N,N-diethyl-4-(methylthio)benzamide | 1378313-78-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N-diethyl-4-(methylthio)benzamide
• 英文别名: N,N-diethyl-4-methylsulfanylbenzamide
• CAS: 1378313-78-0
• 化学式: C₁₂H₁₇NOS
• mdl: MFCD20539112
• 分子量: 223.339
• InChiKey: NEPMAHNIEFMJQD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.61
• 重原子数：
  15.0
• 可旋转键数：
  4.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.416
• 拓扑面积：
  20.31
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  N,N-diethyl-4-(methylthio)benzamide 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 以89%的产率得到N,N-diethyl-4-(methylsulfinyl)benzamide
  参考文献：
  名称：

  芳基亚砜的亲核邻位炔丙基化：中断的Pummerer / Allenyl Thio-Claisen重排序列。

  摘要：

  一个新的方向：芳基亚砜的亲核邻炔丙基化利用了亲核分子向硫的分子间传递，然后是分子间的对碳的中继（参见方案）。对于炔丙基亲核试剂而言，简单，无金属的方法是通用的，区域特异性的，并且对烯丙基化过程中邻炔丙基化的产物具有完全的选择性。

  DOI：

  10.1002/anie.201300223
• 作为产物：
  描述：

  4-甲硫基苯甲酸 、 二乙胺 在 氯化亚砜 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 1.0h， 以93%的产率得到N,N-diethyl-4-(methylthio)benzamide
  参考文献：
  名称：

  硼酸催化氢化硅烷还原叔酰胺：胺的轻度和化学选择性合成

  摘要：

  据报道，由硼酸催化的各种芳基，烷基和α，β-不饱和酰胺与苯基硅烷的还原反应。前所未有的反应是在非常温和的条件下进行的，并生成了有用的胺。此外，该反应可耐受多种官能团。初步研究表明，中间体二芳基氢硼烷参与了反应机理。

  DOI：

  10.1002/chem.201604802

文献信息

• Palladium-Catalyzed Coupling of Azoles or Thiazoles with Aryl Thioethers via C–H/C–S Activation
  作者：Feng Zhu、Zhong-Xia Wang

  DOI：10.1021/acs.orglett.5b00510

  日期：2015.3.20

  Palladium-catalyzed cross-coupling via the (CspS)-S-2 bond activation of aryl thioethers and the C-H bond activation of azoles or thiazoles was carried out. Electron-deficient and -rich aryl methyl thioethers and diaryl thioethers can be employed as the coupling partners and the reaction tolerates a range of functional groups including MeO, CF3, CN, PhCO, CONEt2, and Py groups.
• Negative curable dye-containing composition, color filter, and method of manufacturing the same
  申请人：Takakuwa Hideki

  公开号：US20070072096A1

  公开（公告）日：2007-03-29

  The invention provides a negative curable dye-containing composition including at least one compound selected from amine and pyridine compounds, a phthalocyanine dye soluble in an organic solvent, a photopolymerization initiator, and a radical polymerizable monomer, a color filter formed by using the same, and a manufacturing method of the color filter.
• Dye-containing photosensitive composition, color filter using the same, and production method thereof
  申请人：Takakuwa Hideki

  公开号：US20070190435A1

  公开（公告）日：2007-08-16

  The present invention provides a dye-containing photosensitive composition that includes at least phthalocyanine, a photosensitive compound, and a transition metal complex of which the molar absorption coefficient ε in a visible light region is less than 5000.
• Oxime derivative, photopolymerizable composition, color filter, and process for producing the same
  申请人：Sasaki Tomoya

  公开号：US20070203255A1

  公开（公告）日：2007-08-30

  There are provided a compound represented by the following formula (I), a photopolymerizable composition containing (A) a photopolymerization initiator represented by the formula (I) and (B) a radical polymerizable monomer, a color filter produced by using the photopolymerizable composition, and a process for producing the color filter:
• Dye-containing negative working curable composition, color filter and production method thereof
  申请人：Takakuwa Hideki

  公开号：US20070212623A1

  公开（公告）日：2007-09-13

  The invention provides a dye-containing negative working curable composition comprising at least a dye, a photopolymerization initiator, a polymerizable monomer, and a colorless compound having a number average molecular weight of 1,000 to 5,000, wherein the ratio of an alkali-soluble resin to the total solid content of the composition is 10% by mass or less.