1-butynyl α-phenyl-α-(1-butynyloxy)phenylacetate

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-butynyl α-phenyl-α-(1-butynyloxy)phenylacetate
• 英文别名: 1-Butynyl alpha-phenyl-alpha-(1-butynyloxy)phenylacetate；but-1-ynyl 2-but-1-ynoxy-2,2-diphenylacetate
• 化学式: C₂₂H₂₀O₃
• 分子量: 332.399
• InChiKey: UXTDMLUYMZYAOB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  25
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  、 二苯基羟基乙酸 、 1-溴-1-丁烷 在 乙醚 、 氯化钠 、 Sodium sulfate-III 、 paraffin 作用下， 以 N,N-二甲基甲酰胺 、 ice water 为溶剂， 反应 2.0h， 以to obtain 4.0 g of oily 1-butynyl α-phenyl-α-(1-butynyloxy)phenylacetate的产率得到1-butynyl α-phenyl-α-(1-butynyloxy)phenylacetate
  参考文献：
  名称：

  Phenylacetic acid derivatives

  摘要：

  该化合物的化学式为##SPC1##其中R.sub.1是C.sub.1.sub.-6烷基，C.sub.2.sub.-6烯基，C.sub.3.sub.-6炔基，C.sub.3.sub.-6环烷基，苄基，噻吩基或##SPC2##（其中R.sub.4是氢，卤素，C.sub.1.sub.-4烷基或亚甲氧基，n为1至5的整数），R.sub.2是C.sub.1.sub.-6烷基，C.sub.3.sub.-6烯基或C.sub.3.sub.-6炔基，R.sub.3是C.sub.1.sub.-6烷基，C.sub.3.sub.-6烯基或C.sub.3.sub.-6炔基（前提是当R.sub.3是C.sub.1.sub.-6烷基时，R.sub.2是C.sub.3.sub.-6炔基），A是--COOR.sub.3或--CH.sub.2 OR.sub.3的基团，前提是当A是--CH.sub.2 OR.sub.3的基团时，R.sub.1是C.sub.1.sub.-6烷基，C.sub.2.sub.-6烯基，C.sub.3.sub.-6炔基，C.sub.3.sub.-6环烷基或苄基（R.sub.3如上所定义），当R.sub.1是##SPC3##（其中R.sub.4和n如上所定义）且A是--COOR.sub.3的基团时，R.sub.3是C.sub.4.sub.-6烯基或C.sub.4.sub.-6炔基，该化合物可用作杀虫剂的协同剂，特别是环丙烷羧酸酯类或氨基甲酸酯类杀虫剂。

  公开号：

  US03970703A1

文献信息

• Phenylacetic acid derivatives
  申请人：Sumitomo Chemical Company, Limited

  公开号：US03970703A1

  公开（公告）日：1976-07-20

  A compound of the formula, ##SPC1## Wherein R.sub.1 is a C.sub.1.sub.-6 alkyl, a C.sub.2.sub.-6 alkenyl, a C.sub.3.sub.-6 alkynyl, a C.sub.3.sub.-6 cycloalkyl, benzyl, thienyl or a group of ##SPC2## (R.sub.4 is hydrogen, halogen, a C.sub.1.sub.-4 alkyl or methylenedioxy, and n is an integer of 1 to 5), R.sub.2 is a C.sub.1.sub.-6 alkyl, a C.sub.3.sub.-6 alkenyl or a C.sub.3.sub.-6 alkynyl, R.sub.3 is a C.sub.1.sub.-6 alkyl, a C.sub.3.sub.-6 alkenyl or a C.sub.3.sub.-6 alkynyl, (provided that R.sub.2 is a C.sub.3.sub.-6 alkynyl when R.sub.3 is a C.sub.1.sub.-6 alkyl), and A is a group of --COOR.sub.3 or --CH.sub.2 OR.sub.3, provided that R.sub.1 is a C.sub.1.sub.-6 alkyl, a C.sub.2.sub.-6 alkenyl, a C.sub.3.sub.-6 alkynyl, a C.sub.3.sub.-6 cycloalkyl or benzyl when A is a group of --CH.sub.2 OR.sub.3 (R.sub.3 is as defined above), and R.sub.3 is a C.sub.4.sub.-6 alkenyl or a C.sub.4.sub.-6 alkynyl when R.sub.1 is a group of ##SPC3## (R.sub.4 and n are as defined above) and A is a group of --COOR.sub.3, which is useful as synergist for insecticides, especially for a cyclopropane-carboxylate or a carbamate type insecticide.

  该化合物的化学式为##SPC1##其中R.sub.1是C.sub.1.sub.-6烷基，C.sub.2.sub.-6烯基，C.sub.3.sub.-6炔基，C.sub.3.sub.-6环烷基，苄基，噻吩基或##SPC2##（其中R.sub.4是氢，卤素，C.sub.1.sub.-4烷基或亚甲氧基，n为1至5的整数），R.sub.2是C.sub.1.sub.-6烷基，C.sub.3.sub.-6烯基或C.sub.3.sub.-6炔基，R.sub.3是C.sub.1.sub.-6烷基，C.sub.3.sub.-6烯基或C.sub.3.sub.-6炔基（前提是当R.sub.3是C.sub.1.sub.-6烷基时，R.sub.2是C.sub.3.sub.-6炔基），A是--COOR.sub.3或--CH.sub.2 OR.sub.3的基团，前提是当A是--CH.sub.2 OR.sub.3的基团时，R.sub.1是C.sub.1.sub.-6烷基，C.sub.2.sub.-6烯基，C.sub.3.sub.-6炔基，C.sub.3.sub.-6环烷基或苄基（R.sub.3如上所定义），当R.sub.1是##SPC3##（其中R.sub.4和n如上所定义）且A是--COOR.sub.3的基团时，R.sub.3是C.sub.4.sub.-6烯基或C.sub.4.sub.-6炔基，该化合物可用作杀虫剂的协同剂，特别是环丙烷羧酸酯类或氨基甲酸酯类杀虫剂。
• US3970703A
  申请人：——

  公开号：US3970703A

  公开（公告）日：1976-07-20