反式-1-氯-3-氧基氨基丙烯盐酸盐 | 82244-86-8

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 乙烯基卤化物
• 中文名称: 反式-1-氯-3-氧基氨基丙烯盐酸盐
• 中文别名: 2-(3,4-二羟基苯基)-5,7-二羟基-4-羰基-4H-色烯-8-基β-D-吡喃葡萄糖苷；O-(3-氯丙-2-烯-1-基)羟胺盐酸
• 英文名称: 3-Chloroallyloxyamine hydrochloride
• 英文别名: Hydroxylamine, O-(3-chloro-2-propenyl)-, hydrochloride；O-(3-chloroprop-2-enyl)hydroxylamine;hydrochloride
• CAS: 82244-86-8
• 化学式: C₃H₆ClNO*ClH
• mdl: MFCD08436146
• 分子量: 144.001
• InChiKey: GZDAGPDHXQKVHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.69
• 重原子数：
  7
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.333
• 拓扑面积：
  35.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  反式-1-氯-3-氧基氨基丙烯盐酸盐 在 水 、 sodium hydroxide 作用下， 生成 O-(3-chloro-2-propenyl)hydroxylamine
  参考文献：
  名称：

  CN117024321

  摘要：

  公开号：
• 作为产物：
  描述：

  acetyl O-3-chloro-2-propenylhydroxylamine 在 盐酸 作用下， 以 水 为溶剂， 以100 %的产率得到反式-1-氯-3-氧基氨基丙烯盐酸盐
  参考文献：
  名称：

  CN117024321

  摘要：

  公开号：

文献信息

• Herbicidal 5-(acylphenyl)cyclohexane-1,3-dione derivatives
  申请人：ICI Australia Limited

  公开号：US04652303A1

  公开（公告）日：1987-03-24

  The invention concerns novel compounds of the formula I ##STR1## wherein: W are selected from the group consisting of: the groups R.sup.5 --CO-- and R.sup.5 --CS-- wherein: R.sup.5 is selected from alkenyl, alkynyl, benzyl, phenyl, substituted alkyl, substituted alkenyl, substituted alkynyl, substituted benzyl, substituted phenyl and the acetal, hemiacetal, oxime, imine and Schiff base derivatives of the group R.sup.5 --CO--; the groups Y--CO-- and Y--CS-- wherein Y is selected from hydroxy, mercapto, alkylthio and the groups MO-- and MS-- wherein M is an organic or an inorganic cation; the groups R.sup.6 R.sup.7 NCO-- and R.sup.6 R.sup.7 NCS-- wherein R.sup.6 and R.sup.7 are independently selected from hydrogen, alkyl, substituted alkyl, alkanoyl, carboxy, alkoxycarbonyl, alkylsulfonyl, benzoyl, benzenesulfonyl, substituted benzoyl, substituted benzenesulfonyl, or R.sup.6 and R.sup.7 form a heterocyclic ring; X are selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, alkanoyloxy, benzyloxy, substituted benzyloxy, amino, substituted amino, and the groups formyl and alkanoyl and the acetal, hemiacetal, oxime, imine and Schiff base derivatives thereof; R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation; R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl; R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl; R.sup.4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl; m is selected from integers 1 and 2; n is selected from the integers 1 to 4; and m+n is selected from the integers 3 to 5. The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.

  该发明涉及公式I的新化合物##STR1##其中：W选自以下组：R.sup.5 --CO--和R.sup.5 --CS--其中：R.sup.5选自烯基、炔基、苄基、苯基、取代烷基、取代烯基、取代炔基、取代苄基、取代苯基和R.sup.5 --CO--的乙缩醛、半乙缩醛、肟、亚胺和R.sup.5 --CO--的席夫碱衍生物；Y--CO--和Y--CS--其中Y选自羟基、巯基、烷基硫和MO--和MS--其中M是有机或无机阳离子；R.sup.6 R.sup.7 NCO--和R.sup.6 R.sup.7 NCS--其中R.sup.6和R.sup.7独立选择自氢、烷基、取代烷基、烷酰基、羧基、烷氧羰基、烷基磺酰基、苯甲酰基、苯磺酰基、取代苯甲酰基、取代苯磺酰基，或R.sup.6和R.sup.7形成杂环；X选自卤素、硝基、氰基、烷基、取代烷基、羟基、烷氧基、取代烷氧基、烯基、烯氧基、炔基、炔氧基、酰氧基、烷氧羰基、烷基硫、烷基磺基、磺酰基、取代磺酰基、烷酰氧基、苄氧基、取代苄氧基、氨基、取代氨基，以及甲酰基和烷酰基和其乙缩醛、半乙缩醛、肟、亚胺和席夫碱衍生物；R.sup.1选自氢、烷基、烯基、炔基、取代烷基、烷磺基、芳基磺基、酰基和无机或有机阳离子；R.sup.2选自烷基、取代烷基、烯基、卤代烯基、炔基和卤代炔基；R.sup.3选自烷基、氟烷基、烯基、炔基和苯基；R.sup.4选自氢、卤素、烷基、氰基和烷氧羰基；m选自整数1和2；n选自整数1至4；m+n选自整数3至5。该发明的化合物具有除草和植物生长调节特性，并在进一步的实施中提供了制备公式I化合物的过程、制备公式I化合物的中间体、含有公式I化合物作为活性成分的组合物，以及利用公式I化合物的除草和植物生长调节过程。
• Herbicidal 5-pyrimidylcyclohexan-1,3-dione derivatives
  申请人：ICI Australia Limited

