十二酸乙烯酯与乙酸乙烯酯的聚合物 | 26354-30-3

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 十二酸乙烯酯与乙酸乙烯酯的聚合物
• 英文名称: Ethenyl acetate;ethenyl dodecanoate
• CAS: 26354-30-3
• 化学式: C18H32O4
• 分子量: 312.4
• InChiKey: UXAYDBNWIBJTRO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.29
• 重原子数：
  22
• 可旋转键数：
  14
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• MULTILAYER CATALYST FOR PREPARING PHTHALIC ANHYDRIDE AND PROCESS FOR PREPARING PHTHALIC ANHYDRIDE
  申请人：Altwasser Stefan

  公开号：US20120004425A1

  公开（公告）日：2012-01-05

  The present invention relates to a multilayer catalyst for preparing phthalic anhydride which has a plurality of catalyst layers arranged in succession in the reaction tube, with the individual catalyst layers having alkali metal contents which decrease in the flow direction. The present invention further relates to a process for the oxidation of naphthalene or o-xylene/naphthalene mixtures over such a multilayer catalyst and the use of such multilayer catalysts for the oxidation of naphthalene or o-xylene/naphthalene mixtures to phthalic anhydride.

  本发明涉及一种多层催化剂，用于制备邻苯二甲酸酐，其在反应管中依次排列有多个催化剂层，各个催化剂层在流动方向上具有递减的碱金属含量。本发明还涉及一种在这种多层催化剂上氧化萘或邻二甲苯/萘混合物的工艺，以及使用这种多层催化剂氧化萘或邻二甲苯/萘混合物制备邻苯二甲酸酐。
• Catalytic Converter Arrangement with Optimized Surface for Producing Phthalic Anhydride
  申请人：Clariant International Ltd.

  公开号：US20170044125A1

  公开（公告）日：2017-02-16

  A catalytic converter arrangement for producing phthalic anhydride by means of a gas phase oxidation of aromatic hydrocarbons, comprising a reactor with a gas inlet side for a reactant gas, a gas outlet side for a product gas, a first catalytic converter layer made of catalytic converter elements, and at least one second catalytic converter layer made of catalytic converter elements. The first catalytic converter layer is arranged on the gas inlet side, and the second catalytic converter layer is arranged downstream of the first catalytic converter layer in the gas flow direction. The catalytic converter elements have an outer layer of an active compound. The invention is characterized in that the active compound content in the first catalytic converter layer and/or in the second catalytic converter layer is below 7 wt. %, based on the total weight of the catalytic converter elements, and the ratio of the total surface of the active compound to the volume of the catalytic converter layer is preferably 10000 cm−1 to 20000 cm−1, in each catalytic converter layer.

  一种催化转化器排列，用于通过芳香族碳氢化合物的气相氧化来生产邻苯二甲酸酐，包括一个反应器，具有一个反应气体的进气侧，一个产物气体的出气侧，一个由催化转化器元件制成的第一催化转化器层，以及至少一个由催化转化器元件制成的第二催化转化器层。第一催化转化器层位于进气侧，第二催化转化器层位于气流方向下游的位置。催化转化器元件具有一个活性化合物的外层。该发明的特点在于，第一催化转化器层和/或第二催化转化器层中的活性化合物含量低于催化转化器元件总重量的7wt.％，并且每个催化转化器层中活性化合物的总表面积与催化转化器层的体积的比例优选为10000cm−1至20000cm−1。
• Catalyst Arrangement With Optimized Void Fraction For The Production Of Phthalic Acid Anhydride
  申请人：CLARIANT INTERNATIONAL LTD

  公开号：US20170320803A1

  公开（公告）日：2017-11-09

  The invention relates to a catalyst arrangement for preparing phthalic anhydride by gas-phase oxidation of aromatic hydrocarbons, which comprises a reactor having a gas inlet end for a feed gas and a gas outlet end for a product gas and also a first catalyst zone made up of catalyst bodies and at least one second catalyst zone made up of catalyst bodies, where the first catalyst zone is arranged at the gas inlet end and the second catalyst zone is arranged downstream of the first catalyst zone in the gas flow direction and the length of the first catalyst zone in the gas flow direction is less than the length of the second catalyst zone in the gas flow direction, characterized in that the first catalyst zone has a higher gap content compared to the second catalyst zone.

  本发明涉及一种用于通过芳香烃的气相氧化制备邻苯二甲酸酐的催化剂排列，包括一个反应器，其具有用于进料气体的气体进口端和用于产物气体的气体出口端，以及由催化剂体组成的第一催化剂区和至少一个由催化剂体组成的第二催化剂区，其中第一催化剂区位于气体进口端，第二催化剂区位于气体流动方向下游的第一催化剂区，并且第一催化剂区在气体流动方向上的长度小于第二催化剂区在气体流动方向上的长度，其特征在于第一催化剂区具有比第二催化剂区更高的间隙含量。
• CATALYST FOR THE OXIDATION OF O-XYLENE AND/OR NAPHTHALENE TO PHTHALIC ANHYDRIDE
  申请人：Altwasser Stefan

  公开号：US20120029214A1

  公开（公告）日：2012-02-02

  The present invention relates to a catalyst for the oxidation of o-xylene and/or naphthalene to phthalic anhydride, which has a plurality of catalyst zones which are arranged in series in the reaction tube and have been produced using an antimony trioxide which comprises a significant proportion of valentinite. The present invention further relates to a process for gas-phase oxidation, in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst produced using an antimony trioxide which comprises a significant proportion of valentinite.

  本发明涉及一种用于将o-二甲苯和/或萘氧化为邻苯二甲酸酐的催化剂，其具有一系列催化剂区域，这些区域在反应管中串联排列，并使用含有相当比例的针铅矿的三氧化二锑制备而成。本发明还涉及一种气相氧化过程，其中通过使用含有相当比例的针铅矿的三氧化二锑制备的催化剂，将至少含有一种碳氢化合物和分子氧的气流通过。
• Crosslinked branched polyesters
  申请人：Eastman Chemical Company

  公开号：US20030032764A1

  公开（公告）日：2003-02-13

  A gum base comprising a crosslinked branched polyester gel prepared from the process comprising: a) providing a first pre-gel composition having carboxyl end groups; b) providing a second pre-gel composition having hydroxyl end groups; c) removing either or both of the first and second pre-gel compositions from their respective reactors; d) combining the first and second pre-gel compositions to form a mixture; and e) processing the mixture in an extruder, a continuous processor, or a container thereby providing a crosslinked branched polyester gel.

  一种口香糖基料，包括交联分支聚酯凝胶，其制备过程包括：a）提供具有羧基末端基团的第一预凝胶组合物；b）提供具有羟基末端基团的第二预凝胶组合物；c）将第一和/或第二预凝胶组合物从各自的反应器中取出；d）将第一和第二预凝胶组合物混合形成混合物；e）在挤出机、连续处理器或容器中处理混合物，从而提供交联分支聚酯凝胶。