3-(3,5-di-methylphenoxy)-2-hydroxypropyl methacrylate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3-(3,5-di-methylphenoxy)-2-hydroxypropyl methacrylate
• 英文别名: 3,5-Di-methylphenoxy-2-hydroxypropyl methacrylate；[3-(3,5-dimethylphenoxy)-2-hydroxypropyl] 2-methylprop-2-enoate
• 化学式: C₁₅H₂₀O₄
• 分子量: 264.321
• InChiKey: KJEMFLVKAKROMV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  19
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-[(3,5-二甲基苯氧基)甲基]环氧乙烷 、 甲基丙烯酸 在 2,6-二叔丁基-4-甲基苯酚 、 三乙胺 作用下， 反应 36.0h， 以75%的产率得到3-(3,5-di-methylphenoxy)-2-hydroxypropyl methacrylate
  参考文献：
  名称：

  Carbamate-methacrylate monomers and their use in dental applications

  摘要：

  本发明涉及含有氨基甲酸酯-甲基丙烯酸酯或氨基甲酸酯-甲基丙烯酸酯衍生物的单体，制备该单体的方法以及包含该单体的组合物。本发明还涉及使用该单体的方法，例如在牙科应用中，特别是在牙科修复树脂中的应用。

  公开号：

  US08513326B2

文献信息

• CARBAMATE-METHACRYLATE MONOMERS AND THEIR USE IN DENTAL APPLICATIONS
  申请人：Trujillo-Lemon Marianela

  公开号：US20100307378A1

  公开（公告）日：2010-12-09

  The present invention relates, generally, to monomers containing carbamate-methacrylates or derivatives of carbamate-methacrylates, processes for making the monomers, and compositions comprising the monomers. The present invention also relates to methods of using the monomers, such as in dental applications, and in particular, dental restorative resins.

  本发明涉及含有碳酸酯-甲基丙烯酸酯或碳酸酯-甲基丙烯酸酯衍生物的单体，制备该单体的方法以及包含该单体的组合物。本发明还涉及使用该单体的方法，例如在牙科应用中，特别是在牙科修复树脂中的应用。
• Dimer Acid-Derived Dimethacrylates and Use in Dental Restorative Compositions
  申请人：Stansbury Jeffrey W.

  公开号：US20080318188A1

  公开（公告）日：2008-12-25

  The present invention provides polymerizable dental compositions comprising a dimer acid-derived monomer such as a dimer acid-derived di(meth)acrylate monomer. In one embodiment, the dimer acid-derived monomer is of the formula (I): wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are independently selected from H and optionally substituted C 1 -C 25 straight-chained or branched aliphatic, optionally containing 1 or more double or triple bonds, wherein one or more carbons are optionally replaced by R* wherein R* is —C(O)—, —C(O)C(O)—, —C(O)NR 7 —, —C(O)NR 7 NR 8 —, —C(O)O—, —OC(O)—, —NR 7 CO 2 —, —O—, —NR 7 C(O)NR 8 —, —OC(O)NR 7 —, —NR 7 NR 8 —, —NR 7 C(O)—, —NR 7 C(O)O—, —S—, —SO—, —SO 2 —, —NR 7 —, —SO 2 NR 7 — or —NR 7 SO 2 —, where R 7 and R 8 are independently selected from H and optionally substituted aliphatic, cycloalkyl, heterocycloalkyl, aryl or heteroaryl; provided that at least two of R 1 , R 2 , R 3 , R 4 , R 5 and R 6 are substituted C 1-25 straight-chained or branched aliphatic wherein at least one carbon is replaced by R* and at least one of the substituents is an alkenyl group.
• US8513326B2
  申请人：——

  公开号：US8513326B2

  公开（公告）日：2013-08-20
• US8727775B2
  申请人：——

  公开号：US8727775B2

  公开（公告）日：2014-05-20
• [EN] CARBAMATE-METHACRYLATE MONOMERS AND THEIR USE IN DENTAL APPLICATIONS<br/>[FR] MONOMÈRES DE CARBAMATE-MÉTHACRYLATE ET LEUR UTILISATION DANS DES APPLICATIONS DENTAIRES
  申请人：SEPTODONT CONFI DENTAL DIVISIO

  公开号：WO2010042818A1

  公开（公告）日：2010-04-15

  The present invention relates, generally, to monomers containing carbamate- methacryiates or derivatives of carbamate-methacrylates, processes for making the monomers, and compositions comprising the monomers The present invention also relates to methods of using the monomers, such as in dental applications, and m particular, dental restorative resins.