  公开号：US04659362A1

  公开（公告）日：1987-04-21

  The invention concerns novel compounds of the formula I ##STR1## wherein: X are selected from halogen, nitro, cyano, alkyl, substituted alkyl, hydroxy, alkoxy, substituted alkoxy, alkenyl, alkenyloxy, alkynyl, alkynyloxy, acyloxy, alkoxycarbonyl, alkylthio, alkylsulfinyl, alkylsulfonyl, sulfamoyl, substituted sulfamoyl, alkanoyloxy, benzyloxy, substituted benzyloxy, amino, substituted amino, and the groups formyl and alkanoyl and the oxime, imine and Schiff base derivatives thereof; R.sup.1 is selected from hydrogen, alkyl, alkenyl, alkynyl, substituted alkyl, alkylsulfonyl, arylsulfonyl, acyl and an inorganic or organic cation; R.sup.2 is selected from alkyl, substituted alkyl, alkenyl, haloalkenyl, alkynyl and haloalkynyl; R.sup.3 is selected from alkyl, fluoroalkyl, alkenyl, alkynyl, and phenyl; R.sup.4 is selected from hydrogen, halogen, alkyl, cyano and alkoxycarbonyl; and n is the integer 3. The compounds of the invention show herbicidal properties and plant growth regulating properties and in further embodiments the invention provides processes for the preparation of compounds of formula I, intermediates useful in the preparation of the compounds of formula I, compositions containing as active ingredient a compound of formula I, and herbicidal and plant growth regulating processes utilizing compounds of formula I.

  本发明涉及公式I的新化合物 ##STR1## 其中：X选自卤素，硝基，氰基，烷基，取代烷基，羟基，烷氧基，取代烷氧基，烯基，烯氧基，炔基，炔氧基，酰氧基，烷氧羰基，烷基硫基，烷基亚磺酰基，烷基磺酰基，磺酰胺基，取代磺酰胺基，烷酰氧基，苄氧基，取代苄氧基，氨基，取代氨基，以及酰甲基和烷酰基和其氧肟，亚胺和席夫碱衍生物；R.sup.1选自氢，烷基，烯基，炔基，取代烷基，烷基磺酰基，芳基磺酰基，酰基和无机或有机阳离子；R.sup.2选自烷基，取代烷基，烯基，卤代烯基，炔基和卤代炔基；R.sup.3选自烷基，氟烷基，烯基，炔基和苯基；R.sup.4选自氢，卤素，烷基，氰基和烷氧羰基；n是整数3。本发明的化合物具有除草和植物生长调节性能，在进一步的实施方式中，本发明提供了制备公式I化合物的方法，制备公式I化合物的中间体，含有公式I化合物作为活性成分的组合物，以及利用公式I化合物的除草和植物生长调节过程。
• Calla lily plant named ‘Diva Bianca’
  申请人：Dümmen Group B.V.

  公开号：USPP032489P3

  公开（公告）日：2020-11-17

  ‘Diva Bianca’ is a new variety of calla lily plant having white colored spathes and a sweet fragrance. The leaves are green with no maculations present.

  “Diva Bianca”是一种新品种的马蹄莲植物，具有白色苞片和甜美的香气。叶子呈绿色，没有斑点。
• Herbicidal substituted 2-(1-(oxyamino)-alkylidene)-cyclohexane-1,3-diones
  申请人：Chevron Research Company

  公开号：US04440566A1

  公开（公告）日：1984-04-03

  Substituted 2-[1-(oxyamino)alkylidene]-cyclohexane-1,3-diones have herbicidal activity against grassy weeds.

  替代的2-[1-(氧胺)烷基亚甲基]-环己烷-1,3-二酮对草本杂草具有除草活性。
• Cyclohexane-1,3-dione derivatives and their use for controlling
  申请人：BASF Aktiengesellschaft

  公开号：US04602935A1

  公开（公告）日：1986-07-29

  Cyclohexane-1,3-dione derivatives of the formula ##STR1## where R.sup.1 is alkyl, R.sup.2 is alkyl, unsubstituted or halogen-substituted alkenyl or alkynyl, X is a saturated or unsaturated five-membered or six-membered heterocyclic structure which carries one or more substituents, and Z is hydrogen, methoxycarbonyl, ethoxycarbonyl, methyl or cyano, and salts of these compounds are used for controlling undesirable plant growth.

  Cyclohexane-1,3-二酮衍生物的化学式为##STR1## 其中R.sup.1为烷基，R.sup.2为烷基，未取代或卤素取代的烯基或炔基，X为饱和或不饱和的五元或六元杂环结构，带有一个或多个取代基，Z为氢，甲氧羰基，乙氧羰基，甲基或氰基，这些化合物的盐可用于控制不良植物生长。