bis[4-(m-aminophenoxy)phenyl]phenylphosphine oxide

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis[4-(m-aminophenoxy)phenyl]phenylphosphine oxide
• 英文别名: bis[4-(3-aminophenoxy)phenyl]phenylphosphine oxide；Bis[4-(3-aminophenoxy)phenyl] phenylphosphine oxide；3-[4-[[4-(3-aminophenoxy)phenyl]-phenylphosphoryl]phenoxy]aniline
• 化学式: C₃₀H₂₅N₂O₃P
• 分子量: 492.514
• InChiKey: DRPVTEDJZSZGSY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  36
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  87.6
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  二(4-氟苯基)苯基氧化膦 、 3-氨基苯酚 在 N,N-二甲基乙酰胺 、 potassium carbonate 作用下， 以 甲苯 为溶剂， 生成 bis[4-(m-aminophenoxy)phenyl]phenylphosphine oxide
  参考文献：
  名称：

  单体类型对共聚酰亚胺和共聚酰亚胺-二氧化硅杂化材料性能的结构影响

  摘要：

  在这项工作中，研究了两种不同的含氧化膦的二胺单体对共聚酰亚胺及其杂化材料的热，机械和形态性能的影响。还分析了合成的共聚酰亚胺的气体分离性能。含有氧化膦的两种不同的二胺单体是双（3-氨基苯基）苯基氧化膦（BAPPO）和双[4-（3-氨基苯氧基）苯基）苯基氧化膦（m-BAPPO）。在共聚酰亚胺的合成中，3,3'-二氨基二苯砜（3,3'-DDS）也用作二胺，以及2,2-双（3,4-二羧基苯基）六氟丙烷二酐（6FDA）。通过热酰亚胺化制备共聚酰亚胺膜。此外，通过溶胶-凝胶技术合成了含5％SiO 2的杂化材料。傅里叶变换红外光谱（FTIR）和核磁共振光谱（NMR）确认了预期的结构。动态力学分析（DMA）表明，基于m -BAPPO的共聚酰亚胺具有比基于BAPPO的共聚酰亚胺更低的玻璃化转变温度（T g）。将不含二氧化硅的含m -BAPPO的共聚酰亚胺的热分解温度移至更高的值。含BAPPO二胺的共聚酰亚胺及其杂化物的模量和强度值高于含m

  DOI：

  10.2298/jsc141014029k

文献信息

• PROCESS FOR MAKING BENZOXAZINES
  申请人：Cytec Industries Inc.

  公开号：US20160115139A1

  公开（公告）日：2016-04-28

  A synthesis process for making a benzoxazine compound containing at least one benzoxazine unit from aromatic amine containing at least one primary amino group, at least one phenolic compound with at least one ortho-hydrogen, and alkyl formcel. In one embodiment, the aromatic amine is reacted with alkyl formcel to generate an alkoxymethyl intermediate compound. Subsequently, the intermediate compound is reacted with a phenol to generate the benzoxazine compound. In another embodiment, the benzoxazine compound is formed by reacting aromatic amine with alkyl formcel and phenol in one reaction step. Also disclosed is a method for isolating the alkoxymethyl compound formed by reacting aromatic amine with alkyl formcel. The isolated alkoxymethyl compound is useful as a reactant in a subsequent reaction.

  一种合成过程，用于从含有至少一个苯并噁嗪单元的芳香胺，至少含有一个一级氨基的芳香胺，至少含有一个邻位氢的酚类化合物和烷基甲醛制备含有至少一个苯并噁嗪单元的苯并噁嗪化合物。在一种实施方式中，将芳香胺与烷基甲醛反应以生成烷氧甲基中间体化合物。随后，将中间体化合物与酚反应以生成苯并噁嗪化合物。在另一种实施方式中，通过在一个反应步骤中将芳香胺与烷基甲醛和酚反应来形成苯并噁嗪化合物。还公开了一种方法，用于分离由芳香胺与烷基甲醛反应形成的烷氧甲基化合物。分离的烷氧甲基化合物可用作随后反应中的反应物。
• BENZOXAZINE-BASED MONOMER FOR THERMOSETTING RESINS
  申请人：Cytec Industries Inc.

  公开号：EP3456709A1

  公开（公告）日：2019-03-20

  A benzoxazine monomer of formula (A) useful to prepare thermosetting resins.

  式 (A) 的苯并恶嗪单体 可用于制备热固性树脂。
• Fire retardant materials and devices including same
  申请人：THE BOARD OF REGENTS OF THE NEVADA SYSTEM OF HIGHER EDUCATION on behalf of THE UNIVERSITY OF NEVADA, LAS VEGAS

  公开号：US10240090B2

  公开（公告）日：2019-03-26

  This disclosure provides fire retardant materials, including polymers that include at least one pyridinium salt moiety and at least one phosphine oxide moiety. In some cases, fire retardant polymers provided herein have the following structure:

  本公开提供的阻燃材料包括包含至少一个吡啶鎓盐分子和至少一个氧化膦分子的聚合物。在某些情况下，本文提供的阻燃聚合物具有以下结构：
• Process for making benzoxazines
  申请人：CYTEC INDUSTRIES INC.

  公开号：US10227313B2

  公开（公告）日：2019-03-12

  A synthesis process for making a benzoxazine compound containing at least one benzoxazine unit from aromatic amine containing at least one primary amino group, at least one phenolic compound with at least one ortho-hydrogen, and alkyl formcel. In one embodiment, the aromatic amine is reacted with alkyl formcel to generate an alkoxymethyl intermediate compound. Subsequently, the intermediate compound is reacted with a phenol to generate the benzoxazine compound. In another embodiment, the benzoxazine compound is formed by reacting aromatic amine with alkyl formcel and phenol in one reaction step. Also disclosed is a method for isolating the alkoxymethyl compound formed by reacting aromatic amine with alkyl formcel. The isolated alkoxymethyl compound is useful as a reactant in a subsequent reaction.

  一种用含有至少一个伯氨基的芳香胺、至少一种含有至少一个正交氢的酚类化合物和甲酰烷基醚制取含有至少一个苯并恶嗪单元的苯并恶嗪化合物的合成工艺。在一个实施方案中，芳香胺与甲缩醛烷基酯反应生成烷氧基甲基中间化合物。随后，中间化合物与苯酚反应生成苯并恶嗪化合物。在另一个实施方案中，苯并恶嗪化合物是通过芳香胺与烷基甲缩醛和苯酚在一个反应步骤中反应生成的。还公开了一种分离芳香胺与烷基甲缩醛反应生成的烷氧基甲基化合物的方法。分离出的烷氧基甲基化合物可用作后续反应的反应物。
• FIRE RETARDANT MATERIALS AND DEVICES INCLUDING SAME
  申请人：THE BOARD OF REGENTS OF THE NEVADA SYSTEM OF HIGHE EDUCATION on behalf of THE UNIVERSITY OF NEVADA

  公开号：US20170298278A1

  公开（公告）日：2017-10-19

  This disclosure provides fire retardant materials, including polymers that include at least one pyridinium salt moiety and at least one phosphine oxide moiety. In some cases, fire retardant polymers provided herein have the following structure: