5-[10-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-10-oxodecanoyl]-2,2-dimethyl-1,3-dioxane-4,6-dione

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: 5-[10-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-10-oxodecanoyl]-2,2-dimethyl-1,3-dioxane-4,6-dione
• 化学式: C₂₂H₃₀O₁₀
• 分子量: 454.474
• InChiKey: DODCEPYEIQGVTH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  32
• 可旋转键数：
  11
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  139
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  5-[10-(2,2-Dimethyl-4,6-dioxo-1,3-dioxan-5-yl)-10-oxodecanoyl]-2,2-dimethyl-1,3-dioxane-4,6-dione 以 氯苯 为溶剂， 以60%的产率得到(+/-)-14-hydroxy-12-oxabicyclo[9.2.2]pentadecane-1(14),11(15)-diene-2,13-dione
  参考文献：
  名称：

  高效的亚环糊精合成方法

  摘要：

  描述了用于合成间环烷，例如2，6-桥联的吡啶和吡啶的高效方法。在3位和6位桥接的4-羟基-2-吡喃酮衍生物3是容易获得的。在乙醇或盐酸中加热，将该化合物转化为2，6-桥联的4-吡喃酮4。与氨或甲胺加热4得到相应的2，6-桥连的4-吡喃酮7或8。这些吡啶酮是通过用氨或甲胺处理直接由3合成的。这些方法对间环烷的桥长具有广泛的适用性。具有短桥（n = 8）和长桥（n＝ 18）以令人满意的产率合成。

  DOI：

  10.1016/s0040-4020(03)00326-0

文献信息

• Recyclable and Reconfigurable High-Performance Polymer Networks and Uses Thereof
  申请人：Helms Brett A.

  公开号：US20200283415A1

  公开（公告）日：2020-09-10

  The present invention relates to a composition of polymers comprising dynamic covalent diketoenamine bonds. This composition allows the formulation of polymeric materials with a wide range of architectures and properties, and further allows these materials to be recycled using thermal, chemical, or mechanical processes

  本发明涉及一种聚合物组合物，其中包含动态共价二酮胺键。该组合物允许制备具有各种结构和性质的聚合材料，并进一步允许使用热、化学或机械过程对这些材料进行回收。
• Cured film-forming composition
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US10669376B2

  公开（公告）日：2020-06-02

  Provided are: a cured film-forming composition whereby a underlayer film for image formation formed from the composition exhibits high liquid repellency (lyophobicity) and lyophilic/liquid-repellent properties of the underlayer film can be easily changed even when exposed to a low amount of ultraviolet radiation; and a cured film obtained using the composition. The cured film-forming resin composition is characterized by containing: a polymer comprising a structural unit derived from a first monomer having the structure of formula (1) as component (A); a polymer other than component (A), which is a polymer in which the content of fluorine relative to the overall weight of the polymer is lower than in component (A), as component (B); a photoacid generator as component (C); and a solvent. (In the formula, R1 denotes hydrogen or a methyl group, and R2 denotes a fluorine-containing group able to be detached together with the oxygen atom bonded to R2.)

  提供的是一种治愈的成膜组合物，由该组合物形成的图像形成底层膜表现出高液体排斥性（亲疏性），即使暴露于低量紫外辐射下，底层膜的亲疏性和液体排斥性也可以轻松改变；以及使用该组合物获得的治愈膜。该治愈成膜树脂组合物的特点是包含：作为组分（A）的具有来自第一单体的结构单元的聚合物，该单体的结构式为（1）；除组分（A）外的另一种聚合物，其相对于聚合物总重量的含氟量低于组分（A），作为组分（B）；作为组分（C）的光酸发生剂；和溶剂。（在公式中，R1表示氢或甲基基团，R2表示能够与R2键合的氧原子一起脱落的含氟基团。）
• CURED FILM-FORMING COMPOSITION
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US20190085130A1

  公开（公告）日：2019-03-21

  Provided are: a cured film-forming composition whereby a underlayer film for image formation formed from the composition exhibits high liquid repellency (lyophobicity) and lyophilic/liquid-repellent properties of the underlayer film can be easily changed even when exposed to a low amount of ultraviolet radiation; and a cured film obtained using the composition. The cured film-forming resin composition is characterized by containing: a polymer comprising a structural unit derived from a first monomer having the structure of formula (1) as component (A); a polymer other than component (A), which is a polymer in which the content of fluorine relative to the overall weight of the polymer is lower than in component (A), as component (B); a photoacid generator as component (C); and a solvent. (In the formula, R 1 denotes hydrogen or a methyl group, and R 2 denotes a fluorine-containing group able to be detached together with the oxygen atom bonded to R 2 .)