7,7'-dibenzo[5,6][1,4]oxazino[2,3,4-kl]phenoxazine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 7,7'-dibenzo[5,6][1,4]oxazino[2,3,4-kl]phenoxazine
• 英文别名: 7,7'-Bi[1,4]benzoxazino[2,3,4-kl]phenoxazine；11-(8,14-dioxa-1-azapentacyclo[11.7.1.02,7.09,21.015,20]henicosa-2,4,6,9,11,13(21),15,17,19-nonaen-11-yl)-8,14-dioxa-1-azapentacyclo[11.7.1.02,7.09,21.015,20]henicosa-2,4,6,9,11,13(21),15,17,19-nonaene
• 化学式: C₃₆H₂₀N₂O₄
• 分子量: 544.566
• InChiKey: LQIJYRYGPVWGLO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.5
• 重原子数：
  42
• 可旋转键数：
  1
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  43.4
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-溴-2,6-二氟苯胺 在 2,2'-联吡啶 、 bis(1,5-cyclooctadiene)nickel (0) 、 1,5-cis,cis-cyclooctadiene 、 三溴化硼 、 铜 、 potassium carbonate 作用下， 以 四氢呋喃 、 二氯甲烷 、 N,N-二甲基甲酰胺 、 邻二氯苯 为溶剂， 反应 149.0h， 生成 7,7'-dibenzo[5,6][1,4]oxazino[2,3,4-kl]phenoxazine
  参考文献：
  名称：

  空穴传输材料中准平面分子的顶部π堆积：在非晶膜中诱导各向异性载流子迁移。

  摘要：

  设计并合成了部分氧桥联的三芳基胺的二聚体作为空穴传输材料。X射线结构分析表明，这些化合物以结晶状态形成顶部π堆积聚集体。TRMC测量结果表明，在π堆积方向上诱导了高水平的各向异性电荷传输。出乎意料的是，即使在真空沉积的非晶膜中，这些化合物也保留了一些π堆叠的面，从而促进了面外载流子迁移。

  DOI：

  10.1002/anie.201400068

文献信息

• POLYCYCLIC AROMATIC COMPOUNDS AND THEIR USE AS ORGANIC DEVICE MATERIAL
  申请人：Kwansei Gakuin Educational Foundation

  公开号：EP3345911A1

  公开（公告）日：2018-07-11

  The present invention provides novel polycyclic aromatic compounds and organic electroluminescent elements using the same. The compounds are of formula (2) in which Y1 is P=O or P=S, X1 and X2 are oxygen and R1- R11 are as defined in the claims.

  本发明提供了新型多环芳烃化合物和使用这种化合物的有机电致发光元件。这些化合物为式（2），其中 Y1 为 P=O 或 P=S，X1 和 X2 为氧，R1- R11 如权利要求中所定义。
• Solid-state image sensor, photoelectric conversion film, electron blocking layer, imaging apparatus, and electronic device
  申请人：SONY SEMICONDUCTOR SOLUTIONS CORPORATION

  公开号：US11088207B2

  公开（公告）日：2021-08-10

  The present technology relates to a solid-state image sensor, a photoelectric conversion film, an electron blocking layer, an imaging apparatus, and an electronic device that can appropriately photoelectrically convert light of specific wavelengths with high spectral characteristics and high photoelectric conversion efficiency. A photoelectric conversion layer or an electron blocking layer is configured with a photoelectric conversion film made of only a compound represented by Chemical Formula (1). The present technology can be applied to a solid-state image sensor.

  本技术涉及一种固态图像传感器、一种光电转换膜、一种电子阻挡层、一种成像装置和一种电子设备，可适当地对特定波长的光进行光电转换，具有高光谱特性和高光电转换效率。光电转换层或电子阻挡层配置了仅由化学式（1）所代表的化合物制成的光电转换薄膜。 本技术可应用于固态图像传感器。
• NOVEL COMPOUND, CHARGE TRANSPORT MATERIAL, AND ORGANIC DEVICE
  申请人：Wakamiya Atsushi

  公开号：US20140058099A1

  公开（公告）日：2014-02-27

  The compounds represented fey the following general formula is is thermally stable and has excellent characteristics as a charge transport material [Ar 1 represents a single bond, a benzene ring, etc.; X 1 represents a linking group that links via an oxygen atom, a sulfur atom, a carbon atom, a nitrogen atom, a phosphorus atom or a silicon atom; either one of L 1 and L 2 , and L 3 and L 4 bond to each other to represent a linking group that links via an oxygen atom, a sulfur atom, a carbon atom, a nitrogen atom, a phosphorus atom or a silicon atom; the other of L 1 and L 2 , and L 3 and L 4 represent a hydrogen atom or a substituent; Y 1 represents a linking group that links via a nitrogen atom, a boron atom or a phosphorus atom; R 1 , R 2 , R 5 to R 7 and R 10 to R 12 represent a hydrogen atom or a substituent; and n1 indicates an integer of 2 or more.].
• MATERIAL FOR ORGANIC ELECTROLUMINESCENT DEVICE AND ORGANIC ELECTROLUMINESCENT DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20160099416A1

  公开（公告）日：2016-04-07

  A compound for an organic electroluminescent device is represented by the following General Formula (1). X in General Formula (1) is selected from the following General Formulae (2), (3) and (4).
• POLYMER, ORGANIC LIGHT-EMITTING DEVICE MATERIAL INCLUDING THE SAME, AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE ORGANIC LIGHT-EMITTING DEVICE MATERIAL
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US20170186950A1

  公开（公告）日：2017-06-29

  A polymer comprising a first repeating unit represented by Formula 1: wherein, in Formula 1, groups and variables are the same as described in the specification.