2-propylnaphthalene-1-amine

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-propylnaphthalene-1-amine
• 英文别名: 2-propyl-[1]naphthylamine；2-Propyl-[1]naphthylamin；2-Propyl-1-naphthylamin；2-Propylnaphthalen-1-amine
• 化学式: C₁₃H₁₅N
• 分子量: 185.269
• InChiKey: JKALBFKYSGMPLZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-propylnaphthalene-1-amine 、 1,2-二溴苯 在 palladium diacetate 、 R-(+)-1,1'-联萘-2,2'-双二苯膦 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 24.0h， 以48%的产率得到N-(2-bromophenyl)-2-propylnaphthalen-1-amine
  参考文献：
  名称：

  Garcia-Fortanet, Jorge; Kessler, Florian; Buchwald, Stephen L., Journal of the American Chemical Society, 2009, vol. 131, p. 6676 - 6677

  摘要：

  DOI：
• 作为产物：
  描述：

  1-(2-萘基)丙-1-酮 在 sodium hydroxide 、 硝酸 、 铁粉 、 一水合肼 、 溶剂黄146 、 二乙二醇 作用下， 反应 2.0h， 生成 2-propylnaphthalene-1-amine
  参考文献：
  名称：

  Belcher et al., Journal of the Chemical Society, 1958, p. 3243,3246

  摘要：

  DOI：

文献信息

• The relation between the Claisen rearrangement of allyl ethers and their electronic structure
  作者：S. Marcinkiewicz、J. Green、P. Mamalis

  DOI：10.1016/s0040-4020(01)92170-2

  日期：1961.1

  The kinetics of a number of Claisen rearrangements have been studied and it is shown that the energy of activation of this reaction is a function of the bond orders and free valencies in the ethers undergoing rearrangement. In accordance with prediction from the derived equation, it was shown that N-allyl-1-naphthylamine rearranged smoothly and in high yield to 2-allyl-1-naphthylamine by a first order

  已经研究了许多克莱森重排的动力学，并且表明该反应的活化能是进行重排的醚中键序和自由价的函数。根据推导方程的预测，表明N-烯丙基-1-萘胺通过一阶分子内机理平稳且高产率地重排为2-烯丙基-1-萘胺。这是N-烯丙基化合物的克莱森重排的第一个记录例子。根据这些发现讨论了其他醚的行为，其在文献中的重排已被记录为异常或异常。
• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• [EN] PHOSPHINYL FORMAMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS PHOSPHINYL FORMAMIDINE, COMPLEXES MÉTALLIQUES, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2015094207A1

  公开（公告）日：2015-06-25

  N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are described. Methods for making N2-phosphinyl formamidine compounds and N2-phosphinyl formamidine metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl formamidine metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds and N2- phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物。还公开了制备N2-磷酰基甲酰胺化合物和N2-磷酰基甲酰胺金属盐配合物的方法。还公开了利用N2-磷酰基甲酰胺金属盐配合物的催化剂体系，以及利用N2-磷酰基胺化合物和N2-磷酰基胺金属盐配合物进行烯烃的寡聚和/或聚合的用途。
• IMIDE COMPOUND, METHOD FOR PRODUCING SAME, THICKENING AGENT FOR GREASE, AND GREASE COMPOSITION
  申请人：JX Nippon Oil & Energy Corporation

  公开号：EP2662378A1

  公开（公告）日：2013-11-13

  The present invention provides an imide compound represented by the following general formula (1). The imide compound of the present invention, particularly when used as a thickening agent for grease, is excellent in durability at high temperatures. [wherein X represents a tetravalent residue obtained by removing four carboxylic groups from an aromatic tetracarboxylic acid, Y represents a divalent residue obtained by removing two amino groups from an aliphatic diamine or an aromatic diamine, and R represents a residue obtained by removing an amino group from an aliphatic monoamine, an alicyclic monoamine, or an aromatic monoamine.]

  本发明提供了一种由以下通式（1）表示的酰亚胺化合物。本发明的亚胺化合物，特别是用作润滑脂的增稠剂时，在高温下具有优异的耐久性。 [其中 X 代表通过从芳香族四羧酸中去除四个羧基而得到的四价残基，Y 代表通过从脂肪族二胺或芳香族二胺中去除两个氨基而得到的二价残基，R 代表通过从脂肪族一胺、脂环族一胺或芳香族一胺中去除一个氨基而得到的残基。］
• Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins
  申请人：Chevron Phillips Chemical Company LP

  公开号：US10144752B2

  公开（公告）日：2018-12-04

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物。还公开了制造 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的方法。还公开了利用 N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物的催化剂体系，以及 N2-膦酰基脒化合物、N2-膦酰基脒、N2-膦酰基脒金属盐络合物和 N2-膦酰基脒金属盐络合物在烯烃的低聚和/或聚合中的用途。