叔-丁基异壬烷过氧酸酯 | 958779-36-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 叔-丁基异壬烷过氧酸酯
• 中文别名: 过异壬酸-1,1-二甲基乙基酯；氧过氧异壬酸叔丁酯；过异壬酸-1,1-二甲基乙基酯；氧过氧异壬酸叔丁酯
• 英文名称: tert-Butyl isononaneperoxoate
• 英文别名: tert-butyl 7-methyloctaneperoxoate
• CAS: 958779-36-7；27836-52-8
• 化学式: C₁₃H₂₆O₃
• 分子量: 230.34
• InChiKey: ZUSDEBDNDIJDMZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  16
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险等级：
  5.2

制备方法与用途

用途：主要用作乙烯、苯乙烯、甲基丙烯酸甲酯以及烯丙基化合物的聚合反应引发剂。

文献信息

• Method for oxidizing hydrocarbons
  申请人：——

  公开号：US20030176733A1

  公开（公告）日：2003-09-18

  The invention relates to a method for oxidizing substrates such as hydrocarbons, waxes or soot. The method involves the use of a compound of formula (I) in which: R1 and R2 represent H, an aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, each having 1 to 20 hydrocarbon atoms, SO3H, NH2, OH, F, Cl, Br, I and/or NO2, whereby R1 and R2 designate identical or different radicals or R1 and R2 can be linked to one another via a covalent bonding; Q1 and Q2 represent C, CH, N, CR5, each being the same or different; X and Z represent C, S, CH2, each being the same or different; Y represents O and OH; k=0, 1, 2; l=0, 1, 2; m=1 to 3, and; R5 represents one of the meanings of R1. Said compound is used as a catalyst in the presence of a radical initiator, whereby the molar ratio of the catalyst to the hydrocarbon is less than 10 mol %. Peroxy compounds or azo compounds can be used as the radical initiator. Preferred substrates are aliphatic or aromatic hydrocarbons.

  该发明涉及一种氧化底物（如烃、蜡或烟尘）的方法。该方法涉及使用式（I）的化合物，其中：R1和R2代表H、脂肪或芳香烷氧基基、羧基、烷氧羰基基或烃基，每个基有1到20个碳氢原子，SO3H、NH2、OH、F、Cl、Br、I和/或NO2，其中R1和R2表示相同或不同的基团，或者R1和R2可以通过共价键相连；Q1和Q2代表C、CH、N、CR5，每个基相同或不同；X和Z代表C、S、CH2，每个基相同或不同；Y代表O和OH；k=0、1、2；l=0、1、2；m=1到3；R5代表R1的一种含义。所述化合物作为催化剂在自由基引发剂存在下使用，其中催化剂与烃的摩尔比小于10mol％。过氧化物或偶氮化合物可用作自由基引发剂。首选底物为脂肪或芳香烃。
• Ethylene terpolymer waxes, their preparation and their use
  申请人：——

  公开号：US20040097751A1

  公开（公告）日：2004-05-20

  An ethylene terpolymer wax comprising from 40 to 95% by weight of units of ethylene, from 0.1 to 40% by weight of units of at least one anhydride of a C 4 -C 10 -dicarboxylic acid having at least one ethylenic C—C double bond, and from 0.1 to 40% by weight of units of at least one ester of the formula I 1 where R 1 is selected from hydrogen, C 1 -C 10 -alkyl, C 3 -C 12 -cycloalkyl or C 6 -C 14 -aryl and R 2 is selected from C 1 -C 10 -alkyl, C 3 -C 12 -cycloalkyl or C 6 -C 14 -aryl, having a molecular weight M w of up to 20000 g/mol.

  一种乙烯三元共聚物蜡，包括乙烯单位的质量百分含量为40至95%，至少一种具有至少一个乙烯C—C双键的C4-C10二羧酸酐单位的质量百分含量为0.1至40%，以及至少一种符合以下化学式I1的酯单位的质量百分含量为0.1至40%：其中R1从氢、C1-C10烷基、C3-C12环烷基或C6-C14芳基中选择，R2从C1-C10烷基、C3-C12环烷基或C6-C14芳基中选择，其分子量Mw最多为20000克/摩尔。
• Method for Controlled Free Radical Polymerization or Copolymerization of Methacrylic and/or Methacrylate Monomers or Exclusively Methacrylic and/or Methacrylate Copolymers
  申请人：Couturier Jean-Luc

  公开号：US20080274074A1

  公开（公告）日：2008-11-06

  The invention relates to a method for the polymerization of one or more methacrylate and/or methacrylic monomers, for the synthesis of methacrylate or methacrylic polymers or of exclusively methacrylic and/or methacrylate copolymers, comprising a step of bringing said monomer(s) into contact with one at least of the compounds of formula (I) and (II) below: in which: R 1 and R 2 may represent a phenyl group, R 3 and R 4 may together form an ═N-phenyl group, Z represents a group of formula —CR 8 R 9 R 10 , in which R 8 and R 9 may represent methyl groups and R 10 may represent a —COO-phenyl group.

