The present invention provides solvent- and water-based primer compositions that include at least one carboxylated polyolefin that has been modified with one or more polyfunctional alcohols. The carboxylated polyolefins are obtained by the reaction of polyolefins with at least one of unsaturated carboxylic esters, unsaturated carboxylic acids, unsaturated carboxylic anhydrides, acrylic monomers, and mixtures thereof. The carboxylated polyolefins are then further modified by reaction with one or more polyfunctional alcohols. These polyfunctional alcohol-modified polyolefins may also contain pendant carboxyl groups, which have the propensity to form hydrophilic salts with amines or inorganic bases, thereby rendering the polyfunctional alcohol-modified polyolefins water-dispersible. These primer compositions are useful for significantly improving the adhesion of paints, adhesives, and inks to various plastic and metal substrates.
本发明提供了溶剂型和
水性底漆组合物,其中包括至少一种已经经过一种或多种多官能醇修饰的羧化聚烯烃。这些羧化聚烯烃是通过聚烯烃与不饱和
羧酸酯、不饱和
羧酸、不饱和
羧酸酐、
丙烯酸单体及其混合物之一的反应得到的。然后,这些羧化聚烯烃通过与一种或多种多官能醇的反应进一步修饰。这些多官能醇修饰的聚烯烃也可能含有挂链羧基,这些羧基具有与胺或
无机碱形成亲
水性盐的倾向,从而使多官能醇修饰的聚烯烃变得可分散于
水中。这些底漆组合物可用于显著提高涂料、粘合剂和油墨附着于各种塑料和
金属基材上的能力。