dineopentyl 4,4'-biphenyldisulfonate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dineopentyl 4,4'-biphenyldisulfonate
• 英文别名: 2,2-Dimethylpropyl 4-[4-(2,2-dimethylpropoxysulfonyl)phenyl]benzenesulfonate
• 化学式: C₂₂H₃₀O₆S₂
• 分子量: 454.609
• InChiKey: ZMCDFJAHIURPAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  30
• 可旋转键数：
  9
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  104
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  dineopentyl 4,4'-biphenyldisulfonate 、 甲基溴化镁 在 1,2-双(二苯基膦)乙烷氯化镍 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 12.0h， 以84%的产率得到4,4'-二甲基联苯
  参考文献：
  名称：

  镍催化的新戊基芳烃磺酸盐与甲基和伯烷基镁溴化物的交叉偶联

  摘要：

  在dppeNiCl 2存在下，通过新戊氧基氧磺酰基被伯烷基亲核试剂的亲核芳族取代，使新戊基芳烃磺酸盐与甲基和伯烷基溴化镁反应，以高收率生产相应的烷基芳烃。该结果表明，在某些情况下，烷氧基磺酰基可能是卤化物和三氟甲磺酸酯的合适替代物。

  DOI：

  10.1021/jo048300c
• 作为产物：
  描述：

  新戊醇 、 4,4'-联苯二磺酰氯 在 吡啶 作用下， 以 氯仿 为溶剂， 反应 12.0h， 以83%的产率得到dineopentyl 4,4'-biphenyldisulfonate
  参考文献：
  名称：

  镍催化的新戊基芳烃磺酸盐与甲基和伯烷基镁溴化物的交叉偶联

  摘要：

  在dppeNiCl 2存在下，通过新戊氧基氧磺酰基被伯烷基亲核试剂的亲核芳族取代，使新戊基芳烃磺酸盐与甲基和伯烷基溴化镁反应，以高收率生产相应的烷基芳烃。该结果表明，在某些情况下，烷氧基磺酰基可能是卤化物和三氟甲磺酸酯的合适替代物。

  DOI：

  10.1021/jo048300c

文献信息

• TRANSITION METAL COMPLEX AND PROCESS FOR PRODUCING CONJUGATED AROMATIC COMPOUND USING THE TRANSITION METAL COMPLEX
  申请人：Asaumi Taku

  公开号：US20110046336A1

  公开（公告）日：2011-02-24

  A transition metal complex obtained by contacting a bipyridine compound represented by the formula (1): wherein R 1 , R 2 and R 3 represent a C1-C10 alkyl group which may be substituted, etc., and R 4 and R 5 represent a hydrogen atom etc., with a compound of a transition metal belonging to Group 9, 10 or 11, and a process for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of said transition metal complex.

  通过将式（1）所表示的联吡啶化合物与属于9、10或11族的过渡金属化合物接触而获得的过渡金属配合物，其中R1、R2和R3代表C1-C10烷基，可以被取代等，而R4和R5代表氢原子等。制备共轭芳香化合物的方法包括，在所述过渡金属配合物的存在下，将一个芳香化合物（A），其中一个或两个离去基团与芳香环相键合，与具有与上述芳香化合物（A）相同结构的芳香化合物（A）或在结构上不同于上述芳香化合物（A）并且具有一个或两个离去基团与芳香环相键合的芳香化合物（B）反应。
• BIPYRIDINE COMPOUND, TRANSITION METAL COMPLEX, AND METHOD FOR PRODUCTION OF CONJUGATED AROMATIC COMPOUND USING THE TRANSITION METAL COMPLEX
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2172470A1

  公开（公告）日：2010-04-07

  A bipyridine compound represented by the formula (1): wherein R1, R2 and R3 each independently represent a C1-C10 alkyl group which may be substituted etc., and R4, R5, R6, R7 and R8 each independently represent a hydrogen atom etc., a transition metal complex obtained by contacting a bipyridine compound represented by the formula (1) with a compound of a transition metal belonging to Group 9, 10 or 11, and a method for production of a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of the transition metal complex.

  式 (1) 所代表的联吡啶化合物： 其中 R1、R2 和 R3 各自独立地代表可被取代的 C1-C10 烷基等，R4、R5、R6、R7 和 R8 各自独立地代表氢原子等、将式（1）代表的联吡啶化合物与属于第 9、10 或 11 族的过渡金属化合物接触而得到的过渡金属络合物、以及一种生产共轭芳香族化合物的方法，该方法包括在过渡金属络合物存在下，使一个或两个离去基团键合在芳香环上的芳香族化合物(A)与一个结构与上述芳香族化合物(A)相同的芳香族化合物(A)或一个结构不同于上述芳香族化合物(A)且一个或两个离去基团键合在芳香环上的芳香族化合物(B)反应。
• TRANSITION METAL COMPLEX AND PROCESS FOR PRODUCING CONJUGATED AROMATIC COMPOUND WITH THE TRANSITION METAL COMPLEX
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2192124A1

  公开（公告）日：2010-06-02

  A transition metal complex obtained by contacting a bipyridine compound represented by the formula (1): wherein R1, R2 and R3 represent a C1-C10 alkyl group which may be substituted, etc., and R4 and R5 represent a hydrogen atom etc., with a compound of a transition metal belonging to Group 9, 10 or 11, and a process for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of said transition metal complex.

  一种过渡金属配合物，通过与式 (1) 所代表的联吡啶化合物接触而获得： 其中 R1、R2 和 R3 代表可被取代的 C1-C10 烷基等，R4 和 R5 代表氢原子等、一种生产共轭芳香族化合物的工艺，包括在上述过渡金属配合物存在下，将一个或两个离去基团键合在芳香环上的芳香族化合物(A)与结构与上述芳香族化合物(A)相同的芳香族化合物(A)或结构不同于上述芳香族化合物(A)且一个或两个离去基团键合在芳香环上的芳香族化合物(B)反应。
• METHOD FOR PRODUCING CONJUGATED AROMATIC COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2233459A1

  公开（公告）日：2010-09-29

  A method for producing a conjugated aromatic compound comprising reacting an aromatic compound (A) wherein one or two leaving groups are bonded to an aromatic ring with an aromatic compound (A) having the same structure as that of the above-mentioned aromatic compound (A) or an aromatic compound (B) being structurally different from the above-mentioned aromatic compound (A) and having one or two leaving groups bonded to an aromatic ring, in the presence of a nickel compound, a ligand, a manganese salt and a metal reducing agent.

  一种生产共轭芳香族化合物的方法，包括在镍化合物、配体、锰盐和金属还原剂的存在下，使一个或两个离去基团键合在芳香环上的芳香族化合物（A）与结构与上述芳香族化合物（A）相同的芳香族化合物（A）或结构与上述芳香族化合物（A）不同且一个或两个离去基团键合在芳香环上的芳香族化合物（B）反应。
• METHOD FOR MANUFACTURING CONJUGATED AROMATIC COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2390241B1

  公开（公告）日：2014-10-01