10-(5-(tributylstannyl)thiophen-2-yl)-10H-phenothiazine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 10-(5-(tributylstannyl)thiophen-2-yl)-10H-phenothiazine
• 英文别名: Tributyl-(5-phenothiazin-10-ylthiophen-2-yl)stannane；tributyl-(5-phenothiazin-10-ylthiophen-2-yl)stannane
• 化学式: C₂₈H₃₇NS₂Sn
• 分子量: 570.45
• InChiKey: CYMRTSRMCLIYMV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.96
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  56.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-溴噻吩 、 10-(5-(tributylstannyl)thiophen-2-yl)-10H-phenothiazine 在 四(三苯基膦)钯 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 8.0h， 以62%的产率得到5-(N-phenothiazino)-2,2'-bithiophene
  参考文献：
  名称：

  Preparation and Characterization of α,α‘-Bisdiarylamino-Capped Oligothiophenes

  摘要：

  A series of alpha,alpha'-bisdiarylamino-capped oligothiophenes C-n were prepared by the palladium-catalyzed reaction of the dibromo compounds A(i) with diarylamines, N,N-diarylamino-substituted thiophenes or 2,2'-bithiophenes BXj These easily oxidizable compounds exhibit a high tendency to form amorphous glasses and characteristic electrochemical and spectroscopic properties that depend significantly on the number of their thiophene moieties.

  DOI：

  10.1021/ol034322u
• 作为产物：
  描述：

  三丁基氯化锡 、 2-(N-phenothiazinyl)thiophene 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 8.0h， 以2 g的产率得到10-(5-(tributylstannyl)thiophen-2-yl)-10H-phenothiazine
  参考文献：
  名称：

  COMPOUND AND FILM AND PHOTOELECTRIC DIODE AND ORGANIC SENSOR AND ELECTRONIC DEVICE

  摘要：

  本文揭示了一种化学式1所代表的化合物，一种薄膜，一种光电二极管，一种有机传感器和一种电子设备。在化学式1中，X1、X2、Y1、Y2、Ar、L1、L2、R1、R4和n的定义与规范中相同。

  公开号：

  US20200136063A1

文献信息

• NEAR-INFRARED ABSORBERS, NEAR-INFRARED ABSORBING/BLOCKING FILMS, PHOTOELECTRIC DEVICES, ORGANIC SENSORS, AND ELECTRONIC DEVICES
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20210083199A1

  公开（公告）日：2021-03-18

  A near-infrared absorber includes a compound represented by Chemical Formula 1. A near-infrared absorbing/blocking film, a photoelectric device, an organic sensor, and an electronic device may include the near-infrared absorber. In Chemical Formula 1, X 1 , X 2 , Y 1 , Y 2 , Ar, Ar 1 , and Ar 2 are the same as defined in the detailed description.

  一种近红外吸收剂包括化学式1所表示的化合物。一种近红外吸收/阻挡膜、光电器件、有机传感器和电子器件可能包括该近红外吸收剂。在化学式1中，X1、X2、Y1、Y2、Ar、Ar1和Ar2的定义与详细描述中定义的相同。
• Preparation and Characterization of α,α‘-Bisdiarylamino-Capped Oligothiophenes
  作者：Ahcene Tabet、Anke Schröder、Horst Hartmann、Dirk Rohde、Lothar Dunsch

  DOI：10.1021/ol034322u

  日期：2003.5.1

  A series of alpha,alpha'-bisdiarylamino-capped oligothiophenes C-n were prepared by the palladium-catalyzed reaction of the dibromo compounds A(i) with diarylamines, N,N-diarylamino-substituted thiophenes or 2,2'-bithiophenes BXj These easily oxidizable compounds exhibit a high tendency to form amorphous glasses and characteristic electrochemical and spectroscopic properties that depend significantly on the number of their thiophene moieties.
• COMPOUND AND FILM AND PHOTOELECTRIC DIODE AND ORGANIC SENSOR AND ELECTRONIC DEVICE
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20200136063A1

  公开（公告）日：2020-04-30

  Disclosed are a compound represented by Chemical Formula 1, a film, a photoelectric diode, an organic sensor, and an electronic device. In Chemical Formula 1, X 1 , X 2 , Y 1 , Y 2 , Ar, L 1 , L 2 , R 1 , R 4 , and n are the same as defined in the specification.

  本文揭示了一种化学式1所代表的化合物，一种薄膜，一种光电二极管，一种有机传感器和一种电子设备。在化学式1中，X1、X2、Y1、Y2、Ar、L1、L2、R1、R4和n的定义与规范中相同。