N¹,N²-bis(4-ethoxyphenyl)-1,2-diphenylethane-1,2-diimine

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: N¹,N²-bis(4-ethoxyphenyl)-1,2-diphenylethane-1,2-diimine
• 英文别名: N,N'-bis(4-ethoxyphenyl)-1,2-diphenylethane-1,2-diimine
• 化学式: C₃₀H₂₈N₂O₂
• 分子量: 448.565
• InChiKey: ZBUIQIDDWPPEHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.3
• 重原子数：
  34
• 可旋转键数：
  9
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  43.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N¹,N²-bis(4-ethoxyphenyl)-1,2-diphenylethane-1,2-diimine 在 二甲基亚砜 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 65.08h， 生成 bis[1,3-bis(4-ethoxyphenyl)-4,5-diphenyl-1,3-dihydro-2H-imidazol-2-yliden]mercury(II) dichloride
  参考文献：
  名称：

  Synthesis of Highly Substituted 2-13C-Imidazolium Salts and Metal NHC ­Complexes for the Investigation of Electronic Unsymmetry by NMR

  摘要：

  Complexes of unsymmetrically substituted N-heterocyclic carbenes with NMR-active metals (Ag, Hg, Pt) with or without a C-13-label in the 2-position were synthesized by aldimine cross coupling and analyzed with respect to the scalar couplings between the metal center or C2 and the other ring atoms.

  DOI：

  10.1055/s-0033-1338496
• 作为产物：
  描述：

  对乙氧基苯胺 、 联苯甲酰 以 1,2-二氯乙烷 为溶剂， 反应 72.0h， 以66%的产率得到N¹,N²-bis(4-ethoxyphenyl)-1,2-diphenylethane-1,2-diimine
  参考文献：
  名称：

  Synthesis of Highly Substituted 2-13C-Imidazolium Salts and Metal NHC ­Complexes for the Investigation of Electronic Unsymmetry by NMR

  摘要：

  Complexes of unsymmetrically substituted N-heterocyclic carbenes with NMR-active metals (Ag, Hg, Pt) with or without a C-13-label in the 2-position were synthesized by aldimine cross coupling and analyzed with respect to the scalar couplings between the metal center or C2 and the other ring atoms.

  DOI：

  10.1055/s-0033-1338496

文献信息

• Synthesis of Highly Substituted 2-13C-Imidazolium Salts and Metal NHC ­Complexes for the Investigation of Electronic Unsymmetry by NMR
  作者：Till Opatz、Jens Emsermann、Anthony Arduengo

  DOI：10.1055/s-0033-1338496

  日期：——

  Complexes of unsymmetrically substituted N-heterocyclic carbenes with NMR-active metals (Ag, Hg, Pt) with or without a C-13-label in the 2-position were synthesized by aldimine cross coupling and analyzed with respect to the scalar couplings between the metal center or C2 and the other ring atoms.