5-phenyl-4,6-dipropyl-4,6-nonan-di-ol

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5-phenyl-4,6-dipropyl-4,6-nonan-di-ol
• 英文别名: 5-Phenyl-4,6-dipropylnonane-4,6-diol
• 化学式: C₂₁H₃₆O₂
• 分子量: 320.516
• InChiKey: CFUTTYGVISRSSD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  23
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  4-庚酮 、 bis(benzotriazol-1-yl)phenylmethane 在 lithium 、 1,2-二溴乙烷 作用下， 以 四氢呋喃 为溶剂， 反应 4.0h， 以76%的产率得到5-phenyl-4,6-dipropyl-4,6-nonan-di-ol
  参考文献：
  名称：

  1,1-Bis(benzotriazolyl) derivatives as gem-dianion synthons

  摘要：

  Bis(benzotriazolyl)methylbenzenes la,b were converted by excess lithium metal in the presence of ketones into the 1,3-diols 3a-g in moderate to good yields. However, similar treatment of 5 gave only the mono reduction products 6, 7. Compounds la,b reacted with 1 equivalent of diketone 8 to form olefins 10a,b. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(98)00346-3

文献信息

• 1,1-Bis(benzotriazolyl) derivatives as gem-dianion synthons
  作者：Alan R. Katritzky、Clara N. Fali、Ming Qi

  DOI：10.1016/s0040-4039(98)00346-3

  日期：1998.4

  Bis(benzotriazolyl)methylbenzenes la,b were converted by excess lithium metal in the presence of ketones into the 1,3-diols 3a-g in moderate to good yields. However, similar treatment of 5 gave only the mono reduction products 6, 7. Compounds la,b reacted with 1 equivalent of diketone 8 to form olefins 10a,b. (C) 1998 Elsevier Science Ltd. All rights reserved.