phenanthro[4,5-fgh]pyrido[2,3-b]quinoxaline

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: phenanthro[4,5-fgh]pyrido[2,3-b]quinoxaline
• 英文别名: 3,5,10-Triazahexacyclo[10.10.2.02,11.04,9.016,24.019,23]tetracosa-1(22),2,4(9),5,7,10,12,14,16(24),17,19(23),20-dodecaene；3,5,10-triazahexacyclo[10.10.2.02,11.04,9.016,24.019,23]tetracosa-1(22),2,4(9),5,7,10,12,14,16(24),17,19(23),20-dodecaene
• 化学式: C₂₁H₁₁N₃
• 分子量: 305.338
• InChiKey: ZTQNTGZBCZWWHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  phenanthro[4,5-fgh]pyrido[2,3-b]quinoxaline 、 2,4-二硝基苯胺 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Discrimination in excimer emission quenching of pyrene by nitroaromatics

  摘要：

  Quenching of excimer emission of proximate pyrene units of phenanthro[4,5-fgh]pyrido[2,3-6]quinoxaline allows the detection and discrimination of the electron deficient potentially explosive nitroaromatics, and thus could be used to screen the suspected samples, in security related applications. The detection proceeds through a quenching mechanism, which has been explained on the basis of steady state fluorescence and life-time measurements. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2015.03.053

文献信息

• Discrimination in excimer emission quenching of pyrene by nitroaromatics
  作者：Priya Singla、Paramjit Kaur、Kamaljit Singh

  DOI：10.1016/j.tetlet.2015.03.053

  日期：2015.4

  Quenching of excimer emission of proximate pyrene units of phenanthro[4,5-fgh]pyrido[2,3-6]quinoxaline allows the detection and discrimination of the electron deficient potentially explosive nitroaromatics, and thus could be used to screen the suspected samples, in security related applications. The detection proceeds through a quenching mechanism, which has been explained on the basis of steady state fluorescence and life-time measurements. (C) 2015 Elsevier Ltd. All rights reserved.