2,4,4,5,7,7,8,8,9,9,9-undecafluoro-2,5-bis(trifluoromethyl)-3,6-dioxanonyloxymethyloxirane

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: 2,4,4,5,7,7,8,8,9,9,9-undecafluoro-2,5-bis(trifluoromethyl)-3,6-dioxanonyloxymethyloxirane
• 英文别名: 2-[[2,3,3,3-Tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]methyl]oxirane；2-[[2,3,3,3-tetrafluoro-2-[1,1,2,3,3,3-hexafluoro-2-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]methyl]oxirane
• 化学式: C₁₂H₇F₁₇O₄
• 分子量: 538.158
• InChiKey: KLOYSEPXLXBZQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  33
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.2
• 氢给体数：
  0
• 氢受体数：
  21

反应信息

• 作为反应物：
  描述：

  2,4,4,5,7,7,8,8,9,9,9-undecafluoro-2,5-bis(trifluoromethyl)-3,6-dioxanonyloxymethyloxirane 、 四氟丙醇 在 sodium 作用下， 以 1,4-二氧六环 为溶剂， 反应 2.0h， 以57%的产率得到1-(2,2,3,3-tetrafluoropropoxy)-6,8,8,9,11,11,12,12,13,13,13-undecafluoro-6,9-bis(trifluoromethyl)-4,7,10-trioxatridecan-2-ol
  参考文献：
  名称：

  碱性介质中含氟缩水甘油醚与醇反应的特征

  摘要：

  The reaction of fluorine-containing glycidyl ethers with various alcohols (i-PrOH, MeOH, PhOH, 2,2,3,3-tetrafluoropropanol) in basic medium resulted in products of regioselective opening of the oxirane ring. In reaction of 2,2,3,3-tetrafluoropropyloxymethyloxirane with 2-propanol under conditions of phase-transfer catalysis the main product was the corresponding 1,2-diol (yield 42%).

  DOI：

  10.1134/s1070428007050041

文献信息

• Synthesis and inhibiting capacity of new fluorine-containing quaternary ammonium salts
  作者：T. I. Gorbunova、D. N. Bazhin、A. Ya. Zapevalov、V. I. Saloutin

  DOI：10.1134/s1070427211060127

  日期：2011.6

  New fluorine-containing quaternary ammonium salts exhibiting a high inhibiting capacity against hydrochloric acid corrosion of low-carbon steels were synthesized. The polarization resistance method was used to determine the uniform-corrosion rates of steel-3 and steel-35 in relation to the structure of fluorine-containing moieties of quaternary ammonium salts and their concentration.
• Features of reaction between fluorine-containing glycidyl ethers and alcohols in basic medium
  作者：D. N. Bazhin、T. I. Gorbunova、A. Ya. Zapevalov、V. E. Kirichenko、V. I. Saloutin

  DOI：10.1134/s1070428007050041

  日期：2007.5

  The reaction of fluorine-containing glycidyl ethers with various alcohols (i-PrOH, MeOH, PhOH, 2,2,3,3-tetrafluoropropanol) in basic medium resulted in products of regioselective opening of the oxirane ring. In reaction of 2,2,3,3-tetrafluoropropyloxymethyloxirane with 2-propanol under conditions of phase-transfer catalysis the main product was the corresponding 1,2-diol (yield 42%).