4-methyl-2-oxo-valeric acid sodium salt

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 酮酸及其衍生物
• 英文名称: 4-methyl-2-oxo-valeric acid sodium salt
• 英文别名: 4-Methyl-2-oxovaleriansaeure Na Salz；Sodium;4-methyl-3-oxopentanoate；sodium;4-methyl-3-oxopentanoate
• 化学式: C₆H₉O₃*Na
• 分子量: 152.125
• InChiKey: NNZIKJVBDRXAMZ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.64
• 重原子数：
  10
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  57.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-methyl-2-oxo-valeric acid sodium salt 在 aluminium amalgam 、 溶剂黄146 、 sodium nitrite 作用下， 生成 1-Amino-3-methyl-butanon-(2)
  参考文献：
  名称：

  摘要：

  DOI：

  10.1023/a:1020857721010
• 作为产物：
  描述：

  异丁酰乙酸乙酯 在 sodium hydroxide 作用下， 生成 4-methyl-2-oxo-valeric acid sodium salt
  参考文献：
  名称：

  摘要：

  DOI：

  10.1023/a:1020857721010

文献信息

• Silver Ink Composition and Substrate
  申请人：Matsumoto Takafumi

  公开号：US20130121872A1

  公开（公告）日：2013-05-16

  There is provided with a silver ink composition which is formed by blending one or more kinds of silver β-ketocarboxylates selected from the group consisting of silver isobutyrylacetate, silver benzoylacetate, silver propionylacetate, silver acetoacetate, silver α-methylacetoacetate, and silver α-ethylacetoacetate, and an aliphatic primary or secondary amine having 1 to 10 carbon atoms, and a substrate with a surface on which a metallic silver layer which is formed by heating the silver ink composition is provided. According to the invention, it is possible to obtain a silver ink composition suitable for forming a metallic silver layer which has superior glossiness and specularity, and a substrate with a surface on which a metallic silver layer is formed using the silver ink composition.

  提供了一种银墨水组合物，该组合物由混合从羰基酸酯类银中选择的一种或多种银β-酮酸盐组成，所述羰基酸酯类银包括异丁酰乙酸银、苯甲酰乙酸银、丙酰乙酸银、乙酰乙酸银、α-甲基乙酰乙酸银和α-乙基乙酰乙酸银，以及具有1至10个碳原子的脂肪族一次或二次胺，并提供了一种基板，其表面上提供了通过加热银墨水组合物形成的金属银层。根据本发明，可以获得适用于形成具有卓越光泽和反射率的金属银层的银墨水组合物，以及使用银墨水组合物形成金属银层的基板表面。
• SILVER INK COMPOSITION AND BASE MATERIAL
  申请人：Toppan Forms Co., Ltd.

  公开号：EP2599840A1

  公开（公告）日：2013-06-05

  There is provided with a silver ink composition which is formed by blending one or more kinds of silver β-ketocarboxylates selected from the group consisting of silver isobutyrylacetate, silver benzoylacetate, silver propionylacetate, silver acetoacetate, silver α-methylacetoacetate, and silver α-ethylacetoacetate, and an aliphatic primary or secondary amine having 1 to 10 carbon atoms, and a substrate with a surface on which a metallic silver layer which is formed by heating the silver ink composition is provided. According to the invention, it is possible to obtain a silver ink composition suitable for forming a metallic silver layer which has superior glossiness and specularity, and a substrate with a surface on which a metallic silver layer is formed using the silver ink composition.

  提供了一种银墨组合物，该组合物由一种或多种β-酮羧酸银（选自异丁酰乙酸银、苯甲酰乙酸银、丙酰乙酸银、乙酰乙酸银、α-甲基乙酰乙酸银、α-乙基乙酰乙酸银）和一种具有 1 至 10 个碳原子的脂肪族伯胺或仲胺混合而成、α-甲基乙酰乙酸银、α-乙基乙酰乙酸银和具有 1 至 10 个碳原子的脂肪族伯胺或仲胺，以及具有通过加热银墨组合物形成金属银层的表面的基底。根据本发明，可以获得一种适用于形成具有优异光泽度和镜面性的金属银层的银墨组合物，以及一种具有使用该银墨组合物形成金属银层的表面的基底。
• Koch, Daniela; Hoffmüller, Winfried; Polborn, Kurt, Zeitschrift fur Naturforschung, B: Chemical Sciences, 2001, vol. 56, # 4-5, p. 403 - 410
  作者：Koch, Daniela、Hoffmüller, Winfried、Polborn, Kurt、Beck, Wolfgang

  DOI：——

  日期：——
• US9328254B2
  申请人：——

  公开号：US9328254B2

  公开（公告）日：2016-05-03