N-dichloromethylcarbazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: N-dichloromethylcarbazole
• 英文别名: 9-(Dichloromethyl)carbazole
• 化学式: C₁₃H₉Cl₂N
• 分子量: 250.127
• InChiKey: GZPJNJVPSHYWGK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  N-dichloromethylcarbazole 、 Ru(η6-p.cymene)(η4-cycloocta-1,5-diene) 、 三环己基膦 以 苯 为溶剂， 反应 3.0h， 以45%的产率得到
  参考文献：
  名称：

  PROCESS FOR SYNTHESIS OF ORGANOMETALLIC COMPOUNDS

  摘要：

  公开号：

  EP1431302B1

文献信息

• Process for synthesis of organometallic compounds
  申请人：Hiraike Hiroshi

  公开号：US20060030723A1

  公开（公告）日：2006-02-09

  A method for synthesizing an organometallic compound, which is usefully utilized as a catalyst for manufacturing polyolefins by ring-opening metathesis polymerization of an olefin having strain in a molecule such as dicyclopentadiene or synthesizing epothilones by ring-dosing metathesis reaction, by an efficient and low cost synthesis method using a starting material which is easily available due to relatively simple chemical structure, and further without any possibility of coexistence of a vinylhetero compound or a vinyl compound exchanged which tends to accompany as an impurity in the system in conventional methods, characterized by reacting a starting material comprising a zero-valent transition metal complex (A) or a polyvalent transition metal complex (A′), a compound (B) or (B′) shown by the following general formula (1) or (4), respectively, and a neutral ligand (C) or (C′), in one step under non-reducing condition or reducing condition. R 1 Y 1 CR 2 X 1 2 (1) R 4 Y 2 CR 5 X 2 2 (4)

  一种有机金属化合物的合成方法，该化合物可用作催化剂，通过分子中具有应变性的烯烃（如二环戊二烯）的开环偏聚合反应制造聚烯烃，或通过环配料偏聚合反应合成表噻吩酮，该方法采用高效、低成本的合成方法，使用的起始原料由于化学结构相对简单而易于获得、在传统方法中，乙烯基杂环化合物或交换的乙烯基化合物往往作为杂质存在于体系中，而本发明不存在这种可能性，其特征在于：使包含零价过渡金属络合物（A）或多价过渡金属络合物（A′）的起始原料发生反应、分别如下通式(1)或(4)所示的化合物(B)或(B′)和中性配体(C)或(C′)，在非还原条件或还原条件下一步反应。 R 1 Y 1 CR 2 X 1 2 (1) R 4 Y 2 CR 5 X 2 2 (4)
• ZERO-VALENCE TRANSITION METAL COMPLEX AND METHOD OF SYNTHESIZING ORGANOMETALLIC COMPOUND FROM THE SAME AS STARTING MATERIAL
  申请人：SEKISUI CHEMICAL CO., LTD.

  公开号：EP1604964B1

  公开（公告）日：2009-06-10
• Zero-valence transition metal complex and method of synthesizing organometallic compound from the same as starting material
  申请人：Hiraike Hiroshi

  公开号：US20060149088A1

  公开（公告）日：2006-07-06

  The present invention relates to a zero-valent transition metal complex which can be used as a starting material for producing a catalyst usable for producing a polyolefin by ring-opening metathesis polymerization of an olefin and an epothilone by ring-closing metathesis reaction, and a method for efficiently producing, at low cost, an organometallic compound useful as a catalyst, using the zero-valent transition metal complex as a starting material. Provided is a method for producing a zero-valent transition metal complex (C), which comprises reacting a divalent transition metal complex (A) with an olefin (B), the complex (A) being selected from the group consisting of a divalent ruthenium complex (A 1 ) and a divalent osmium complex (A 2 ), thereby obtaining a zero-valent transition metal complex (C), wherein the reaction is conducted under reducing conditions and after the reaction, the resultant crude product is extracted at high temperature using a saturated hydrocarbon as an extracting solvent. Also provided is a method for producing an organometallic compound, which comprises reacting the metal complex (C) with a specific compound (D) and a neutral ligand (E) in one step.
• US7098355B2
  申请人：——

  公开号：US7098355B2

  公开（公告）日：2006-08-29
• US7361776B2
  申请人：——

  公开号：US7361776B2

  公开（公告）日：2008-04-22