1,8-bis[N-(2-naphthyl)-N-phenylamino]pyrene

• 分子结构分类: 有机化合物 - 苯类化合物 - 芘
• 英文名称: 1,8-bis[N-(2-naphthyl)-N-phenylamino]pyrene
• 英文别名: 1-N,8-N-dinaphthalen-2-yl-1-N,8-N-diphenylpyrene-1,8-diamine
• 化学式: C₄₈H₃₂N₂
• 分子量: 636.795
• InChiKey: VQMXMVPPYHINQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14
• 重原子数：
  50
• 可旋转键数：
  6
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  芘 在 三叔丁基膦 、 溴 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 四氯化碳 、 邻二甲苯 为溶剂， 反应 57.5h， 生成 1,8-bis[N-(2-naphthyl)-N-phenylamino]pyrene
  参考文献：
  名称：

  Novel 1,8-bis(diarylamino)pyrenes as OLED materials

  摘要：

  New soluble electroluminescent pyrene derivatives, namely, 1,8-bis(diarylamino)pyrenes, have been synthesized by the Buchwald-Hartwing cross-coupling. Light-emitting devices based on these derivatives have been prepared.

  DOI：

  10.1016/j.mencom.2016.09.025

文献信息

• PYRENE POLYMER COMPOUND AND LIGHT EMITTING DEVICE USING THE SAME
  申请人：Fukushima Daisuke

  公开号：US20100109517A1

  公开（公告）日：2010-05-06

  A polymer compound comprising a constitutional unit of the formula (1), and a repeating unit of any of the formulae (2) to (4): (wherein, x3, y1, y2, z1 to z3 are 0 or 1. y3 represents an integer of 0 to 2. u represents an integer of 0 to 8. Z represents a pyrene residue, Ar 1 represents an arylene group or di-valent heterocyclic group, and Ar 2 represents an aryl group or mono-valent heterocyclic group.)
• Novel 1,8-bis(diarylamino)pyrenes as OLED materials
  作者：Mikhail G. Kaplunov、Igor K. Yakushchenko、Svetlana S. Krasnikova、Sergei B. Echmaev

  DOI：10.1016/j.mencom.2016.09.025

  日期：2016.9

  New soluble electroluminescent pyrene derivatives, namely, 1,8-bis(diarylamino)pyrenes, have been synthesized by the Buchwald-Hartwing cross-coupling. Light-emitting devices based on these derivatives have been prepared.