1,3-bis(3-butenyl-1-oxy)benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 1,3-bis(3-butenyl-1-oxy)benzene
• 英文别名: 1,3-Bis(but-3-enoxy)benzene；1,3-bis(but-3-enoxy)benzene
• 化学式: C₁₄H₁₈O₂
• 分子量: 218.296
• InChiKey: FLHTUCHACHEBFH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  硫代乙酸 、 1,3-bis(3-butenyl-1-oxy)benzene 在 偶氮二异丁腈 作用下， 以 乙酸丁酯 为溶剂， 反应 15.0h， 生成
  参考文献：
  名称：

  THIOL COMPOUNDS, SYNTHESIS METHOD THEREFOR, AND UTILIZATION OF SAID THIOL COMPOUNDS

  摘要：

  本发明的目的是提供：新型硫醇化合物；合成该硫醇化合物的方法；含有该硫醇化合物的固化剂；含有该硫醇化合物和环氧化合物的树脂组合物；以及含有该硫醇化合物和分子中含有碳碳双键的烯烃化合物的树脂组合物。此外，本发明的目的是提供将这些树脂组合物作为成分的粘合剂和密封剂。本发明的硫醇化合物由化学式(I)到化学式(VII)表示。

  公开号：

  US20200369606A1
• 作为产物：
  描述：

  丁-3-烯-1-醇,4-甲基苯磺酸 、 间苯二酚 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 以23%的产率得到1,3-bis(3-butenyl-1-oxy)benzene
  参考文献：
  名称：

  Intramolecular Photochemical Reactions of Bichromophoric 3-(Alkenyloxy)phenols and 1-(Alkenyloxy)-3-(alkyloxy)benzene Derivatives. Acid-Catalyzed Transformations of the Primary Cycloadducts

  摘要：

  Irradiation of 3-(alkenyloxy)phenols and 1-(alkenyloxy)-3-(alkyloxy)benzene derivatives, at lambda = 254 nm in acidic media, yields benzocyclobutenes, 3-alkylphenols, 3-alkylanisols, and 4-alkyl-1,2-dialkyloxybenzenes depending on the substitution pattern of the aromatic ring and the olefinic side chain. The final products are derived from an intramolecular [2 + 2] photocycloaddition and acidic rearrangements from a common intermediate.

  DOI：

  10.1021/jo970554t

文献信息

• Oligomers as Intermediates in Ring-Closing Metathesis
  作者：Jay C. Conrad、Melanie D. Eelman、João A. Duarte Silva、Sebastien Monfette、Henrietta H. Parnas、Jennifer L. Snelgrove、Deryn E. Fogg

  DOI：10.1021/ja067531t

  日期：2007.2.1

  Oligomerization is kinetically favored in RCM reactions catalyzed by RuCl2(PCy3)(IMes)(=CHPh), for a range of unhindered , alpha,omega-dienes leading to large or medium-sized rings, even at dilutions designed to minimize intermolecular reaction. Reversible metathesis (i.e., ethenolysis) is inhibited by rapid volatilization of ethylene. At appropriately high dilutions, however, the RCM products are efficiently liberated by backbiting.
• Intramolecular Photochemical Reactions of Bichromophoric 3-(Alkenyloxy)phenols and 1-(Alkenyloxy)-3-(alkyloxy)benzene Derivatives. Acid-Catalyzed Transformations of the Primary Cycloadducts
  作者：Norbert Hoffmann、Jean-Pierre Pete

  DOI：10.1021/jo970554t

  日期：1997.10.1

  Irradiation of 3-(alkenyloxy)phenols and 1-(alkenyloxy)-3-(alkyloxy)benzene derivatives, at lambda = 254 nm in acidic media, yields benzocyclobutenes, 3-alkylphenols, 3-alkylanisols, and 4-alkyl-1,2-dialkyloxybenzenes depending on the substitution pattern of the aromatic ring and the olefinic side chain. The final products are derived from an intramolecular [2 + 2] photocycloaddition and acidic rearrangements from a common intermediate.
• THIOL COMPOUNDS, SYNTHESIS METHOD THEREFOR, AND UTILIZATION OF SAID THIOL COMPOUNDS
  申请人：SHIKOKU CHEMICALS CORPORATION

  公开号：US20200369606A1

  公开（公告）日：2020-11-26

  The purpose of the present invention is to provide: novel thiol compounds; a method for synthesizing said thiol compounds; curing agents containing said thiol compounds; resin compositions containing said thiol compounds and an epoxy compound; and resin compositions containing said thiol compounds and an ene compound having a carbon-carbon double bond in a molecule. Furthermore, the purpose of the present invention is to provide adhesives and sealants having these resin compositions as ingredients. The thiol compounds of the present invention are represented by chemical formula (I) to chemical formula (VII).

  本发明的目的是提供：新型硫醇化合物；合成该硫醇化合物的方法；含有该硫醇化合物的固化剂；含有该硫醇化合物和环氧化合物的树脂组合物；以及含有该硫醇化合物和分子中含有碳碳双键的烯烃化合物的树脂组合物。此外，本发明的目的是提供将这些树脂组合物作为成分的粘合剂和密封剂。本发明的硫醇化合物由化学式(I)到化学式(VII)表示。