N-(2-{Bis-[2-(2-methyl-acryloylamino)-ethyl]-amino}-ethyl)-2-methyl-acrylamide

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: N-(2-{Bis-[2-(2-methyl-acryloylamino)-ethyl]-amino}-ethyl)-2-methyl-acrylamide
• 英文别名: N-[2-[bis[2-(2-methylprop-2-enoylamino)ethyl]amino]ethyl]-2-methylprop-2-enamide
• 化学式: C₁₈H₃₀N₄O₃
• 分子量: 350.461
• InChiKey: BPOLKGPFEJLEGU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  25
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  90.5
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  三(2-氨基乙基)胺 、 甲基丙烯酰氯 以 二氯甲烷 为溶剂， 反应 24.0h， 以21%的产率得到N-(2-{Bis-[2-(2-methyl-acryloylamino)-ethyl]-amino}-ethyl)-2-methyl-acrylamide
  参考文献：
  名称：

  Synthesis, Characterization, and Modelling of Novel Multifunctional Acryloyl-Based Monomers: An Experimental and Computational Study

  摘要：

  我们合成了几种至少具有三个活性 N-丙烯酰双键的新型多功能单体，并对其进行了全面鉴定。量子化学计算和核磁共振（NMR）光谱被用来预测这些单体的结构不对称性：通过模拟单体（3）的构象和 NMR 光谱，可以解释观察到的 13C NMR 光谱，并比较几种计算化学位移方法的性能。

  DOI：

  10.1071/ch01082

文献信息

• AQUEOUS CURABLE COMPOSITION AND WATER-SOLUBLE PHOTOPOLYMERIZATION INITIATOR
  申请人：FUJIFILM CORPORATION

  公开号：US20180362558A1

  公开（公告）日：2018-12-20

  An aqueous curable composition includes a water-soluble photopolymerization initiator having a structure in which one or more carbonyl groups further directly bond to an aromatic ring of an aromatic acyl group that bonds to a phosphorus atom in an acylphosphine oxide structure, water, and a polymerizable compound. A novel water-soluble photopolymerization initiator is a compound represented by formula 1-1 or formula 2-1.

  一种水性可固化组合物包括一种水溶性光聚合引发剂，其具有结构，其中一个或多个羰基直接与芳香酰基的芳香环结合，该芳香酰基与酰磷氧化物结构中的磷原子结合，水，以及一种可聚合化合物。一种新型水溶性光聚合引发剂是由式1-1或式2-1表示的化合物。
• PHOTOPOLYMERIZATION METHOD, INK SET, IMAGE FORMATION METHOD, INK COMPOSITION, AND PHOTOPOLYMERIZATION INITIATOR AND WATER-SOLUBLE BIIMIDAZOLE USED THEREIN
  申请人：FUJI-FILM Corporation

  公开号：EP2899241A1

  公开（公告）日：2015-07-29

  A photopolymerization method in which an ink composition including (A) a polymerizing compound having an ethylenic unsaturated group, (B) a photopolymerization initiator represented by Formula (1) described below, and (C) a hydrogen donor having a structure in which a nitrogen atom is directly bonded to an aromatic ring, in which the aromatic ring has an electron-withdrawing group or the nitrogen atom constitutes a hetero ring, is photopolymerized under acidic conditions, in Formula (1), each of R1 to R30 represents a hydrogen atom, a halogen atom, an alkyl group, or an alkoxy group.

  一种在酸性条件下进行光聚合的油墨组合物的光聚合方法，其中包括：(A) 具有乙烯不饱和基团的聚合化合物；(B) 由下述式(1)表示的光聚合引发剂；(C) 具有氮原子直接键合到芳香环上的结构的氢供体，其中芳香环上有一个抽电子基团或氮原子构成一个杂环、 式（1）中，R1 至 R30 各代表氢原子、卤素原子、烷基或烷氧基。
• CURABLE RESIN COMPOSITION, WATER-SOLUBLE INK COMPOSITION, INK SET, AND IMAGE FORMATION METHOD
  申请人：Fujifilm Corporation

  公开号：EP2902417A1

  公开（公告）日：2015-08-05

  The present invention relates to a curable resin composition including fine particles, a polymerizable compound having an ethylenic unsaturated group, a photopolymerization initiator having a betaine structure, and water, a water-soluble ink composition, an ink set, and an image-forming method.

  本发明涉及一种可固化树脂组合物，包括细颗粒、具有乙烯不饱和基团的可聚合化合物、具有甜菜碱结构的光聚合引发剂和水，还涉及一种水溶性油墨组合物、油墨组和图像形成方法。
• INK COMPOSITION, INK SET, AND IMAGE FORMATION METHOD
  申请人：FUJIFILM Corporation

  公开号：EP2977413A1

  公开（公告）日：2016-01-27

  An ink composition contains the following (A) to (D): (A) a polymerizable compound having an ethylenically unsaturated group, (B) a photopolymerization initiator other than a photopolymerization initiator having a biimidazole structure, (C) water, and (D) a chain transfer agent precursor represented by the following Formula (1). In Formula (1), each of R1 to R4 represents a hydrogen atom or a substituent; X represents an oxygen atom or a sulfur atom; and M represents an alkali metal.

  一种油墨组合物包含以下（A）至（D）：（A）具有乙烯不饱和基团的可聚合化合物，（B）光聚合引发剂（具有双咪唑结构的光聚合引发剂除外），（C）水，和（D）由下式（1）代表的链转移剂前体。 在式 (1) 中，R1 至 R4 各代表氢原子或取代基；X 代表氧原子或硫原子；M 代表碱金属。
• Inclusion complexes of unsaturated monomers, their polymers and process for preparation thereof
  申请人：Patil Maruti Prerana

  公开号：US20060094844A1

  公开（公告）日：2006-05-04

  The present invention describes water-soluble homopolymers obtained by polymerization of monomers containing multiple unsaturations. These monomers form inclusion complexes with cyclodextrins and methylated cyclodextrins. The unsaturated site involved in the formation of the inclusion complex does not take part in the polymeization reaction. After cyclodextrin is recovered, the polymer containing multiple unsaturations can be further polymerized either by thermal and/or photochemical initiators to yield crosslinked polymers.

  本发明描述了通过聚合含有多种不饱和基的单体而获得的水溶性均聚物。这些单体与环糊精和甲基化环糊精形成包合物。参与形成包合物的不饱和位点不参与聚合反应。回收环糊精后，含有多重不饱和的聚合物可通过热引发剂和/或光化学引发剂进一步聚合，生成交联聚合物。