3H-carbazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3H-carbazole
• 化学式: C₁₂H₉N
• 分子量: 167.21
• InChiKey: YWYHKRGWAKXZRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  12.4
• 氢给体数：
  0
• 氢受体数：
  1

文献信息

• [EN] NOVEL ORGANIC ELECTROLUMINESCENCE COMPOUNDS AND ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THE SAME<br/>[FR] NOUVEAUX COMPOSÉS ORGANIQUES ÉLECTROLUMINESCENTS ET DISPOSITIF ORGANIQUE ÉLECTROLUMINESCENT COMPRENANT LESDITS COMPOSÉS
  申请人：ROHM & HAAS ELECT MAT

  公开号：WO2013073859A1

  公开（公告）日：2013-05-23

  The present invention relates to novel organic electroluminescence compounds and an organic electroluminescence device comprising the same. The organic electroluminescence compound according to the present invention has an advantage of manufacturing an OLED device having long operating lifespan due to its high luminous efficiency compared with conventional materials, and having reduced power consumption induced by improved power efficiency.

  本发明涉及新型有机电致发光化合物以及包括该化合物的有机电致发光装置。根据本发明的有机电致发光化合物具有制造具有长寿命的OLED装置的优点，因为与传统材料相比，其具有较高的发光效率，并且由于改善的功率效率而减少了由此引起的功耗。
• [EN] CARBAZOLE-BASED GUMBOS FOR HIGHLY EFFICIENT BLUE OLEDS<br/>[FR] GROUPE DE SUBSTANCES UNIFORMES À BASE DE SELS ORGANIQUES (GUMBOS) À BASE DE CARBAZOLE POUR DIODES ÉLECTROLUMINESCENTES ORGANIQUES (DELO) BLEUES HAUTEMENT EFFICACES
  申请人：UNIV LOUISIANA STATE

  公开号：WO2016112027A1

  公开（公告）日：2016-07-14

  Various examples are provided for carbazole-based GUMBOS (group of uniform materials based on organic salts), and its application in organic light emitting diodes (OLEDs). In one example, a composition includes a solid phase carbazole-based GUMBOS (group of uniform materials based on organic salts) comprising a counterion such as, e.g., trifluoromethanesulfonate ([OTf]), bis-(trifluoromethanesulfonyl)imide ([NTf2]), bis-(pentafluoroethylsulfonyl)imide ([BETI]), tetrafluoroborate (BF4), hexafluorophosphate (PF6), and/or thiocyanate (SCN). The carbazole-based GUMBOS can include carbazoleimidazole-based GUMBOS or 3,6-diBDC carbazolium-based GUMBOS. In another example, a method includes preparing a biphasic solution; separating a layer of DCM from the biphasic solution after stirring; washing the DCM with water to remove byproducts; and evaporating the DCM to form a solid phase carbazoleimidazole-based GUMBOS. Preparing the biphasic solution can include carbazoleimidazolium iodide (CM) dissolved in dichloromethane (DCM) and a dissolved salt including a sodium salt or a lithium salt.

  提供了关于基于咔唑的GUMBOS（基于有机盐的均匀材料组）的各种示例，以及其在有机发光二极管（OLEDs）中的应用。在一个示例中，一种组合物包括固相咔唑基GUMBOS（基于有机盐的均匀材料组），其中包括诸如三氟甲磺酸盐（[OTf]）、双（三氟甲磺酰）亚胺盐（[NTf2]）、双（五氟乙磺酰）亚胺盐（[BETI]）、四氟硼酸盐（BF4）、六氟磷酸盐（PF6）和/或硫氰酸盐（SCN）等对离子。基于咔唑的GUMBOS可以包括咔唑咪唑基GUMBOS或3,6-二BDC咔唑基GUMBOS。在另一个示例中，一种方法包括制备两相溶液；搅拌后从两相溶液中分离DCM层；用水洗涤DCM以去除副产物；并蒸发DCM以形成固相咔唑咪唑基GUMBOS。制备两相溶液可以包括咔唑咪唑盐（CM）溶解在二氯甲烷（DCM）中以及溶解的盐，包括钠盐或锂盐。
• HETEROCYCLIC COMPOUND FOR USE IN ELECTRONIC DEVICES
  申请人：Merck Patent GmbH

  公开号：US20210363159A1

  公开（公告）日：2021-11-25

  The present invention relates to heterocyclic compounds, especially for use in electronic devices. The invention further relates to a process for preparing the compounds of the invention and to electronic devices comprising these.

  本发明涉及杂环化合物，特别是用于电子设备。该发明还涉及制备本发明化合物的方法以及包含这些化合物的电子设备。
• COMPOUNDS WITH ARYLAMINE STRUCTURES
  申请人：Merck Patent GmbH

  公开号：US20200048207A1

  公开（公告）日：2020-02-13

  The present invention describes arylamine derivatives which are substituted by diazanaphthalene groups, in particular for use in electronic devices. The invention furthermore relates to a process for the preparation of the compounds according to the invention and to electronic devices containing same.

  本发明描述了被二氮萘基团取代的芳胺衍生物，特别适用于电子设备。该发明还涉及根据本发明制备化合物的方法以及含有这些化合物的电子设备。
• COMPOUNDS WITH SPIROBIFLUORENE-STRUCTURES
  申请人：Merck Patent GmbH

  公开号：US20190106391A1

  公开（公告）日：2019-04-11

  The present invention describes spirobifluorene derivatives substituted by pyridine and/or pyrimidine groups, especially for use in electronic devices. The invention further relates to a process for preparing the compounds of the invention and to electronic devices comprising these.

  本发明描述了由吡啶和/或嘧啶基团取代的螺环联苯衍生物，特别适用于电子器件。该发明还涉及制备本发明化合物的方法以及包含这些化合物的电子器件。