dl-2-Methyllaurinsaeureamid

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: dl-2-Methyllaurinsaeureamid
• 英文别名: 2-Methyl-dodecansaeureamid；2-Methyldodecanamide；(+/-)-2-Methyl-dodecanamid
• 化学式: C₁₃H₂₇NO
• 分子量: 213.363
• InChiKey: ZCSPGETUPZSUOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 ammonium hydroxide 、 草酰氯 、 苯 作用下， 生成 dl-2-Methyllaurinsaeureamid
  参考文献：
  名称：

  Staellberg-Stenhagen, Arkiv foer Kemi, 1947, vol. 23 A, # 15, p. 8

  摘要：

  DOI：

文献信息

• Palladium-catalyzed regiodivergent hydroaminocarbonylation of alkenes to primary amides with ammonium chloride
  作者：Bao Gao、Guoying Zhang、Xibing Zhou、Hanmin Huang

  DOI：10.1039/c7sc04054g

  日期：——

  the synthesis of primary amides has long been an elusive aim. Here, we report an efficient catalytic system which enables inexpensive NH4Cl to be utilized as a practical alternative to gaseous ammonia for the palladium-catalyzed alkene-hydroaminocarbonylation reaction. Through appropriate choice of the palladium precursors and ligands, either branched or linear primary amides can be obtained in good

  钯催化烯烃的氢氨基羰基化合成伯酰胺长期以来一直是一个难以实现的目标。在这里，我们报道了一种高效的催化系统，该系统能够利用廉价的 NH 4 Cl 作为气态氨的实际替代品，用于钯催化的烯烃-氢氨基羰基化反应。通过适当选择钯前体和配体，可以以良好的产率获得支链或直链伯酰胺，并具有良好至优异的区域选择性。进行了初步机理研究并揭示了亲电子酰基钯物质能够在 CO 存在下以 NMP 作为碱捕获铵盐中的 NH 2 -部分以形成酰胺。
• AMINONITRILE PRODUCTION
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP1062200A1

  公开（公告）日：2000-12-27
• Agroformulation comprising copolymer of acrylic acid, poly(alkylene glycol) (meth)acrylate, and alkyl (meth)acrylate
  申请人：BASF SE

  公开号：US20150126363A1

  公开（公告）日：2015-05-07

  The present invention provides a composition comprising a pesticide and a copolymer, which contains in polymerized form acrylic acid and/or methacrylic acid (monomer A); a mono C 12 -C 22 alkyl terminated poly(C 2- 6 alkylene glycol)(meth)acrylate (monomer B); and a C 1 -C 8 alkyl(meth)acrylate (monomer C). Further on, it provides a process for preparing said composition by contacting the pesticide and the copolymer; a method for controlling phytopathogenic fungi and/or unwanted plant growth and/or unwanted insect or mite infestation and/or for regulating the growth of plants, wherein said composition is caused to act on the respective pests, their habitat or the plants to be protected from the respective pest, to the soil and/or to unwanted plants and/or the crop plants and/or their habitat; and a plant propagation material comprising said composition.
• US4747967A
  申请人：——

  公开号：US4747967A

  公开（公告）日：1988-05-31
• US9374996B2
  申请人：——

  公开号：US9374996B2

  公开（公告）日：2016-06-28