nitrato(diethylenetriamine)platinum(II) nitrate

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机含氧阴离子化合物
• 英文名称: nitrato(diethylenetriamine)platinum(II) nitrate
• 化学式: C₄H₁₃N₃*2NO₃*Pt
• 分子量: 422.257
• InChiKey: YNIJKAYVSFIUES-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.75
• 重原子数：
  12.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  130.27
• 氢给体数：
  3.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  (甲硫基)乙酸 、 nitrato(diethylenetriamine)platinum(II) nitrate 在 lithium hydroxide 作用下， 以 水 为溶剂， 以56.5%的产率得到diethylenetriamine(methylsulfanylacetate)platinum(II) nitrate
  参考文献：
  名称：

  Studies on Pt–S bonds. Complexes of methylsulfanyl- and methylsulfynil-acetate, benzoate and phenolate with the diethylenetriamineplatinum(II) moiety

  摘要：

  This paper reports on some complexes of formula [Pt(dien)(L-S](+), where dien is diethylenetriamine and L are methylsulfanyl- and methylsulfinyl-acetate, benzoate and phenolate. These ligands are monodentate and bound to Pt via the sulfur atoms. Reactions with guanosinemonophosphate (GMP) give, in all cases, [Pt(dien)(GMP)(2-), with GMP coordinated through the N(7) atom. The reactivities of the [Pt(dien)(L-S)](+) complexes are compared with those of [Pt(en)(L-S,O)](+) (en, ethylenediamine), in which the ligands L are chelated to Pt via the sulfur and the carboxylate, or phenolate oxygen atoms. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00347-8
• 作为产物：
  描述：

  氯二乙烯三胺铂 、 silver nitrate 以 水 为溶剂， 以96%的产率得到nitrato(diethylenetriamine)platinum(II) nitrate
  参考文献：
  名称：

  Studies on Pt–S bonds. Complexes of methylsulfanyl- and methylsulfynil-acetate, benzoate and phenolate with the diethylenetriamineplatinum(II) moiety

  摘要：

  This paper reports on some complexes of formula [Pt(dien)(L-S](+), where dien is diethylenetriamine and L are methylsulfanyl- and methylsulfinyl-acetate, benzoate and phenolate. These ligands are monodentate and bound to Pt via the sulfur atoms. Reactions with guanosinemonophosphate (GMP) give, in all cases, [Pt(dien)(GMP)(2-), with GMP coordinated through the N(7) atom. The reactivities of the [Pt(dien)(L-S)](+) complexes are compared with those of [Pt(en)(L-S,O)](+) (en, ethylenediamine), in which the ligands L are chelated to Pt via the sulfur and the carboxylate, or phenolate oxygen atoms. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(98)00347-8

文献信息

• Studies on Pt–S bonds. Complexes of methylsulfanyl- and methylsulfynil-acetate, benzoate and phenolate with the diethylenetriamineplatinum(II) moiety
  作者：Alessandro Pasini、Cristiano Fiore

  DOI：10.1016/s0020-1693(98)00347-8

  日期：1999.2

  This paper reports on some complexes of formula [Pt(dien)(L-S](+), where dien is diethylenetriamine and L are methylsulfanyl- and methylsulfinyl-acetate, benzoate and phenolate. These ligands are monodentate and bound to Pt via the sulfur atoms. Reactions with guanosinemonophosphate (GMP) give, in all cases, [Pt(dien)(GMP)(2-), with GMP coordinated through the N(7) atom. The reactivities of the [Pt(dien)(L-S)](+) complexes are compared with those of [Pt(en)(L-S,O)](+) (en, ethylenediamine), in which the ligands L are chelated to Pt via the sulfur and the carboxylate, or phenolate oxygen atoms. (C) 1999 Elsevier Science S.A. All rights reserved.