1,4-bis(4-vinylbenzylamino) anthraquinone

• 分子结构分类: 有机化合物 - 苯类化合物 - 蒽
• 英文名称: 1,4-bis(4-vinylbenzylamino) anthraquinone
• 英文别名: 1,4-bis(4-vinylbenzylamino)-anthraquinone；1,4-bis[(4-ethenylphenyl)methylamino]anthracene-9,10-dione
• 化学式: C₃₂H₂₆N₂O₂
• 分子量: 470.571
• InChiKey: TYRRSVCFVDQEFQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  36
• 可旋转键数：
  8
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  58.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2,6-二甲基吡啶 、 4-氯甲基苯乙烯 、 1,4-二氨基蒽醌 以 水 、 乙腈 为溶剂， 以60%的产率得到1,4-bis(4-vinylbenzylamino) anthraquinone
  参考文献：
  名称：

  Reactive dyes and lenses utilizing the same

  摘要：

  公开号：

  EP0799864B1

文献信息

• SILICONE HYDROGEL SOFT CONTACT LENS HAVING WETTABLE SURFACE
  申请人：HOYA CORPORATION

  公开号：EP2840431A1

  公开（公告）日：2015-02-25

  Provided is a silicone hydrogel soft contact lens obtained by curing in a double-sided casting mold, a liquid mixture including glycerol mono(meth)acrylate and at least one type of silicone monomer having at least one hydroxyl group or polyethylene glycol group in the molecular structure thereof, the silicone hydrogel soft contact lens having a wettable surface without a polymerized lens-shaped material being subjected to post-processing to improve the water wetting properties of a surface thereof.

  本发明提供了一种硅水凝胶软性隐形眼镜，该隐形眼镜通过在双面浇铸模具中固化一种液体混合物而获得，该液体混合物包括甘油单（甲基）丙烯酸酯和至少一种在其分子结构中具有至少一个羟基或聚乙二醇基团的硅树脂单体，该硅水凝胶软性隐形眼镜具有可润湿的表面，无需对聚合镜片形状材料进行后处理以改善其表面的水润湿性能。
• METHOD FOR PRODUCING SILICONE-CONTAINING COPOLYMER MOLDED ARTICLE HAVING HYDROPHILIC SURFACE, AND SILICONE HYDROGEL CONTACT LENS HAVING HYDROPHILIC SURFACE
  申请人：HOYA Corporation

  公开号：EP2845708A1

  公开（公告）日：2015-03-11

  The present invention provides a method permitting the fabrication of a silicone-containing copolymer molded article having a hydrophilic surface by means of the cast molding method and without employing a high-molecular-weight hydrophilic polymer even when employing a polypropylene mold. Provide is a method for fabricating a silicone-containing copolymer molded article having a hydrophilic surface by polymerizing a monomer solution containing (a) a silicone monomer comprising a (meth)acryloyl group; (b) a hydrophilic monomer comprising a vinyl group; (c) a crosslinkable monomer; and (d) a polymerization initiator in a cavity of a mold having a hydrophobic cavity surface. The polymerization initiator has a 10-hour half-life temperature (T10) of 70°C or higher and 100°C or lower, and the polymerization is conducted by means of a step P1 of maintaining a temperature within a range of from the T10 of the polymerization initiator contained in the monomer solution to 35°C below T10 for one hour or more; and a step P2 of maintaining a temperature higher than the T10 of the polymerization initiator contained in the monomer solution for one hour or more.

  本发明提供了一种方法，可通过浇注成型法制造具有亲水性表面的含硅共聚物模制件，即使使用聚丙烯模具，也无需使用高分子量亲水性聚合物。本发明提供了一种制造具有亲水表面的含硅共聚物模塑制品的方法，该方法是在具有疏水型腔表面的模具型腔中聚合单体溶液，该单体溶液含有：(a) 含有(甲基)丙烯酰基的硅树脂单体；(b) 含有乙烯基的亲水单体；(c) 可交联单体；以及 (d) 聚合引发剂。聚合引发剂的10小时半衰期温度(T10)为70℃或更高，100℃或更低，聚合通过以下步骤进行：步骤P1，将温度保持在单体溶液中所含聚合引发剂的T10至低于T10的35℃的范围内一小时或更长时间；步骤P2，将温度保持在高于单体溶液中所含聚合引发剂的T10一小时或更长时间。
• Silicone hydrogel contact lens having hydrophilic surface
  申请人：HOYA CORPORATION

  公开号：EP2926967A1

  公开（公告）日：2015-10-07

  The present invention provides a silicone-containing copolymer molded article having a hydrophilic surface by means of the cast molding method and without employing a high-molecular-weight hydrophilic polymer even when employing a polypropylene mold. The silicone-containing copolymer molded article having a hydrophilic surface is prepared by polymerizing a monomer solution containing (a) a silicone monomer comprising a (meth)acryloyl group; (b) a hydrophilic monomer comprising a vinyl group; (c) a crosslinkable monomer; and (d) a polymerization initiator in a cavity of a mold having a hydrophobic cavity surface. The polymerization initiator has a 10-hour half-life temperature (T10) of 70 °C or higher and 100°C or lower, and the polymerization is conducted by means of a step P1 of maintaining a temperature within a range of from the T10 of the polymerization initiator contained in the monomer solution to 35°C below T10 for one hour or more; and a step P2 of maintaining a temperature higher than the T10 of the polymerization initiator contained in the monomer solution for one hour or more.

  本发明提供了一种含硅共聚物模制品，该模制品通过浇注成型法，即使使用聚丙烯模具，也无需使用高分子量亲水聚合物，即可获得具有亲水性表面的模制品。制备具有亲水性表面的含硅共聚物模塑制品的方法是，在具有疏水性模腔表面的模具模腔中聚合单体溶液，该单体溶液含有：(a) 含有(甲基丙烯酰基)的有机硅单体；(b) 含有乙烯基的亲水单体；(c) 可交联单体；以及 (d) 聚合引发剂。聚合引发剂的10小时半衰期温度(T10)为70℃或更高，100℃或更低，聚合是通过以下步骤进行的：步骤P1，将温度保持在单体溶液中所含聚合引发剂的T10至低于T10的35℃的范围内一小时或更长时间；步骤P2，将温度保持在高于单体溶液中所含聚合引发剂的T10的范围内一小时或更长时间。
• Silicone hydrogel soft contact lens having wettable surface
  申请人：HOYA CORPORATION

  公开号：US10241234B2

  公开（公告）日：2019-03-26

  Provided is a silicone hydrogel soft contact lens obtained by curing in a double-sided casting mold, a liquid mixture including glycerol mono(meth)acrylate and at least one type of silicone monomer having at least one hydroxyl group or polyethylene glycol group in the molecular structure thereof, the silicone hydrogel soft contact lens having a wettable surface without a polymerized lens-shaped material being subjected to post-processing to improve the water wetting properties of a surface thereof.

  本发明提供了一种硅水凝胶软性隐形眼镜，该隐形眼镜通过在双面浇铸模具中固化一种液体混合物而获得，该液体混合物包括甘油单（甲基）丙烯酸酯和至少一种在其分子结构中具有至少一个羟基或聚乙二醇基团的硅树脂单体，该硅水凝胶软性隐形眼镜具有可润湿的表面，无需对聚合镜片形状材料进行后处理以改善其表面的水润湿性能。
• Materials for contact lenses comprising a macromer having the polysiloxane structure in the side chain
  申请人：HOYA HEALTHCARE CORPORATION

  公开号：EP1128191B1

  公开（公告）日：2005-04-20