N,N-bis(3-aminopropyl)diethylenetriamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-bis(3-aminopropyl)diethylenetriamine
• 英文别名: N'-[2-(2-aminoethylamino)ethyl]-N'-(3-aminopropyl)propane-1,3-diamine
• 化学式: C₁₀H₂₇N₅
• 分子量: 217.358
• InChiKey: YKQBMYCRCNRDEB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.3
• 重原子数：
  15
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  93.3
• 氢给体数：
  4
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  丙烯腈 、 二乙烯三胺 在 lithium hydroxide monohydrate 、 氢气 作用下， 以 水 、 异丙醇 为溶剂， 70.0~145.0 ℃ 、5.62 MPa 条件下， 反应 4.67h， 生成 N,N'-bis(3-aminopropyl)diethylenetriamine 、 N'-[2-(2-氨基乙胺基)乙基]丙烷-1,3-二胺 、 N,N',N''-tris(3-aminopropyl)diethylenetriamine 、 N,N-bis(3-aminopropyl)diethylenetriamine 、 N-3-aminopropyl-[N'-3-[N-3-aminopropyl]aminopropyl]diethylenetriamine 、 N,N,N'-tris(3-aminopropyl)diethylenetriamine
  参考文献：
  名称：

  [EN] AMIDOAMINE AND POLYAMIDE CURING AGENTS, COMPOSITIONS, AND METHODS
  [FR] AGENTS, COMPOSITIONS ET PROCÉDÉS DE DURCISSEMENT D'AMIDOAMINE ET DE POLYAMIDES

  摘要：

  本发明涉及一种包括肽胺固化剂组合物或聚酰胺固化剂组合物的组成物。该组合物包括以下反应产物：(1)胺组分，包括至少一种结构为(I)的多功能胺，其中每个R独立地为H或CH2CH2CH2NH2; R1为H、CH3CH2CH2N-、C1-C21烷基或C1-C21烯基; n为2; m为1或2；(2)脂肪酸或酯组分，选自二聚脂肪酸或酯组分、单功能脂肪酸或酯组分及其组合物。该肽胺固化剂组合物在常温下仍保持液态。

  公开号：

  WO2017136333A1

文献信息

• BENZYLATED MANNICH BASE CURING AGENTS, COMPOSITIONS, AND METHODS
  申请人：EVONIK DEGUSSA GMBH

  公开号：US20170240691A1

  公开（公告）日：2017-08-24

  Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): wherein R 1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R 2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): wherein R A is substituted or unsubstituted benzyl; R B is each independently R A , or a hydrogen atom, or a group selected from C 1 -C 16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C 2 -C 10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.

  含有苄基曼尼希碱基组分的组合物和固化剂。所述苄基曼尼希碱基组分包括以下反应产物：(a)至少具有一个取代基的取代酚化合物，所述取代基的公式为(I)：其中R1各自独立地是具有1到4个碳原子的线性或支链烷基，R2是氢、甲基、乙基或苯基；(b)苄基化的聚烯烃聚醚胺(II)：其中RA是取代或未取代的苄基，RB各自独立地是RA或氢原子，或选自C1-C16线性、环状和支链烷基、烯基和烷基芳基基团；X、Y和Z各自独立地选自C2-C10烷基和环状烷基基团；y是0到7的整数，z是0到4的整数；可选地，(c)多功能胺。还公开了胺-环氧组合物和由这些组合物制成的物品。
• Benzylated mannich base curing agents, compositions, and methods
  申请人：Evonik Operations GmbH

  公开号：US10669370B2

  公开（公告）日：2020-06-02

  Compositions and curing agents comprising a benzylated Mannich base composition. The benzylated Mannich base composition includes a reaction product of (a) a substituted phenolic compound having at least one substituent of formula (I): wherein R1 is each independently a linear or branched alkyl group having 1 to 4 carbon atoms, and R2 is hydrogen, methyl, ethyl or phenyl, with (b) a benzylated polyalkylene polyamine (II): wherein RA is substituted or unsubstituted benzyl; RB is each independently RA, or a hydrogen atom, or a group selected from C1-C16 linear, cyclic, and branched alkyl, alkenyl, and alkaryl groups; X, Y, and Z are independently selected from C2-C10 alkylene, and cycloalkylene groups; y is an integer from 0 to 7, and z is an integer from 0 to 4; and, optionally, (c) a multifunctional amine. Amine-epoxy compositions and articles produced from these compositions are also disclosed.

