trimethyl(4,4,5,5-tetrafluoro-5-(phenylthio)pentyl)silane

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: trimethyl(4,4,5,5-tetrafluoro-5-(phenylthio)pentyl)silane
• 英文别名: Trimethyl-(4,4,5,5-tetrafluoro-5-phenylsulfanylpentyl)silane；trimethyl-(4,4,5,5-tetrafluoro-5-phenylsulfanylpentyl)silane
• 化学式: C₁₄H₂₀F₄SSi
• 分子量: 324.458
• InChiKey: JGQSGARCLWRFRK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.13
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  (2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane 、 烯丙基三甲基硅烷 在 三乙基硼 、 三正丁基氢锡 作用下， 以 正己烷 、 二氯甲烷 为溶剂， 反应 1.25h， 以77%的产率得到trimethyl(4,4,5,5-tetrafluoro-5-(phenylthio)pentyl)silane
  参考文献：
  名称：

  Development of (2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane as tetrafluoroethyl-radical and tetrafluoroethylene-diradical synthons for additions to alkenes

  摘要：

  PhSCF2CF2Br in the presence of tributyltin hydride and substochiometric triethylborane in dichloromethane underwent radical addition to alkenes to give the bromine-free products. Reductive substitution of the phenylsulfanyl group for hydrogen in these adducts provided compounds with the tetrafluoroethyl group. Under the same conditions and in the presence of alkenes, radical addition took place to furnish tetrafluoroethylene-containing alkanes. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2013.07.012

文献信息

• Development of (2-bromo-1,1,2,2-tetrafluoroethyl)(phenyl)sulfane as tetrafluoroethyl-radical and tetrafluoroethylene-diradical synthons for additions to alkenes
  作者：Yana Chernykh、Petr Beier

  DOI：10.1016/j.jfluchem.2013.07.012

  日期：2013.12

  PhSCF2CF2Br in the presence of tributyltin hydride and substochiometric triethylborane in dichloromethane underwent radical addition to alkenes to give the bromine-free products. Reductive substitution of the phenylsulfanyl group for hydrogen in these adducts provided compounds with the tetrafluoroethyl group. Under the same conditions and in the presence of alkenes, radical addition took place to furnish tetrafluoroethylene-containing alkanes. (C) 2013 Elsevier B.V. All rights reserved.