(+/-)-2-methylsulfanyl-2-methylsulfinyl-1-indanone

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: (+/-)-2-methylsulfanyl-2-methylsulfinyl-1-indanone
• 英文别名: 2-methylsulfanyl-2-methylsulfinyl-3H-inden-1-one
• 化学式: C₁₁H₁₂O₂S₂
• 分子量: 240.347
• InChiKey: DHCHKSKELDTRSL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  78.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-(methylthio)-1-indanone 在 苄基三乙基氯化铵 selenium(IV) oxide 、 双氧水 、 potassium carbonate 作用下， 以 二氯甲烷 、 苯 为溶剂， 生成 (+/-)-2-methylsulfanyl-2-methylsulfinyl-1-indanone
  参考文献：
  名称：

  Phase Transfer Catalysis (PTC) Sulfanylation of Some 2-Methylsulfinyl-Cyclanones

  摘要：

  The sulfanylation reactions of 2-methylsulfinylated cyclopentanone, 1-indanone, and cyclohexanone by a PTC procedure are reported and the yields and diastereoselectivity compared to those obtained by the homogeneousphase method. The stability of the sulfanylated methylsulfinyl derivatives at room temperature versus the instability of the p-tolylsulfinyl derivatives is also reported.

  DOI：

  10.1021/jo048751x

文献信息

• Phase Transfer Catalysis (PTC) Sulfanylation of Some 2-Methylsulfinyl-Cyclanones
  作者：Blanka Wladislaw、Mauro Alves Bueno、Liliana Marzorati、Claudio Di Vitta、Júlio Zukerman-Schpector

  DOI：10.1021/jo048751x

  日期：2004.12.1

  The sulfanylation reactions of 2-methylsulfinylated cyclopentanone, 1-indanone, and cyclohexanone by a PTC procedure are reported and the yields and diastereoselectivity compared to those obtained by the homogeneousphase method. The stability of the sulfanylated methylsulfinyl derivatives at room temperature versus the instability of the p-tolylsulfinyl derivatives is also reported.