  本发明涉及一种合成甲基丙烯酸甲酯或甲基丙烯酸聚合物或仅为甲基丙烯酸和/或甲基丙烯酸酯共聚物的聚合物的聚合方法，包括将上述单体与以下式(I)和(II)化合物之一中的至少一种接触的步骤：式中：R1和R2可以表示苯基，R3和R4可以共同形成═N-苯基，Z表示式—CR8R9R10的基团，其中R8和R9可以表示甲基基团，而R10可以表示—COO-苯基基团。
• [EN] COPOLYMER OF ETHYLENE AND ION PAIR COMPOUND<br/>[FR] COPOLYMÈRE D'ÉTHYLÈNE ET COMPOSÉ DE PAIRE D'IONS
  申请人：SABIC GLOBAL TECHNOLOGIES BV

  公开号：WO2021009274A1

  公开（公告）日：2021-01-21

  The invention relates to an ethylene copolymer obtained by copolymerizing ethylene and an ion pair compound consisting of a cation of formula (I) and an anion selected from formulas (II), (III), (IV) and (V), wherein (I) where R1 = H or C1-C10 alkyl; X = O or NH; R2=C1-C40 alkyl; R3, R4 = H or C1-C10 alkyl which can be connected through a cyclic structure, R5 = H or C1-C20, (II) (III) (IV) (V) where R6, R7, R9 = H or C1-C10 alkyl; R8, R10 = C1-C40 alkyl; Y, V, W = O or NH; n = 1 to 20; Z = -SO3 or -C(O)O.

  本发明涉及一种乙烯共聚物，其通过共聚乙烯和由式(I)阳离子和从式(II)、(III)、(IV)和(V)中选择的阴离子组成的离子对化合物共聚而得，其中(I)中R1 = H或C1-C10烷基；X = O或NH；R2 = C1-C40烷基；R3、R4 = H或C1-C10烷基，可以通过环状结构连接；R5 = H或C1-C20；(II) (III) (IV) (V)中R6、R7、R9 = H或C1-C10烷基；R8、R10 = C1-C40烷基；Y、V、W = O或NH；n = 1至20；Z = -SO3或-C(O)O。
• Method for producing aromatic alcohols, especially phenol
  申请人：——

  公开号：US20030083527A1

  公开（公告）日：2003-05-01

  The invention relates to a process for preparing phenol derivatives by catalytic oxidation of an aromatic hydrocarbon to the hydroperoxide and subsequent cleavage of the hydroperoxide to give the phenol derivative and a ketone, wherein a compound of the formula I 1 where R 1 , R 2 =H, aliphatic or aromatic alkoxy radical, carboxyl radical, alkoxycarbonyl radical or hydrocarbon radical, in each case having from 1 to 20 carbon atoms, SO 3 H, NH 2 , OH, F, Cl, Br, I and/or NO 2 , where R 1 and R 2 are identical or different radicals or R 1 and R 2 may be joined to one another via a covalent bond, and X, Z=C, S, CH 2 Y=O, OH k=0, 1, 2 l=0, 1, 2 m=1-3; is used as oxidation catalyst in the presence of a free-radical initiator, where the molar ratio of the catalyst to the aromatic hydrocarbon is less than 10 mol %.

  该发明涉及一种制备苯酚衍生物的过程，通过催化氧化芳香烃制备过氧化氢，随后裂解过氧化氢以得到苯酚衍生物和酮类。其中，化合物I的公式为：R1，R2 = H，脂肪或芳香基烷氧基基团，羧基基团，烷氧羰基基团或烃基，每种基团均含有1至20个碳原子，SO3H，NH2，OH，F，Cl，Br，I和/或NO2，其中R1和R2是相同的或不同的基团，或者R1和R2可以通过共价键连接在一起，同时X，Z = C，S，CH2，Y = O，OH，k = 0，1，2，l = 0，1，2，m = 1-3。该化合物作为氧化催化剂，在自由基引发剂的存在下使用，其中催化剂与芳香烃的摩尔比小于10摩尔％。