lyophyllin

• 分子结构分类: 有机化合物 - 有机1,3-偶极化合物 - 烯丙基型1,3-偶极有机化合物
• 英文名称: lyophyllin
• 英文别名: Lyophyllin；dimethylcarbamoylimino-methyl-oxidoazanium
• 化学式: C₄H₉N₃O₂
• 分子量: 131.134
• InChiKey: HQAXXRWVFPWZIL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.3
• 重原子数：
  9
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  61.4
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N-甲基羟胺 、 N-hydroxy-N',N'-dimethylurea 以 水 为溶剂， 生成 lyophyllin
  参考文献：
  名称：

  Biosynthesis of the Azoxycarboxamide Lyophyllin and Formation of Some of its Unnatural Analogues in Fruit-bodies of Lyophyllum connatum

  摘要：

  The azoxy compound lyophyllin (3) is formed in fruit-bodies of the toadstool Lyophyllum connatum by oxidative condensation of N-hydroxy-N'N'-dimethyiurea (2) with N-methylhydroxylamine (4). The condensing enzyme is remarkably unspecific and transforms a variety of hydroxyureas and N-alkyl-hydroxylamines into the corresponding lyophyllin analogues 5. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)10177-0

文献信息

• Biosynthesis of the Azoxycarboxamide Lyophyllin and Formation of Some of its Unnatural Analogues in Fruit-bodies of Lyophyllum connatum
  作者：Yang Ye、Katharina Aulinger、Norbert Arnold、Werner Spahl、Wolfgang Steglich

  DOI：10.1016/s0040-4039(97)10177-0

  日期：1997.11

  The azoxy compound lyophyllin (3) is formed in fruit-bodies of the toadstool Lyophyllum connatum by oxidative condensation of N-hydroxy-N'N'-dimethyiurea (2) with N-methylhydroxylamine (4). The condensing enzyme is remarkably unspecific and transforms a variety of hydroxyureas and N-alkyl-hydroxylamines into the corresponding lyophyllin analogues 5. (C) 1997 Elsevier Science Ltd.