copper;2-methoxy-6-[(E)-[(2-oxidobenzoyl)hydrazinylidene]methyl]phenolate;hydrate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: copper;2-methoxy-6-[(E)-[(2-oxidobenzoyl)hydrazinylidene]methyl]phenolate;hydrate
• 化学式: C₁₅H₁₄CuN₂O₅
• 分子量: 365.833
• InChiKey: GGLVYDZDUVWOKA-NENXIMLWSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.22
• 重原子数：
  23
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  97.8
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  2-hydroxy-N'-(2-hydroxy-3-methoxybenzylidene)benzohydrazide 、 copper(II) acetate monohydrate 以 乙醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 以70%的产率得到copper;2-methoxy-6-[(E)-[(2-oxidobenzoyl)hydrazinylidene]methyl]phenolate;hydrate
  参考文献：
  名称：

  NMR and Other Physicochemical Studies of o-Vanillin and Isovanillin Salicyloylhydrazones and Their Metal Complexes

  摘要：

  Cobalt(II), nickel(II) and copper (II) complexes of (o) under bar-vanillin and isovanillin salicyloylhydrazones have been synthesised. These compounds were characterised by elemental analyses, IR, magnetic, thermal and diffuse reflectance spectra. The salicyloylhydrazones have been further characterised by H-1 NMR. Force constants of the major bonds, M-O and M-N have also been calculated.

  DOI：

  10.1080/00945719608004335

文献信息

• NMR and Other Physicochemical Studies of o-Vanillin and Isovanillin Salicyloylhydrazones and Their Metal Complexes
  作者：Vanita Puri、B. V. Agarwala

  DOI：10.1080/00945719608004335

  日期：1996.5

  Cobalt(II), nickel(II) and copper (II) complexes of (o) under bar-vanillin and isovanillin salicyloylhydrazones have been synthesised. These compounds were characterised by elemental analyses, IR, magnetic, thermal and diffuse reflectance spectra. The salicyloylhydrazones have been further characterised by H-1 NMR. Force constants of the major bonds, M-O and M-N have also been calculated.