ammonium bismuth citrate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: ammonium bismuth citrate
• 英文别名: bismuth ammonium citrate；Bismuth;azane;3-carboxy-3-hydroxypentanedioate
• 化学式: Bi*2C₆H₅O₇*3H₄N
• 分子量: 641.299
• InChiKey: QSBNOZODKXUXSP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -5.26
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  142
• 氢给体数：
  2
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  ammonium bismuth citrate 、 水 在 sodium hydrate or nitric acid 、 Sb₂O₃ 作用下， 以 not given 为溶剂， 生成 bismuth(III) oxide
  参考文献：
  名称：

  A facile hydrothermal method to BiSbO4 nanoplates with superior photocatalytic performance for benzene and 4-chlorophenol degradations

  摘要：

  成功通过简单的水热反应从Sb2O3和Bi(NO3)3制备了具有大比表面积的BiSbO4纳米片。研究了反应条件和前体对最终产物的影响。提出Sb2O3和Bi(NO3)3之间的氧化还原反应在纳米晶BiSbO4的形成中起着关键作用。通过X射线衍射（XRD）、氮气吸附BET表面积、紫外-可见漫反射光谱（DRS）、X射线光电子能谱（XPS）、扫描电子显微镜（SEM）、透射电子显微镜（TEM）和高分辨率透射电子显微镜（HRTEM）对水热制备的纳米晶BiSbO4进行了表征。DRS结果表明，BiSbO4最初被认为是可见光响应的光催化剂，但实际上是对紫外光响应的，带隙为3.5 eV。Bi的存在可能是通过常规固态反应制备的BiSbO4对可见光响应的原因。与通过固态反应和Degussa P25制备的BiSbO4相比，通过水热法制备的BiSbO4（Hy）纳米片表现出更优越的光催化性能，能够降解苯和4-氯酚（4-CP）。BiSbO4（Hy）纳米片可能成为治理环境污染的有前景的光催化剂。

  DOI：

  10.1039/c1dt10130g

文献信息

• Accelerated separation of photogenerated charge carriers and enhanced photocatalytic performance of g-C3N4 by Bi2S3 nanoparticles
  作者：Qiang Hao、Ci'an Xie、Yongming Huang、Daimei Chen、Yiwen Liu、Wei Wei、Bing-Jie Ni

  DOI：10.1016/s1872-2067(19)63450-9

  日期：2020.2

  Employing photothermal conversion to improve the photocatalytic activity of g-C3N4 is rarely re-Received 1 July 2019 ported previously. Herein, different ratios of g-C3N4/Bi2S3 heterojunction materials are synthesized Accepted 12 July 2019 by a facile ultrasonic method. Advanced characterizations such as X-ray diffraction, Fourier trans-Published 5 February 2020 form infrared spectroscopy, X-ray photoelectron spectroscopy and high-resolution transmission electron microscopy are employed to analyze the morphology and structure of the prepared materials. Compared with sole counterparts, the heterojunction materials CN-BiS-2 exhibit significantly enhanced photocatalytic performance, which is 2.05-fold as g-C3N4 and 4.42-fold as Bi2S3. A possible degradation pathway of methylene blue (MB) was proposed. Based on the photoproduced high-energy electrons and photothermal effect of Bi2S3, the transfer and separation of electron-hole pairs are greatly enhanced and more active species are produced. In addition, the relatively high utilization efficiency of solar energy has synergistic effect for the better photocatalytic performance. (C) 2020, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
• A facile hydrothermal method to BiSbO4 nanoplates with superior photocatalytic performance for benzene and 4-chlorophenol degradations
  作者：Qingqing You、Yanghe Fu、Zhengxin Ding、Ling Wu、Xuxu Wang、Zhaohui Li

  DOI：10.1039/c1dt10130g

  日期：——

  BiSbO4 nanoplates with a large BET specific area has been prepared successfully via a facile hydrothermal reaction from Sb2O3 and Bi(NO3)3. The effects of reaction conditions and the precursors on the final products were investigated. It is proposed that the redox reaction between Sb2O3 and Bi(NO3)3 plays a pivotal role in the formation of nanocrystalline BiSbO4. The hydrothermally prepared nanocrystalline BiSbO4 was characterized by X-ray diffraction (XRD), N2-sorption BET surface area, UV-vis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). The DRS result clarifies that BiSbO4, originally believed to be a visible light responsive photocatalyst, is indeed UV light responsive with a band gap of 3.5 eV. The existence of Bi containing an impurity may be responsible for the visible light response of BiSbO4 prepared via a conventional solid state reaction. BiSbO4 nanoplates prepared via the hydrothermal method showed superior photocatalytic performance for the degradation of benzene and 4-chlorophenol (4-CP) as compared to BiSbO4 prepared via a solid state reaction and Degussa P25. BiSbO4(Hy) nanoplates can be a promising photocatalyst in the treatment of environmental pollution.

  成功通过简单的水热反应从Sb2O3和Bi(NO3)3制备了具有大比表面积的BiSbO4纳米片。研究了反应条件和前体对最终产物的影响。提出Sb2O3和Bi(NO3)3之间的氧化还原反应在纳米晶BiSbO4的形成中起着关键作用。通过X射线衍射（XRD）、氮气吸附BET表面积、紫外-可见漫反射光谱（DRS）、X射线光电子能谱（XPS）、扫描电子显微镜（SEM）、透射电子显微镜（TEM）和高分辨率透射电子显微镜（HRTEM）对水热制备的纳米晶BiSbO4进行了表征。DRS结果表明，BiSbO4最初被认为是可见光响应的光催化剂，但实际上是对紫外光响应的，带隙为3.5 eV。Bi的存在可能是通过常规固态反应制备的BiSbO4对可见光响应的原因。与通过固态反应和Degussa P25制备的BiSbO4相比，通过水热法制备的BiSbO4（Hy）纳米片表现出更优越的光催化性能，能够降解苯和4-氯酚（4-CP）。BiSbO4（Hy）纳米片可能成为治理环境污染的有前景的光催化剂。