2,4-diethylocten-2-ol

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2,4-diethylocten-2-ol
• 英文别名: 2,4-diethyloct-2-en-1-ol；2,4-Diethyloct-2-en-1-ol
• 化学式: C₁₂H₂₄O
• 分子量: 184.322
• InChiKey: HRXJVGRDUFYZAI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2,4-diethylocten-2-al 在 氢气 作用下， 以 异丙醇 为溶剂， 150.0 ℃ 、6.9 MPa 条件下， 反应 4.0h， 生成 2-乙基己醇 、 2,4-二乙基辛醇 、 2,4-diethylocten-2-ol
  参考文献：
  名称：

  BRANCHED TRIALKYLAMINE PRECURSORS, INTERMEDIATES, PRODUCTS MADE THEREFROM AND PROCESSES OF MANUFACTURE

  摘要：

  这项发明提供了支链疏水基团，用于生产具有比线性疏水基团更好性能的表面活性剂。该发明还提供了支链C10-12 烯醛和醛，它们被氧化为支链脂肪酸或氢化为支链脂肪醇，并进一步通过乙氧基化或酯化等反应或随后的反应衍生为表面活性剂。该发明还提供了由支链三烷基胺中间体制备的表面活性剂，包括两性离子、阳离子和非离子表面活性剂。

  公开号：

  US20190218170A1

文献信息

• Branched trialkyl quaternary ammonium compounds
  申请人：Eastman Chemical Company

  公开号：US10640452B2

  公开（公告）日：2020-05-05

  The surfactants which can be produced from the trialkylamine intermediates include the quaternary ammonium compounds of formula:

  可以用三烷基胺中间体生产的表面活性剂包括式中的季铵盐化合物：
• Branched trialkyl amine oxides
  申请人：Eastman Chemical Company

  公开号：US10961180B2

  公开（公告）日：2021-03-30

  The invention provides branched trialkylamine oxides with improved properties. The trialkylamine oxides of the invention produced from branched trialkylamines, in one embodiment, can be made using certain branched C10-12 enals and aldehydes. The invention also provides an trialkylamine oxide having the formula: wherein R5, R6 and R7 are independently at least one of C3H7, C2H5, CH3, or H, or mixtures thereof; and wherein R5 and R6 are not H at the same time. In one embodiment, the trialkylamine oxides of the invention can be useful in making various products, for example, as surfactants.

  本发明提供了性能更好的支链三烷基胺氧化物。由支链三烷基胺生产的本发明三烷基胺氧化物，在一个实施方案中，可以使用某些支链 C10-12 烯和醛来制造。本发明还提供了一种具有以下式子的三烷基氧化胺： 其中R5、R6和R7独立地至少是C3H7、C2H5、CH3或H中的一种，或它们的混合物；并且其中R5和R6不是同时为H。在一个实施方案中，本发明的三烷基胺氧化物可用于制造各种产品，例如用作表面活性剂。
• Vanin; Krut-skii; Krut-skaya, Journal of applied chemistry of the USSR, 1986, vol. 59, # 2 pt 2, p. 428 - 430
  作者：Vanin、Krut-skii、Krut-skaya、Safiulina、Korneva

  DOI：——

  日期：——
• BRANCHED TRIALKYL AMINE OXIDES
  申请人：Eastman Chemical Company

  公开号：US20190218169A1

  公开（公告）日：2019-07-18

  The invention provides branched trialkylamine oxides with improved properties. The trialkylamine oxides of the invention produced from branched trialkylamines, in one embodiment, can be made using certain branched C10-12 enals and aldehydes. The invention also provides an trialkylamine oxide having the formula: wherein R5, R6 and R7 are independently at least one of C3H7, C2H5, CH3, or H, or mixtures thereof; and wherein R5 and R6 are not H at the same time. In one embodiment, the trialkylamine oxides of the invention can be useful in making various products, for example, as surfactants.
• BRANCHED TRIALKYL QUATERNARY AMMONIUM COMPOUNDS
  申请人：Eastman Chemical Company

  公开号：US20190218171A1

  公开（公告）日：2019-07-18

  The invention provides branched hydrophobes for the production of surfactants with improved properties over linear hydrophobes. The invention also provides branched C 10-12 enals and aldehydes. The invention additionally provides branched C 10-12 enals and aldehydes that are oxidized to branched fatty acids or hydrogenated to branched fatty alcohols and further derivatized to surfactants, through ethoxylation or esterification and other or subsequent reactions. The enals and aldehydes are useful in making branched trialkylamine intermediates useful in making certain surfactants, including amphoteric, cationic and nonionic surfactants. The surfactants which can be produced from the trialkylamine intermediates include the quaternary ammonium compounds of the invention. The quaternary ammonium compounds of the invention are also useful in making the branched enals and/or aldehydes useful in the invention.