an average 4.0-mer or an average 4.0-mer, and polymerizing using the oligomer having a polymerization active end as an initiating species.

  本文揭示了一种基于丙烯酸的星形聚合物，其包含由公式(I)表示的(α-低烷基)丙烯酸酯衍生的重复单元的臂部分；一种基于丙烯酸的聚合物，其中包含由聚(α-低烷基)丙烯酸酯和由公式(I)表示的(α-低烷基)丙烯酸酯衍生的重复单元，并且通过活性聚合法制备聚合物的方法，包括形成具有聚合活性端的寡聚物，该寡聚物高于平均1.0-聚体但低于平均4.0-聚体或平均4.0-聚体，并使用具有聚合活性端的寡聚物作为引发物种进行聚合。
• METHOD FOR PRODUCING STAR POLYMER
  申请人：Nippon Soda Co., Ltd.

  公开号：EP2186838A1

  公开（公告）日：2010-05-19

  It is to provide a star polymer that can be used as a photoresist material of photolithography processing with no linear polymer remained. After forming the core part by producing a polymer by polymerizing one or more polyfunctional (meth)acrylic acid ester derivative represented by formula (IV) (wherein R represents a hydrogen atom, etc. , n represents 2 or 3, and A represents an organic group linking at a carbon atom) by anionic polymerization in an organic solvent, in the presence of 0.1 to 0.99 mol of organic alkali metal compound with respect to 1 mol of the compound of the formula (IV), and in the presence of 0.1 to 20 mol of inorganic salts of alkali metal or alkali earth metal with respect to 1 mol of the organic alkali metal compound, the arm part is formed by polymerizing one or more monofunctional (meth)acrylic acid ester derivative represented by formula (I) (wherein R1 represents a hydrogen atom, etc., and R2 represents an organic group) by anionic polymerization from the anionic active site of the core part.

  其目的是提供一种星形聚合物，可用作光刻加工的光刻胶材料，且不残留线性聚合物。通过聚合一种或多种由式（IV）表示的多官能度（甲基）丙烯酸酯衍生物来生产聚合物，从而形成核心部分。 (其中 R 代表氢原子等式(IV)代表的一种或多种多官能团(甲基)丙烯酸酯衍生物(其中R代表氢原子等，n代表2或3，A代表连接在碳原子上的有机基团)在有机溶剂中，在0.1至0.99摩尔有机碱金属化合物(相对于1摩尔式(IV)化合物)和0.1至20摩尔碱金属或碱土金属的无机盐（相对于1摩尔有机碱金属化合物）的情况下，通过聚合一种或多种由式(I)代表的单官能团(甲基)丙烯酸酯衍生物，形成臂部分。 (其中 R1 代表氢原子等，R2 代表有机基团）通过阴离子聚合从核心部分的阴离子活性位点形成。
• Positive resist composition and method of forming pattern using the same
  申请人：FUJIFILM Corporation

  公开号：EP1489459B1

  公开（公告）日：2015-10-14
• ACRYLIC STAR POLYMER
  申请人：NIPPON SODA CO., LTD.

  公开号：EP1752479B1

  公开（公告）日：2013-02-27