1,4-bis(2-chloro-1-propene-3-ylsulfanyl)butane

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 英文名称: 1,4-bis(2-chloro-1-propene-3-ylsulfanyl)butane
• 英文别名: 1,4-Bis(2-chloroprop-2-enylsulfanyl)butane；1,4-bis(2-chloroprop-2-enylsulfanyl)butane
• 化学式: C₁₀H₁₆Cl₂S₂
• 分子量: 271.275
• InChiKey: LJFDQLWQHNNJJR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  14
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,3-二氯丙烯 、 potassium 1,4-butanedithiolate 以32%的产率得到1,4-bis(2-chloro-1-propene-3-ylsulfanyl)butane
  参考文献：
  名称：

  Domino reactions of alkane dithiolates with 2,3-dichloro-1-propene in hydrazine hydrate – KOH medium

  摘要：

  2,3-Dichloro-1-propene reacts with alkane dithiolates in hydrazine hydrate - KOH medium to produce derivatives of dithiin, dithiepin, chloropropenyl, and allenyl sulfides depending on conditions and dithiolate structure. The formation of the heterocyclic products is a result of possible domino reactions, including a substitution of an allylic chlorine atom, dehydrochlorination, and intramolecular heterocyclization.[GRAPHICS].

  DOI：

  10.1080/17415993.2013.849704

文献信息

• Domino reactions of alkane dithiolates with 2,3-dichloro-1-propene in hydrazine hydrate – KOH medium
  作者：Ekaterina P. Levanova、Valentina A. Grabelnykh、Valentina S. Vahrina、Alexander I. Albanov、Lyudmila V. Klyba、Natalia V. Russavskaya、Nikolai A. Korchevin、Igor B. Rozentsveig

  DOI：10.1080/17415993.2013.849704

  日期：2014.3.4

  2,3-Dichloro-1-propene reacts with alkane dithiolates in hydrazine hydrate - KOH medium to produce derivatives of dithiin, dithiepin, chloropropenyl, and allenyl sulfides depending on conditions and dithiolate structure. The formation of the heterocyclic products is a result of possible domino reactions, including a substitution of an allylic chlorine atom, dehydrochlorination, and intramolecular heterocyclization.[GRAPHICS].