trifluoromethoxy phenylallene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: trifluoromethoxy phenylallene
• 英文别名: 1-Propadienyl-4-(trifluoromethoxy)benzene
• 化学式: C₁₀H₇F₃O
• 分子量: 200.16
• InChiKey: LSGOESYPXQJFNN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.5
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  trifluoromethoxy phenylallene 以46%的产率得到
  参考文献：
  名称：

  Yamamoto Yoshinori, Al-Masum Mohammad, Fujiwara Naoya, Asao Naoki, Tetrahedron Lett, 36 (1995) N 16, S 2811-2814

  摘要：

  DOI：

文献信息

• The two component palladium catalyst system for intermolecular hydroamination of allenes
  作者：Mohammad Al-Masum、Masaki Meguro、Yoshinori Yamamoto

  DOI：10.1016/s0040-4039(97)01370-1

  日期：1997.8

  The combination of acetic acid with Pd-2(dba)(3).CHCl3 and dppf [1.1(1)-Bis(diphenylphosphino ferrocene)] is a new type of catalytic system, capable of effecting the addition of protected and/or functionalized amines to allenes with high regio- and stereoselectivity. (C) 1997 Elsevier Science Ltd.
• Remarkable reversal of the regioselectivity in the palladium catalyzed hydrocarbonation reaction of allenes with methylmalononitrile
  作者：Yoshinori Yamamoto、Mohammad Al-Masum、Naoya Fujiwara、Naoki Asao

  DOI：10.1016/0040-4039(95)00403-y

  日期：1995.4

  The palladium catalyzed addition of methylmalononitrile 4a to arylallenes 3 affords the internal adducts 5 and 6 either predominantly or exclusively when an electron-withdrawing group is present at the para-position, whereas it gives the terminal adduct 7 exclusively when an electron-donating group is present at the para-position.