  包含苄化曼尼希基组合物的组合物和固化剂。苄化曼尼希基组合物包括以下物质的反应产物：(a) 具有至少一个式 (I) 取代基的取代酚化合物： 其中 R1 各自独立地为具有 1 至 4 个碳原子的直链或支链烷基，R2 为氢、甲基、乙基或苯基，与(b)苄化聚亚烷基多胺(II)的反应产物： 其中 RA 是取代或未取代的苄基；RB 各自独立地是 RA，或氢原子，或选自 C1-C16 直链、环链和支链烷基、烯基和芳烷基的基团；X、Y 和 Z 独立地选自 C2-C10 亚烷基和环亚烷基；y 是 0 至 7 的整数，z 是 0 至 4 的整数；以及，任选地，(c) 多官能胺。此外，还公开了胺环氧组合物和由这些组合物生产的物品。
• Amidoamine and polyamide curing agents, compositions, and methods
  申请人：Evonik Operations GmbH

  公开号：US10676564B2

  公开（公告）日：2020-06-09

  A composition including an amidoamine curing agent composition or a polyamide curing agent composition are disclosed. The composition includes the reaction products of (1) an amine component including at least one multifunctional amine of structure (I): wherein each R is independently H or CH2CH2CH2NH2; R1 is H, CH3CH2CH2N—, C1-C21 alkyl, or C1-C21 alkenyl; n is 2; and m is 1 or 2, with (2) a fatty acid or ester component selected from the group consisting of a dimer fatty acid or ester component, a monofunctional fatty acid or ester component, and combinations thereof. The amidoamine curing agent composition remains as liquid at ambient temperature.

  本发明公开了一种包括氨基胺固化剂组合物或聚酰胺固化剂组合物的组合物。该组合物包括以下物质的反应产物：(1) 包括至少一种结构(I)的多功能胺的胺组分： 其中每个 R 独立地为 H 或 CH2CH2CH2NH2；R1 为 H、CH3CH2CH2N-、C1-C21 烷基或 C1-C21 烯基；n 为 2；m 为 1 或 2，与(2)选自由二聚脂肪酸或酯类组分、单官能脂肪酸或酯类组分及其组合组成的组的脂肪酸或酯类组分。氨基胺固化剂组合物在环境温度下保持液态。
• Amine alkenyl substituted succinimide reaction product fuel additives, compositions, and methods
  申请人：Evonik Operations GmbH

  公开号：US10899985B2

  公开（公告）日：2021-01-26

  Amine alkenyl substituted succinimide reaction product compositions including the reaction products of (1) an amine component including at least one multifunctional amine of structure (1): wherein each R is independently H or CH2CH2CH2NH2; R1 is H, CH2CH2CH2NH2, C1-C21 alkyl, or C2-C21 alkenyl; n is 2; and m is 1 or 2 and (2) an alkenyl substituted anhydride. Additive compositions, fuel additives, fuel compositions and methods for reducing deposit formations in a fuel system are also disclosed.

  胺烯丙基取代琥珀酰亚胺反应产物组合物，包括(1)的反应产物，胺组分包括至少一种结构(1)的多功能胺： 其中每个 R 独立地为 H 或 CH2CH2CH2NH2；R1 为 H、CH2CH2CH2NH2、C1-C21 烷基或 C2-C21 烯基；n 为 2；以及 m 为 1 或 2 和 (2) 烯基取代的酸酐。此外，还公开了用于减少燃料系统中沉积物形成的添加剂组合物、燃料添加剂、燃料组合物和方法。
• Substituted Mannich base fuel additives, compositions, and methods
  申请人：Evonik Operations GmbH

  公开号：US10899986B2

  公开（公告）日：2021-01-26

  Mannich base compositions include the reaction products of (1) an amine component including at least one multifunctional amine of structure (1): wherein each R is independently H or CH2CH2CH2NH2; R1 is H, CH2CH2CH2NH2, C1-C21 alkyl, or C2-C21 alkenyl; n is 2; and m is 1 or 2, with (2) an alkyl substituted hydroxyaromatic compound, and (3) and aldehyde. The Mannich base compositions are useful for fuel additives and other articles. Additive compositions, fuel additives, fuel compositions and methods for reducing deposit formations in a fuel system are also disclosed.

  曼尼希碱组合物包括 (1) 包括至少一种结构 (1) 的多功能胺的胺组分的反应产物： 其中每个 R 独立地为 H 或 CH2CH2CH2NH2；R1 为 H、CH2CH2CH2NH2、C1-C21 烷基或 C2-C21 烯基；n 为 2；m 为 1 或 2，与(2)烷基取代的羟基芳香族化合物和(3)醛反应。曼尼希碱组合物适用于燃料添加剂和其他物品。此外，还公开了用于减少燃料系统中沉积物形成的添加剂组合物、燃料添加剂、燃料组合物和方法。