十三烷酸异丙酯 | 28267-30-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 十三烷酸异丙酯
• 中文别名: 15-羟基二十烷酸
• 英文名称: isopropyl tridecanoate
• 英文别名: propan-2-yl tridecanoate
• CAS: 28267-30-3
• 化学式: C₁₆H₃₂O₂
• 分子量: 256.429
• InChiKey: CZYGEVQQOCNIML-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.6
• 重原子数：
  18
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.94
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-十二烯十二碳烯α-十二碳烯α-十二碳烯 、 异丙醇 在 bis-triphenylphosphine-palladium(II) chloride 、 四丁基溴化铵 、 水 、 对甲苯磺酸 作用下， 110.0 ℃ 、3.0 MPa 条件下， 反应 2.0h， 生成 isopropyl 2-propyldecanoate 、 isopropyl 2-ethylundecanoate 、 isopropyl 2-methyldodecanoate 、 十三烷酸异丙酯
  参考文献：
  名称：

  Manufacture of C13 higher fatty acids from their esters by carbonylation of dodecene-1 in ionic liquid medium

  摘要：

  The effect of catalyst nature, temperature, acidity, promoters, and feedstock composition on dodecene-1 carbonylation in the presence of Pd compounds in an ionic liquid medium yielding higher fatty acid and their esters was studied. Palladium salts without phosphine ligands show high activity in tetrabutylammonium bromide. In systems of this kind, the catalyst is suspended in the reaction mass in the form of Pd particles with a size of 4-10 nm. It was shown that the catalytic system can be repeatedly used without loss of activity. It is acceptable to use synthesis gas instead of bare carbon monoxide with the selectivity for tride-canoic acid increasing.

  DOI：

  10.1134/s096554411006006x

文献信息

• Cooling product
  申请人：SYMRISE AG

  公开号：US11491091B2

  公开（公告）日：2022-11-08

  There are provided herein cosmetic and sanitary products comprising physiologic cooling compounds, selected 1,2-alkanediols, and tensides and/or UV filters.

  本文提供的化妆品和卫生用品包含生理性冷却化合物、精选的 1,2-烷二醇、硒化物和/或紫外线过滤剂。
• TRANSDERMAL ABSORPTION PREPARATION
  申请人：FUJIFILM Toyama Chemical Co., Ltd.

  公开号：EP2623102B1

  公开（公告）日：2019-01-09
• COOLING PRODUCT
  申请人：SYMRISE AG

  公开号：US20190099342A1

  公开（公告）日：2019-04-04

  Suggested are cosmetic and sanitary products comprising physiologic cooling compounds, selected 1,2-alkanediols, and tensides and/or UV filters.
• US7829373B2
  申请人：——

  公开号：US7829373B2

  公开（公告）日：2010-11-09
• Manufacture of C13 higher fatty acids from their esters by carbonylation of dodecene-1 in ionic liquid medium
  作者：A. L. Lapidus、O. L. Eliseev、T. N. Bondarenko、N. H. Chau

  DOI：10.1134/s096554411006006x

  日期：2010.11

  The effect of catalyst nature, temperature, acidity, promoters, and feedstock composition on dodecene-1 carbonylation in the presence of Pd compounds in an ionic liquid medium yielding higher fatty acid and their esters was studied. Palladium salts without phosphine ligands show high activity in tetrabutylammonium bromide. In systems of this kind, the catalyst is suspended in the reaction mass in the form of Pd particles with a size of 4-10 nm. It was shown that the catalytic system can be repeatedly used without loss of activity. It is acceptable to use synthesis gas instead of bare carbon monoxide with the selectivity for tride-canoic acid increasing.