3,4,5-tri(tridecyloxy)benzene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3,4,5-tri(tridecyloxy)benzene
• 英文别名: 1,2,3-Tri(tridecoxy)benzene；1,2,3-tri(tridecoxy)benzene
• 化学式: C₄₅H₈₄O₃
• 分子量: 673.16
• InChiKey: SMTDHGVVOLGPAQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.2
• 重原子数：
  48
• 可旋转键数：
  39
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.87
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1-iodotridecane 、 邻苯三酚 在 sodium hydroxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以65%的产率得到3,4,5-tri(tridecyloxy)benzene
  参考文献：
  名称：

  Mesomorphic Dithiooxamide Complexes of Platinum(II)

  摘要：

  Complexation of non-mesomorphic dithiooxamide ligands to Pt(II) leads to square planar complexes which exhibit mesomorphic properties. The synthesis of these complexes was accomplished in three steps: the formation of bisamides, starting from conveniently substituted anilines, their conversion into dithiooxamides and the reaction of these sulfur derivatives with [PtCl2(dmso)(2)]. Four, eight and twelve-chained complexes were obtained and their behaviour as potentially mesomorphic material was studied. The eight-chained complexes 21 (n = 12-16) and the twelve-chained complexes 22 (n = 8,11,13) exhibit columnar mesophases which have been characterised by optical microscopy, X-ray scattering and related miscibility studies.

  DOI：

  10.1080/10587250008024795

文献信息

• Mesomorphic Dithiooxamide Complexes of Platinum(II)
  作者：Maria Chiara Aversa、Paola Bonaccorsi、Duncan W. Bruce、Francesco Caruso、Bertrand Donnio、Placido Giannetto、Daniel Guillon、Santo Lanza、Stefania Morrone

  DOI：10.1080/10587250008024795

  日期：2000.8.1

  Complexation of non-mesomorphic dithiooxamide ligands to Pt(II) leads to square planar complexes which exhibit mesomorphic properties. The synthesis of these complexes was accomplished in three steps: the formation of bisamides, starting from conveniently substituted anilines, their conversion into dithiooxamides and the reaction of these sulfur derivatives with [PtCl2(dmso)(2)]. Four, eight and twelve-chained complexes were obtained and their behaviour as potentially mesomorphic material was studied. The eight-chained complexes 21 (n = 12-16) and the twelve-chained complexes 22 (n = 8,11,13) exhibit columnar mesophases which have been characterised by optical microscopy, X-ray scattering and related miscibility studies.