phenyl-(1,1,2-tribromo-ethyl)-ether

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: phenyl-(1,1,2-tribromo-ethyl)-ether
• 英文别名: Phenyl-(1,1,2-tribrom-aethyl)-aether；1.1.2-Tribrom-1-phenoxy-aethan；1,1,2-Tribromoethoxybenzene
• 化学式: C₈H₇Br₃O
• 分子量: 358.855
• InChiKey: PYFMNEQBUHBZFS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  sodium phenoxide 在 1,4-二氧六环 、 四氯化碳 、 溴 作用下， 生成 phenyl-(1,1,2-tribromo-ethyl)-ether
  参考文献：
  名称：

  McElvain; Fajardo-Pinzon, Journal of the American Chemical Society, 1945, vol. 67, p. 651

  摘要：

  DOI：

文献信息

• Color balanced rubber-reinforced plastic
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0260083A2

  公开（公告）日：1988-03-16

  The color stability of certain rubber-­reinforced polymeric compositions upon exposure to ultraviolet (UV) light is enhanced by incorporating a fadeable, yellow color balancer in an amount effective to reduce the overall color shift of the plastic due to exposure to UV light. The color balancer is an organic dye or pigment, preferably and anthraquinone dye, present in an amount (0.001 to 0.1 weight percent) below that at which it would be used to color the composition.

  某些橡胶增强聚合物成分在紫外线（UV）照射下的颜色稳定性，可通过加入一定量的可褪色的黄色颜色平衡剂来提高，该平衡剂的用量可有效减少塑料在紫外线照射下的整体颜色偏移。 颜色平衡剂是一种有机染料或颜料，最好是蒽醌染料，其用量（0.001 至 0.1 重量百分比）低于用于给成分着色的用量。
• (Meth)acrylates, resin composition using the same and ultraviolet-curing resin composite for transmission type screens
  申请人：Nippon Kayaku Kabushiki Kaisha

  公开号：EP0519410A2

  公开（公告）日：1992-12-23

  This invention relates to (meth)acrylates represented by formula (1):    wherein, R₁ and R₂ are each independently H or CH₃ and average value of n is 1 - 5; resin composite comprising (A) an urethane (meth)acrylate and/or epoxy (meth)acrylate, (B) a (meth)acrylate represented by formula (1) above, (C) an ethylenically unsaturated compound other than component (A) or (B), and (D) a photopolymerization initiator; and cured products of said resin composites. The cured products of said resin composites of this invention have high refractive index and are superior in mold release property, shape reproducibility, restorability, and scratch resistance and suited in particular for transmission type screens.

  本发明涉及式（1）所代表的（甲基）丙烯酸酯： 其中，R₁ 和 R₂ 各自独立地为 H 或 CH₃，n 的平均值为 1 - 5；树脂复合材料，包括 (A) 聚氨酯（甲基）丙烯酸酯和/或环氧（甲基）丙烯酸酯，(B) 上述式 (1) 所代表的（甲基）丙烯酸酯，(C) 除组分 (A) 或 (B) 以外的乙烯基不饱和化合物，以及 (D) 光聚合引发剂；以及上述树脂复合材料的固化产物。本发明的上述树脂复合材料的固化产物具有高折射率，在脱模性、形状再现性、修复性和抗划伤性方面都很出色，尤其适用于透射型屏幕。
• METHOD FOR DECOMPOSING POLYCARBONATE
  申请人：TEIJIN LIMITED

  公开号：EP1731218A1

  公开（公告）日：2006-12-13

  A method of decomposing a polycarbonate with water in a supercritical or subcritical state. A high-purity dihydroxy compound which is a constituent component of the polycarbonate can be recovered at a high yield by this decomposition method. This decomposition method is environment-friendly because it does not use an organic solvent, easy to be carried out, has a high decomposition rate and rarely causes a side reaction.

