4-decyl-N-(4-(octyloxy)benzylidene)aniline

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 4-decyl-N-(4-(octyloxy)benzylidene)aniline
• 英文别名: N-(4-decylphenyl)-1-(4-octoxyphenyl)methanimine
• 化学式: C₃₁H₄₇NO
• 分子量: 449.72
• InChiKey: LUDIZVSAMNNNHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.7
• 重原子数：
  33
• 可旋转键数：
  19
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  21.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  pentacarbonyl(methyl)manganese(I) 、 4-decyl-N-(4-(octyloxy)benzylidene)aniline 以 甲苯 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Synthesis and characterisation of rod-like metallomesogens of Mn(I) based on Schiff base ligands

  摘要：

  Complexation of liquid-crystalline imines to Mn(I) carbonyls led to liquid-crystalline complexes when the ligated imine was sufficiently anisotropic. Thus, all two-ring and some three-ring imine ligands were not mesomorphic when complexed, while some three-ring and all four-ring imines led to mesomorphic complexes. As expected, complexation disturbed the anisotropy of the ligands and led to a lowering of clearing points and a suppression of smectic phase formation. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00437-3
• 作为产物：
  描述：

  2,4-二硝基苯甲醛 、 4-辛氧基苯甲醛 、 4-癸基苯胺 、 2,4-二甲氧基苯胺 以 甲苯 为溶剂， 70.0~140.0 ℃ 、13.33 Pa 条件下， 反应 24.0h， 以98%的产率得到N-(2,4-dinitrobenzylidene)-2,4-dimethoxyaniline
  参考文献：
  名称：

  蒸馏过程中动态胺库的自选

  摘要：

  保持简单：n醛与n胺的反应生成[ n × n ]亚胺的动态库。库的缓慢蒸馏会放大最易挥发的亚胺，从而从所有其他库组分中提取出最易挥发的醛和胺。该过程的反复重复使动态库可以自动分类为n个机械分离的亚胺，这些亚胺以高收率获得。

  DOI：

  10.1002/anie.201102813

文献信息

• Self-Sorting of Dynamic Imine Libraries during Distillation
  作者：Karolina Osowska、Ognjen Š. Miljanić

  DOI：10.1002/anie.201102813

  日期：2011.8.29

  reaction of n aldehydes with n amines leads to a dynamic library of [n×n] imines. Slow distillation of the library amplifies the most volatile imine, whereby the most volatile aldehyde and amine are extracted from all other library components. Iterative repetition of the process enabled the self‐sorting of the dynamic library into n mechanically separated imines, which were obtained in high yield.

  保持简单：n醛与n胺的反应生成[ n × n ]亚胺的动态库。库的缓慢蒸馏会放大最易挥发的亚胺，从而从所有其他库组分中提取出最易挥发的醛和胺。该过程的反复重复使动态库可以自动分类为n个机械分离的亚胺，这些亚胺以高收率获得。
• Synthesis and characterisation of rod-like metallomesogens of Mn(I) based on Schiff base ligands
  作者：Xiao-Hua Liu、M. Nurul Abser、Duncan W. Bruce

  DOI：10.1016/s0022-328x(97)00437-3

  日期：1998.1

  Complexation of liquid-crystalline imines to Mn(I) carbonyls led to liquid-crystalline complexes when the ligated imine was sufficiently anisotropic. Thus, all two-ring and some three-ring imine ligands were not mesomorphic when complexed, while some three-ring and all four-ring imines led to mesomorphic complexes. As expected, complexation disturbed the anisotropy of the ligands and led to a lowering of clearing points and a suppression of smectic phase formation. (C) 1998 Elsevier Science S.A.