2,3,5,6,10,11-hexahydroxytriphenylene

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,3,5,6,10,11-hexahydroxytriphenylene
• 英文别名: triphenylene-1,2,6,7,10,11-hexol
• 化学式: C₁₈H₁₂O₆
• 分子量: 324.29
• InChiKey: RIXCQDQUABOYET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  121
• 氢给体数：
  6
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,3,5,6,10,11-hexahydroxytriphenylene 、 cobalt(II) diacetate tetrahydrate 以 N-甲基吡咯烷酮 、 水 为溶剂， 反应 24.5h， 以65%的产率得到
  参考文献：
  名称：

  [EN] PREPARATION OF METAL-CATECHOLATE FRAMEWORKS
  [FR] PRÉPARATION DE STRUCTURES EN CATÉCHOLATE MÉTALLIQUE

  摘要：

  公开号：

  WO2012106451A3

文献信息

• Conductive textiles and uses thereof in functional devices
  申请人：Dartmouth College

  公开号：US11092562B2

  公开（公告）日：2021-08-17

  Embodiments of the present disclosure pertain to conductive textiles that include a textile component with a plurality of fibers; and metal-organic frameworks associated with the fibers of the textile component in the form of a conductive network. Metal-organic frameworks may have a two-dimensional structure and a crystalline form. Metal-organic frameworks may be conformally coated on the fibers of the textile component. Additional embodiments of the present disclosure pertain to methods of sensing an analyte in a sample by exposing the sample to a conductive textile; and detecting the presence or absence of the analyte by detecting a change in a property of the conductive textile, and correlating the change in the property to the presence or absence of the analyte. The analyte in the sample may reversibly associate with the conductive textile. The association may also result in filtration, pre-concentration, and capture of the analyte by the conductive textile.

  本公开的实施方案涉及导电纺织品，其中包括具有多种纤维的纺织部件；以及以导电网络形式与纺织部件的纤维相关联的金属有机框架。金属有机框架可具有二维结构和结晶形式。金属有机框架可以保形涂覆在纺织部件的纤维上。本公开的其它实施例涉及通过将样品暴露于导电纺织品来感测样品中分析物的方法；以及通过检测导电纺织品属性的变化来检测分析物的存在或不存在，并将属性的变化与分析物的存在或不存在相关联的方法。样品中的分析物可能会与导电织物发生可逆关联。这种关联还可能导致过滤、预浓缩以及导电织物对分析物的捕获。
• CONDUCTIVE TEXTILES AND USES THEREOF IN FUNCTIONAL DEVICES
  申请人：Dartmouth College

  公开号：US20180306740A1

  公开（公告）日：2018-10-25

  Embodiments of the present disclosure pertain to conductive textiles that include a textile component with a plurality of fibers; and metal-organic frameworks associated with the fibers of the textile component in the form of a conductive network. Metal-organic frameworks may have a two-dimensional structure and a crystalline form. Metal-organic frameworks may be conformally coated on the fibers of the textile component. Additional embodiments of the present disclosure pertain to methods of sensing an analyte in a sample by exposing the sample to a conductive textile; and detecting the presence or absence of the analyte by detecting a change in a property of the conductive textile, and correlating the change in the property to the presence or absence of the analyte. The analyte in the sample may reversibly associate with the conductive textile. The association may also result in filtration, pre-concentration, and capture of the analyte by the conductive textile.
• METAL-ORGANIC FRAMEWORKS AS ION-TO-ELECTRON TRANSDUCERS AND DETECTORS
  申请人：Trustees of Dartmouth College

  公开号：US20210164930A1

  公开（公告）日：2021-06-03

  Embodiments of the present disclosure pertain to ion-selective electrodes that include a metal-organic framework and an electrode surface. The metal-organic framework is associated with the electrode surface in a manner that forms an interface between the metal-organic framework and the electrode surface. Additional embodiments pertain to methods of detecting an ion in a sample by associating the sample with the ion-selective electrodes of the present disclosure. The metal-organic frameworks of the ion-selective electrodes mediate ion-to-electron transduction through the interface between the metal-organic and the electrode surface. Thereafter, the presence or absence of the ion in the sample is detected by detecting a change in potential of the ion-selective electrode and correlating the change in the potential to the presence or absence of the ion. The metal organic frameworks may simultaneously mediate ion sensing and ion-to-electron transduction through the interface between the metal-organic frameworks and the electrode surface.
• METAL-ORGANIC FRAMEWORKS AS ION CAPTURE COMPOSITIONS
  申请人：Trustees of Dartmouth College

  公开号：US20220404308A1

  公开（公告）日：2022-12-22

  Embodiments of the present disclosure pertain to methods of capturing one or more ions from an environment by associating the environment with a composition that includes a metal-organic framework. The association results in the capture of the one or more ions by the metal-organic framework. The metal-organic frameworks may include a plurality of metals and a plurality of triphenylene-based ligands that interconnect the plurality of the metals. The methods of the present disclosure may also include a step of detecting one or more captured ions. Additional embodiments of the present disclosure pertain to the compositions for capturing one or more ions from an environment.
• [EN] METAL-ORGANIC FRAMEWORKS AS ION-TO-ELECTRON TRANSDUCERS AND DETECTORS<br/>[FR] CADRES MÉTALLO-ORGANIQUES EN TANT QUE TRANSDUCTEURS IONS-ÉLECTRONS ET DÉTECTEURS
  申请人：DARTMOUTH COLLEGE

  公开号：WO2019033104A1

  公开（公告）日：2019-02-14

  Embodiments of the present disclosure pertain to ion-selective electrodes that include a metal-organic framework and an electrode surface. The metal-organic framework is associated with the electrode surface in a manner that forms an interface between the metal-organic framework and the electrode surface. Additional embodiments pertain to methods of detecting an ion in a sample by associating the sample with the ion- selective electrodes of the present disclosure. The metal-organic frameworks of the ion-selective electrodes mediate ion-to- electron transduction through the interface between the metal-organic frameworks and the electrode surface. Thereafter, the presence or absence of the ion in the sample is detected by detecting a change in potential of the ion-selective electrode and correlating the change in the potential to the presence or absence of the ion. The metal organic frameworks may simultaneously mediate ion sensing and ion-to-electron transduction through the interface between the metal-organic frameworks and the electrode surface.