2-methyl-3-vinyl-thiophene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: 2-methyl-3-vinyl-thiophene
• 英文别名: 3-Ethenyl-2-methylthiophene
• 化学式: C₇H₈S
• 分子量: 124.207
• InChiKey: XKWYJGQHYVSADX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.8
• 重原子数：
  8
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-methyl-3-vinyl-thiophene 、 1,3-dioxoisoindolin-2-yl (3r,5r,7r)-adamantane-1-carboxylate 、 苯胺 在 tris(2,2'-bipyridyl)ruthenium dichloride 、 三(五氟苯基)硼烷 作用下， 以 二甲基亚砜 为溶剂， 反应 24.0h， 以58%的产率得到N-(2-adamant-1-yl-1-(2-methylthiophen-3-yl)ethyl)aniline
  参考文献：
  名称：

  B（C 6 H 5）3-促进的光氧化还原催化烷基N-羟基邻苯二甲酰亚胺酯和胺对苯乙烯的烷基化反应

  摘要：

  描述了通过路易斯酸和可见光光氧化还原协同催化的烷基N-羟基邻苯二甲酰亚胺（NHP）酯和胺对苯乙烯进行的新的三组分1,2-烷基氨基化。该反应采用烷基NHP酯作为一般的烷基化试剂，以高效率且具有出色的官能团耐受性完成烯烃的1,2-烷基氨基化，从而显着提高了烯烃1,2-烷基氨基化的合成潜力，可用于获得复杂的官能化胺。

  DOI：

  10.1021/acs.orglett.8b02670

文献信息

• Fungicidal Composition Containing Acid Amide Derivative
  申请人：Nakamura Yuji

  公开号：US20080318779A1

  公开（公告）日：2008-12-25

  Conventional many fungicidal compositions have had practical problems such that either a preventive effect or a curing effect is inadequate, the residual effect tends to be inadequate, or the controlling effect against plant diseases tends to be inadequate depending upon the application site, and a fungicidal composition to overcome such problems has been desired. The present invention provides a fungicidal composition containing an acid amide derivative of the formula (I) or a salt thereof, as an active ingredient: wherein A is phenyl which may be substituted, benzyl which may be substituted, naphthyl which may be substituted, heterocyclic ring which may be substituted, fused heterocyclic ring which may be substituted, or the like; B is heterocyclic ring which may be substituted, fused heterocyclic ring which may be substituted, or naphthyl which may be substituted; each of R 1 and R 2 which are independent of each other, is alkyl, or the like; R 3 is hydrogen, or the like; each of W 1 and W 2 which are independent of each other, is oxygen or sulfur.

  传统的许多杀菌组合物存在实际问题，例如预防效果或治疗效果不足，残留效果倾向于不足，或者根据应用场所，对植物疾病的控制效果倾向于不足，因此需要一种克服这些问题的杀菌组合物。本发明提供了一种含有式(I)的酸酰胺衍生物或其盐作为活性成分的杀菌组合物：其中，A是苯基，可以是取代的苯基，苄基，可以是取代的苄基，萘基，可以是取代的萘基，杂环环，可以是取代的杂环环，融合的杂环环，可以是取代的融合的杂环环或类似物；B是杂环环，可以是取代的融合的杂环环或取代的萘基；R1和R2各自独立地是烷基或类似物；R3是氢或类似物；W1和W2各自独立地是氧或硫。
• FUNGICIDAL COMPOSITION CONTAINING ACID AMIDE DERIVATIVE
  申请人：Nakamura Yuji

  公开号：US20100261675A1

  公开（公告）日：2010-10-14

  Conventional many fungicidal compositions have had practical problems such that either a preventive effect or a curing effect is inadequate, the residual effect tends to be inadequate, or the controlling effect against plant diseases tends to be inadequate depending upon the application site, and a fungicidal composition to overcome such problems has been desired. The present invention provides a fungicidal composition containing an acid amide derivative of the formula (I) or a salt thereof, as an active ingredient: wherein A is phenyl which may be substituted, benzyl which may be substituted, naphthyl which may be substituted, heterocyclic ring which may be substituted, fused heterocyclic ring which may be substituted, or the like; B is heterocyclic ring which may be substituted, fused heterocyclic ring which may be substituted, or naphthyl which may be substituted; each of R 1 and R 2 which are independent of each other, is alkyl, or the like; R 3 is hydrogen, or the like; each of W 1 and W 2 which are independent of each other, is oxygen or sulfur.

  传统的多种杀菌剂组合存在实际问题，例如预防效果或治疗效果不足，残留效果往往不足，或者根据应用场所，对植物疾病的控制效果往往不足，因此需要一种能够克服这些问题的杀菌剂组合。本发明提供了一种杀菌剂组合，其包含式（I）的酸酰胺衍生物或其盐作为活性成分：其中A是苯基，可以是取代的苯基，苄基，可以是取代的苄基，萘基，可以是取代的萘基，杂环环，可以是取代的杂环环，融合的杂环环，可以是取代的融合的杂环环等；B是杂环环，可以是取代的融合的杂环环或萘基，可以是取代的萘基；R1和R2各自独立地是烷基或类似物；R3是氢或类似物；W1和W2各自独立地是氧或硫。
• Silicone Composition and Organic Light-Emitting Diode
  申请人：Suzuki Toshio

  公开号：US20110017986A1

  公开（公告）日：2011-01-27

  A silicone composition comprising (A) a hydrolysis product prepared by reacting at least one thiophenyl-substituted silane and a cross-linking agent with water in the presence of an organic solvent to form an organic phase containing the hydrolysis product and an aqueous phase, and separating the organic phase from the aqueous phase, and (B) an organic solvent; and an organic light-emitting diode (OLED) containing a hole-transport/hole-injection layer comprising a cured polysiloxane prepared by applying the aforementioned silicone composition to form a film and curing the film.

  一种硅组合物，包括（A）至少一种硫代苯基取代硅烷和交联剂在有机溶剂存在下与水反应制备的水解产物，形成含有水解产物的有机相和水相，并将有机相与水相分离，以及（B）有机溶剂；以及包含经由将上述硅组合物涂覆形成薄膜并固化薄膜制备的固化聚硅氧烷的空穴传输/空穴注入层的有机发光二极管（OLED）。
• Verfahren zur Herstellung von acylierten Heteroaromaten an zeolithischen Katalysatoren
  申请人：BASF Aktiengesellschaft

  公开号：EP0248393B1

  公开（公告）日：1991-08-07
• FUNGICIDAL COMPOSITION CONTAINING AN ACID AMIDE DERIVATIVE
  申请人：ISHIHARA SANGYO KAISHA, LTD.

  公开号：EP1776011B1

  公开（公告）日：2012-03-21