  一种在超临界或亚临界状态下用水分解聚碳酸酯的方法。通过这种分解方法，可以高产率回收作为聚碳酸酯组成成分的高纯度二羟基化合物。这种分解方法不使用有机溶剂，易于操作，分解率高，而且很少引起副反应，因此对环境友好。
• Styrene based compositions made with a minor part of metal free recycled styrene polymer
  申请人：Total Petrochemicals Research Feluy

  公开号：EP2354168A1

  公开（公告）日：2011-08-10

  The present invention relates to styrene based compositions made with a minor part of metal free post-consumer recycled styrene polymer. This metal free post-consumer recycled styrene polymer can include electronics and electrical devices. Advantageously the proportion of the metal free recycled vinyl aromatic polymer is up to 50 weight % of the overall polymer (virgin vinyl aromatic polymer + metal free recycled vinyl aromatic polymer). This means the present invention is a vinyl aromatic polymer composition comprising 1 to 50 weight % of a metal free recycled vinyl aromatic polymer for respectively 99 to 50 weight % of a virgin vinyl aromatic polymer. Preferably said proportion is from 1 to 30%. This means the present invention is a vinyl aromatic polymer composition comprising 1 to 30 weight % of a metal free recycled vinyl aromatic polymer for respectively 99 to 70 weight % of a virgin vinyl aromatic polymer. Advantageously the present invention is a vinyl aromatic polymer composition comprising 5 to 15 weight % of a metal free recycled vinyl aromatic polymer for respectively 95 to 85 weight % of a virgin vinyl aromatic polymer. In an embodiment the present invention relates to flame resistant vinyl aromatic polymer based compositions comprising, 1 to 30 parts by weight of a flame retardant, 0.5 to 15 parts by weight of a flame retardant aid, 0 to 2 parts by weight of an anti dripping agent, 0 to 5 parts by weight of additives, per 100 parts by weight of a vinyl aromatic polymer mixture comprising a minor part of metal free recycled vinyl aromatic polymer.

  本发明涉及使用少量不含金属的消费后再生苯乙烯聚合物制成的苯乙烯基组合物。这种不含金属的消费后再生苯乙烯聚合物可包括电子和电气设备。 无金属回收乙烯基芳香族聚合物在整个聚合物（原生乙烯基芳香族聚合物 + 无金属回收乙烯基芳香族聚合物）中的比例最好达到 50%。这意味着本发明是一种乙烯基芳香族聚合物组合物，其中 1 至 50 重量百分比的无金属回收乙烯基芳香族聚合物分别代表 99 至 50 重量百分比的原生乙烯基芳香族聚合物。 上述比例最好为 1 至 30%。这意味着本发明是一种乙烯基芳香族聚合物组合物，其中不含金属的再生乙烯基芳香族聚合物占原生乙烯基芳香族聚合物的重量百分比为 1 至 30%，原生乙烯基芳香族聚合物的重量百分比为 99 至 70%。 更有利的是，本发明是一种乙烯基芳香族聚合物组合物，其中不含金属的再生乙烯基芳香族聚合物的重量百分比为 5 至 15，原生乙烯基芳香族聚合物的重量百分比为 95 至 85。 在一个实施方案中，本发明涉及以阻燃乙烯基芳香族聚合物为基础的组合物，该组合物包括 1 至 30 重量份的阻燃剂、 0.5 至 15 份（按重量计）阻燃助剂、 0 至 2 份（按重量计）防滴剂、 0 至 5 份（按重量计）添加剂、 每 100 份（重量）乙烯基芳香族聚合物混合物中含少量不含金属的再生乙烯基芳香族聚合物。
• Flame resistant styrene based compositions comprising antimony pentoxide
  申请人：Total Petrochemicals Research Feluy

  公开号：EP2354181A1

  公开（公告）日：2011-08-10

  The present invention relates to flame resistant vinyl aromatic polymer based compositions comprising, 1 to 30 parts by weight of a flame retardant, 0.5 to 15 parts by weight of antimony pentoxide as a flame retardant aid, 0.1 to 2 parts by weight of an anti dripping agent, 0 to 5 parts by weight of additives, per 100 parts by weight of the vinyl aromatic polymer.

  本发明涉及以阻燃乙烯基芳香族聚合物为基础的组合物，该组合物包括 1 至 30 份（重量）阻燃剂、 0.5 至 15 份(重量)的五氧化二锑作为阻燃助剂、 0.1 至 2 份（按重量计）防滴剂、 0 至 5 份（按重量计）添加剂、 每 100 份（重量）乙烯基芳香族聚合物中含 0 至 5 份添加剂。