4,4'-bis(acryloyloxy)benzophenone

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4,4'-bis(acryloyloxy)benzophenone
• 英文别名: 4,4'-Diacryloyloxybenzophenone；[4-(4-prop-2-enoyloxybenzoyl)phenyl] prop-2-enoate
• 化学式: C₁₉H₁₄O₅
• 分子量: 322.317
• InChiKey: FQGXORNEAHWMOH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  69.7
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  4,4'-二羟基二苯甲酮 、 丙烯酰氯 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 乙腈 为溶剂， 反应 28.33h， 以13%的产率得到4,4'-bis(acryloyloxy)benzophenone
  参考文献：
  名称：

  Tuning the color switching of naphthopyrans via the control of polymeric architectures

  摘要：

  一系列可聚合的光致变色萘吡喃通过在萘环（R）和/或二芳基（Ar）环的3位上合成丙烯酸酯基团来制备。获得的单体（NA）通过RAFT（可逆加成断裂链转移）过程与甲基丙烯酸甲酯（MMA）和丙烯酸甲酯（MA）共聚，以控制聚合物链的结构并精确控制每条链上的光致变色分子数量。制备了合成的光致变色聚合物薄膜并评估了它们的光致变色性能。我们发现，光致变色染料在PMMA（高Tg）基质中的褪色速率比在PMA（低Tg）基质中慢。通过制备PMMA-b-聚（MA-co-NA）嵌段共聚物，褪色速率增加，而制备PS-b-聚（MA-co-NA）进一步提高了开关速度，因为聚（MA-co-NA）嵌段和PS嵌段之间发生了相分离。这项研究展示了一个通过改变染料聚合物支撑结构的实例来调谐光致变色性能。

  DOI：

  10.1039/b617865k

文献信息

• A CURABLE JETTABLE FLUID FOR MAKING A FLEXOGRAPHIC PRINTING MASTER
  申请人：AGFA NV

  公开号：EP2656144B1

  公开（公告）日：2020-06-24
• PHOTOCHROMIC FILMS AND METHOD FOR MANUFACTURING THE SAME
  申请人：Kim Sang Young

  公开号：US20090250670A1

  公开（公告）日：2009-10-08

  Disclosed is a photochromic film for automobiles prepared by curing a photochromic composition comprising an acrylic resin, a crosslinking agent having an intramolecular UV stabilizing structure, and a photochromic dye, a preparation method of the photochromic film for automobiles, and an article comprising the photochromic film for automobiles.
• CURABLE JETTABLE FLUID FOR MAKING A FLEXOGRAPHIC PRINTING MASTER
  申请人：Vanmaele Luc

  公开号：US20130269558A1

  公开（公告）日：2013-10-17

  The present invention relates to a curable jettable fluid for making a flexographic printing master comprising an initiator, a cyclic monofunctional (meth)acrylate monomer and a difunctional (meth)acrylate monomer characterized in that the initiator is an oligomer, a polymer or a copolymerizable compound.
• US4329360A
  申请人：——

  公开号：US4329360A

  公开（公告）日：1982-05-11
• Tuning the color switching of naphthopyrans via the control of polymeric architectures
  作者：Wilasinee Sriprom、Marjorie Néel、Christopher D. Gabbutt、B. Mark Heron、Sébastien Perrier

  DOI：10.1039/b617865k

  日期：——

  A range of polymerisable photochromic naphthopyrans were prepared via the synthesis of an acrylate moiety on either the naphthalene ring (R) and/or the di-aryl (Ar) rings on the 3-position of the naphthopyran. The monomers obtained (NA) were copolymerised with methyl methacrylate (MMA) and methyl acrylate (MA) by the RAFT (reversible addition fragmentation chain transfer) process in order to control the structure of the polymeric chains and accurately control the number of photochromic molecules per chain. Films were prepared with the synthesized photochromic polymers and their photochromic properties were assessed. We found that the fading rate of the photochromic dye was slower in a matrix of PMMA (higher Tg) than in a matrix of PMA (lower Tg). By producing block copolymers of PMMA-b-poly(MA-co-NA), the fading rate was increased, and the production of PS-b-poly(MA-co-NA) further enhanced the speed of switching, as phase separation occurred between the poly(MA-co-NA) block and the PS block. This study presents an example of tuning the photochromic properties of a dye via variation of the architecture of its polymeric support.

  一系列可聚合的光致变色萘吡喃通过在萘环（R）和/或二芳基（Ar）环的3位上合成丙烯酸酯基团来制备。获得的单体（NA）通过RAFT（可逆加成断裂链转移）过程与甲基丙烯酸甲酯（MMA）和丙烯酸甲酯（MA）共聚，以控制聚合物链的结构并精确控制每条链上的光致变色分子数量。制备了合成的光致变色聚合物薄膜并评估了它们的光致变色性能。我们发现，光致变色染料在PMMA（高Tg）基质中的褪色速率比在PMA（低Tg）基质中慢。通过制备PMMA-b-聚（MA-co-NA）嵌段共聚物，褪色速率增加，而制备PS-b-聚（MA-co-NA）进一步提高了开关速度，因为聚（MA-co-NA）嵌段和PS嵌段之间发生了相分离。这项研究展示了一个通过改变染料聚合物支撑结构的实例来调谐光致变色性能。