(2-dodecylsulfide)selenophene

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: (2-dodecylsulfide)selenophene
• 英文别名: 2-Dodecylsulfanylselenophene
• 化学式: C₁₆H₂₈SSe
• 分子量: 331.424
• InChiKey: NTPXQFAHATUWBK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.76
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  25.3
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-碘硒吩 、 十二硫醇 在 copper(l) iodide 氢氧化钾 作用下， 以 1,4-二氧六环 为溶剂， 反应 8.0h， 以82%的产率得到(2-dodecylsulfide)selenophene
  参考文献：
  名称：

  Carbon–sulfur bond formation from 2-halochalcogenophenes via copper catalyzed thiol cross-coupling

  摘要：

  We present herein our results of the thiol coupling reaction of 2-halochalcogenophenes with Cu(I) and establish the first route to prepare (2-sulfides)-chalcogenophenes in good yields. The reaction performed with both electron donating and electron withdrawing substituents on thiol in the absence of any supplementary additives. In addition, the reaction proceeded cleanly under mild reaction conditions and was sensitive to nature of catalyst, base, and solvent. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.02.102

文献信息

• Carbon–sulfur bond formation from 2-halochalcogenophenes via copper catalyzed thiol cross-coupling
  作者：Gilson Zeni

  DOI：10.1016/j.tetlet.2005.02.102

  日期：2005.4

  We present herein our results of the thiol coupling reaction of 2-halochalcogenophenes with Cu(I) and establish the first route to prepare (2-sulfides)-chalcogenophenes in good yields. The reaction performed with both electron donating and electron withdrawing substituents on thiol in the absence of any supplementary additives. In addition, the reaction proceeded cleanly under mild reaction conditions and was sensitive to nature of catalyst, base, and solvent. (c) 2005 Elsevier Ltd. All rights reserved.